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Oxygen isotope composition of annually banded modern and mid-Holocene travertine and evidence of paleomonsoon floods, Grand Canyon, Arizona, USA

Published online by Cambridge University Press:  20 January 2017

Gary R. O'Brien
Affiliation:
Department of Geology, Northern Arizona University, Flagstaff, AZ 86011-4099, USA
Darrell S. Kaufman*
Affiliation:
Department of Geology, Northern Arizona University, Flagstaff, AZ 86011-4099, USA Department of Environmental Sciences, Northern Arizona University, Flagstaff, AZ 86011-4099, USA
Warren D. Sharp
Affiliation:
Berkeley Geochronology Center, Berkeley, CA 94709, USA
Viorel Atudorei
Affiliation:
Department of Earth and Planetary Science, University of New Mexico, Albuquerque, NM 87131-0001, USA
Roderic A. Parnell
Affiliation:
Department of Geology, Northern Arizona University, Flagstaff, AZ 86011-4099, USA Department of Earth and Planetary Science, University of New Mexico, Albuquerque, NM 87131-0001, USA
Laura J. Crossey
Affiliation:
Department of Earth and Planetary Science, University of New Mexico, Albuquerque, NM 87131-0001, USA
*
*Corresponding author. Department of Geology, Northern Arizona University, Flagstaff, AZ 86011-4099, USA. E-mail address:Darrell.Kaufman@nau.edu (D.S. Kaufman).

Abstract

Holocene and modern travertine formed in spring-fed Havasu Creek of the Grand Canyon, Arizona, was studied to determine the factors governing its oxygen-isotope composition. Analysis of substrate-grown travertine indicates that calculated calcite-formation temperatures compare favorably with measured water temperatures, and include silt-rich laminae deposited by monsoon-driven floods. Ancient spring-pool travertine is dated by U-series at 7380 ± 110 yr and consists of 14 travertine-silt couplets of probable annual deposition. One hundred eighty high-resolution δ18O analyses of this mid-Holocene sample average −11.0‰ PDB. The average value for modern travertine is ∼0.5‰ lower, perhaps because mid-Holocene temperature was higher or there was proportionally greater summer recharge. δ18O cyclicity in the mid-Holocene travertine has average amplitude of 1.9 ± 0.5‰ PDB, slightly less than the inferred modern-day annual temperature range of Havasu Creek. The annual temperature range might have been reduced during the 14-yr interval compared to present, although other non-temperature factors could account for the muted annual variation. Silt-rich laminae within isotopically lower calcite in the modern and mid-Holocene travertine verifies the seasonal resolution of both samples, and suggests that similar temperature-precipitation conditions, as well as monsoon-generated summer floods, prevailed in the mid-Holocene as they do throughout the Grand Canyon region today.

