We consider composite media made of homogeneous inclusions with C1,α,boundaries. Our goal is to compare the potential uε in a perfectly periodic composite with the potential uε,d, of a perturbed periodic medium, where the periodicity defects consist of misplaced inclusions. We give an asymptotic expansion of the difference uε,d − uε away from the defects and show that, to first order, a misplaced inclusion manifests itself via a polarization tensor, which is characterized.