Type
Research Article
Copyright
University of Washington

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References

Adams, D.K., Comrie, A.C., (1997). The North American monsoon. Bulletin of the American Meteorological Society 78, 21972213.Google Scholar
Andrews, J.E., Brasier, A.T., (2005). Seasonal records of climatic change in annually laminated tufas: short review and future prospects. Journal of Quaternary Science 20, 411421.CrossRefGoogle Scholar
Black, D.M., (1955). Natural dams of Havasu Canyon, Supai, Arizona. Science 121, 611612.Google Scholar
Broström, A., Coe, M., Harrison, S.P., Gallimore, R., Kutzbach, J.E., Foley, J., Prentice, I.C., Behling, P., (1998). Land surface feedbacks and palaeomonsoons in northern Africa. Geophysical Research Letters 25, 36153618.CrossRefGoogle Scholar
Chafetz, H.S., Utech, N.M., Fitzmaurice, S.P., (1991). Differences in the δ 18O and δ 13C signatures of seasonal laminae comprising travertine stromatolites. Journal of Sedimentary Petrology 61, 10151028.Google Scholar
Chen, J., Zhang, D.D., Wang, S., Xiao, T., Huang, R., (2004). Factors controlling tufa deposition in natural waters at waterfall sites. Sedimentary Geology 166, 353366.CrossRefGoogle Scholar
Cole, K., (1982). Late Quaternary zonation of vegetation in the eastern Grand Canyon. Science 217, 11421145.CrossRefGoogle ScholarPubMed
Dettman, D.L., Lohman, K.C., (1993). Seasonal change in Paleogene surface water δ 18O: fresh water bivalves of western North America. Swart, P.K., Lohmann, K.C., McKenzie, J., Savin, S. Climate Change in Continental Isotopic Records. Geophysical Monograph vol. 78, American Geophysical Union, Washington DC.153163.Google Scholar
Epstein, S., Buchsbaum, R., Lowenstam, H.A., Urey, H.C., (1951). Carbonate–water isotopic temperature scale. Geological Society of America Bulletin 62, 417425.Google Scholar
Fitzgerald, J., (1996). Residence time of groundwater issuing from the south-rim aquifer in the eastern Grand Canyon. Unpublished MS thesis, Department of Geosciences.. University of Nevada, Las Vegas.Google Scholar
Friedman, T., O'Neil, J.R., (1977). Compilation of stable isotope fractionation factors of geochemical interest.. In: Data Geochemical 6th Edition Geological Survey Professional Paper 440KK .Google Scholar
Garnett, E., Andrews, J., Preece, R., Dennis, P., (2004). Climatic change recorded by stable isotopes and trace elements in a British Holocene tufa. Journal of Quaternary Science 19, 251262.Google Scholar
Giegengack, R., Ralph, E.K., Gaines, A.M., (1979). Havasu Canyon, a natural geochemical laboratory. Proceedings of the First Conference on Scientific Research in the National Parks 2, 719726.Google Scholar
Harrison, S.P., Kutzbach, J.E., Liu, Z., Bartlein, P.J., Otto-Bliesner, B., Muhs, D., Prentice, I.C., Thompson, R.S., (2003). Mid-Holocene climates of the Americas: a dynamical response to changed seasonality. Climate Dynamics 20, 663688.CrossRefGoogle Scholar
Hart, R.J., Rihs, J., Taylor, H.E., Monroe, S.A., (2005). Assessment of spring chemistry along the south rim of Grand Canyon in Grand Canyon National Park, Arizona-A U.S.. Geological Survey and National Park Service Partnership. U.S. Geological Survey Fact Sheet 096-02. 4 p.Google Scholar
Hendy, C.H., (1971). The isotopic geochemistry of speleothems–I. The calculation of the effects of different modes of formation on the isotopic composition of speleothems and applicability as palaeoclimate indicators. Geochimica et Cosmochimica Acta 35, 801824.CrossRefGoogle Scholar
Herman, J.S., Lorah, M.M., (1987). CO2 outgassing and calcite precipitation in Falling Springs Creek, Virginia, U.S.A.. Chemical Geology 62, 251262.Google Scholar
Huntoon, P.W., (2000). Variability of karstic permeability between unconfined and confined aquifers, Grand Canyon region, Arizona. Environmental and Engineering Geoscience 6, 155170.CrossRefGoogle Scholar
IAEA/WMO, . Global network for isotopes in precipitation: The GNIP database. Release 3, August 2003.. http://www.iaea.org/programs/ri/gnip/gnipmain.html.Google Scholar
Ihlenfeld, C., Norman, M.D., Gagan, M.K., Drysdale, R.N., Maas, R., Webb, J., (2002). Climatic significance of seasonal trace element and stable isotope variations in a modern freshwater tufa. Geochimica et Cosmochimica Acta 67, 23412357.Google Scholar
Ingraham, N.L., Zukosky, K., Kreamer, D.K., (2001). Application of stable isotopes to identify problems in large-scale water transfer in Grand Canyon National Park. Environmental Science Technology 35, 12991302.CrossRefGoogle ScholarPubMed
Janssen, A., Swennen, R., Podoor, N., Keppens, E., (1999). Biological and diagenetic influence in recent and fossil tufa deposits from Belgium. Sedimentary Geology 126, 7595.Google Scholar
Kano, A., Kawai, T., Matsuoka, J., Ihara, T., (2004). High-resolution records of rainfall events from clay bands in tufa. Geology 32, 793796.CrossRefGoogle Scholar
Kirschner, D.L., Sharp, Z.D., (1996). Oxygen isotope analyses of fine-grained minerals and rocks using the laser-extraction technique. Chemical Geology 37, 109115.Google Scholar
Love, K.C., Chafetz, H.S., (1988). Diagenesis of laminated travertine crusts, Arbuckle Mountains, Oklahoma. Journal of Sedimentary Petrology 58, 441445.Google Scholar
Malusa, J., Overby, S.T., Parnell, R.A., (2003). Potential for travertine formation: fossil Creek, Arizona. Applied Geochemistry 18, 10811093.Google Scholar
Matsuoka, J., Kano, A., Oba, T., Watanabe, T., Seto, K., (2001). Seasonal variation of stable isotopic compositions recorded in a laminated tufa. Earth and Planetary Science Letters 192, 3144.Google Scholar
McCrea, J.M., (1950). On the isotopic chemistry of carbonates and a paleotemperature scale. Journal of Chemical Physics 18, 849857.Google Scholar
Melis, T.S., Phillips, W., Webb, R.H., Bills, D.J., (1996). When the blue-green waters turn red: historical flooding in Havasu Creek, Arizona.. U.S. Geological Survey Open-File Report. WRI 96-4059, 136 p.Google Scholar
Merz-Preiss, M., Riding, R., (1999). Cyanobacterial tufa calcification in two freshwater streams; ambient environment, chemical thresholds and biological processes. Sedimentary Geology 126, 103124.Google Scholar
Monroe, S.A., Antweiler, R.C., Hart, R.J., Taylor, H.E., Truini, M., Rihs, J.R., Felger, T.J., (2005). Chemical characteristics of ground-water discharge along the south rim of the Grand Canyon in Grand Canyon National Park, Arizona, 2000–2001.. U.S. Geological Survey Scientific Investigations Report 2004–5146, 71 p.Google Scholar
Muller, A.B., Mayo, A.L., (1986). 13C variation in limestone on an aquifer-wide scale and its effects on groundwater 14C dating models. Radiocarbon 28, 10411054.Google Scholar
O'Brien, G.R., (2002). Oxygen isotope composition of banded Quaternary travertine, Grand Canyon National Park, Arizona.. Unpublished MS thesis, Department of Geology. Northern Arizona University, Flagstaff, AZ.Google Scholar
Rozanski, K., Araguás-Araguás, L., Gonfiantini, R., (1993). Isotopic patterns in modern global precipitation. Swart, P.K., Lohmann, K.C., McKenzie, J., Savin, S. Climate Change in Continental Isotopic Records. Geophysical Monograph vol. 78, American Geophysical Union, Washington DC.136.Google Scholar
Sharp, Z.D., (2006). Principles of Stable Isotope Geochemistry. Prentice Hall, (500 pp.).Google Scholar
Sharp, Z.D., Cerling, T.E., (1996). A laser GC-IRMS technique for in situ stable isotope analyses of carbonates and phosphates. Geochimica et Cosmochimica Acta 60, 29092916.Google Scholar
Sharp, Z.D., Atudorei, V., Durakiewicz, T., (2001). A rapid method for determination of hydrogen and oxygen isotope ratios from water and hydrous minerals. Chemical Geology 178, 197210.Google Scholar
Sharp, W.D., Ludwig, K.R., Chadwick, O.A., Amundson, R., Glaser, L.L., (2003). Dating fluvial terraces by 230Th on pedogenic carbonate, Wind River Basin, Wyoming. Quaternary Research 59, 139150.Google Scholar
Smith, G., Irving, I., Veronda, G., Johnson, C., (2002). Stable isotope compositions of waters in the Great Basin, United States 3. Comparison of ground waters with modern precipitation. Journal of Geophysical Research 107, 115.Google Scholar
Szabo, B., (1989). Ages of travertine deposits in eastern Grand Canyon National Park, Arizona. Quaternary Research 34, 2432.CrossRefGoogle Scholar
Thompson, R.S., Whitlock, C., Bartlein, P.J., Harrison, S.P., Spaulding, W.G., (1993). Climate changes in the western United States since 18,000 yr B.P.. Wright, H. Global Climates Since The Last Glacial Maximum. University of Minnesota Press, Minneapolis MN.468513.Google Scholar
United States Geological Survey, (2004a). Real time water data.. http://www.water.usgs.gov/realtime.html.Google Scholar
United States Geological Survey, (2004b). Water Quality Samples for Arizona.. http://www.water.usgs.gov/az/nwis/qwdata.Google Scholar
Usdowski, E., Hoefs, J., Menschel, G., (1979). Relationship between 13C and 18O fractionation and changes in major element composition in a recent calcite-depositing spring-A model of chemical variations with inorganic CaCO3 precipitation. Earth and Planetary Science Letters 42, 267276.Google Scholar
Western Regional Climate Center (WRCC), . Arizona climate summaries, Supai, Arizona.. URL: http://www.wrcc.dri.edu/cgi-bin/cliMAIN.pl?azsupa. 2215 Raggio Parkway Reno, Nevada 89512.Google Scholar
Winograd, I.J., Riggs, A.C., Coplen, T.B., (1998). The relative contribution of summer and cool-season precipitation to groundwater recharge, Spring Mountains, Nevada, USA. Hydrogeology Journal 6, 7793.Google Scholar
Zhou, G.T., Zheng, Y.F., (2002). Kinetic mechanism of oxygen isotope disequilibrium in precipitated witherite and aragonite at low temperatures: an experimental study. Geochimica et Cosmochimica Acta 66, 6371.CrossRefGoogle Scholar
Zukosky, K., (1995). An assessment of the potential to use water chemistry parameters to define ground water flow pathways at Grand Canyon National Park, Arizona.. Unpublished MS thesis, Department of Geosciences. University of Nevada, Las Vegas.Google Scholar