Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-17T22:07:09.715Z Has data issue: false hasContentIssue false
  • English
  • Français

Late Pliocene–Quaternary evolution of redox conditions in the western Qaidam paleolake (NE Tibetan Plateau) deduced from Mn geochemistry in the drilling core SG-1

Published online by Cambridge University Press:  20 January 2017

Yibo Yang ,
Xiaomin Fang ,
Erwin Appel ,
Albert Galy ,
Minghui Li  and
Weilin Zhang
Yibo Yang
Affiliation:
Key Laboratory of Continental Collision and Plateau Uplift, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100085, China
Xiaomin Fang*
Affiliation:
Key Laboratory of Continental Collision and Plateau Uplift, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100085, China Key Laboratory of Western China's Environmental Systems, Ministry of Education of China and College of Resources and Environment, Lanzhou University, Lanzhou 730000, China
Erwin Appel
Affiliation:
Department of Geosciences, Center for Applied Geoscience, University of Tübingen, Hölderlinstr. 12, 72074 Töbingen, Germany
Albert Galy
Affiliation:
Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, UK
Minghui Li
Affiliation:
Key Laboratory of Continental Collision and Plateau Uplift, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100085, China
Weilin Zhang
Affiliation:
Key Laboratory of Continental Collision and Plateau Uplift, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100085, China
*
*Corresponding author at: Key Laboratory of Continental Collision and Plateau uplift, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100085, China. Fax: + 86 10 8409 7079. E-mail address:fangxm@itpcas.ac.cn (X. Fang).
Get access Rights & Permissions [Opens in a new window]

Abstract

Manganese (Mn) in lake sediments reacts strongly to changes of redox conditions. This study analyzed Mn concentrations in oxides, carbonates, and bulk phases of the calcareous lacustrine sediments of a 938.5-m-long core (SG-1) taken from the western Qaidam Basin, well dated from 2.77 Ma to 0.1 Ma. Comparisons of extractions from diluted hydrochloric acid, acetic acid and citrate"bicarbonate"dithionite demonstrate that variations of Mn concentrations from acetic acid leaching (MnHOAc) are mostly responsible for Mn (II) fluctuations in the carbonate phase. Taking into account the relevant processes during weathering, transportation, deposition and post-deposition of Mn-bearing rocks, we conclude that Mn input from catchment weathering and paleolake redox condition provide the primary controls on variations in the Mn records of carbonate and oxide phases. We propose MnHOAc as a new sensitive indicator of paleolake redox evolution and catchment-scale climate change. The MnHOAc variations show a long-term upward decreasing trend, indicating a long-term decrease of Mn input from catchment weathering associated with increasing oxygen content in the paleolake bottom water. The great similarities of the MnHOAc record with other regional and global records suggest that paleolake redox changes and climatic drying in the Qaidam Basin may be largely related to global cooling.

Keywords

Late Pliocene–QuaternaryQaidam BasinManganese geochemistryLake redox conditionsAsian inland drying
Type
Original Articles
Information
Quaternary Research , Volume 80 , Issue 3 , November 2013 , pp. 586 - 595
Copyright
University of Washington

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Algeo, T.J., Maynard, J.B., (2004). Trace-element behavior and redox facies in core shales of Upper Pennsylvanian Kansas-type cyclothems. Chemical Geology 206, 289–318.Google Scholar
Barnaby, R.J., Rimstidt, J.D., (1989). Redox conditions of calcite cementation interpreted from Mn-contents and Fe-contents of authigenic calcites. Geological Society of America Bulletin 101, 795–804.Google Scholar
Brand, U., Veizer, J., (1980). Chemical diagenesis of a multicomponent carbonate system-1: trace elements. Journal of Sedimentary Research 50, 1219–1236.Google Scholar
Burns, R.G., Burns, V.M., (1979). Manganese oxides. Burns, R.G. Marine Minerals. Reviews in Mineralogy vol. 6, Mineralogy Society of America, Washington, DC.(1–46. pp.).Google Scholar
Cai, M., Fang, X., Wu, F., Miao, Y., Appel, E., (2012). Pliocene–Pleistocene stepwise drying of Central Asia: evidence from paleomagnetism and sporopollen record of the deep borehole SG-3 in the western Qaidam Basin, NE Tibetan Plateau. Global and Planetary Change 94–95, 72–81.Google Scholar
Calvert, S.E., Pedersen, T.F., (1993). Geochemistry of recent oxic and anoxic sediments: implications for the geological record. Marine Geology 113, 67–88.Google Scholar
Caplan, M.L., Bustin, R.M., (1999). Devonian–Carboniferous Hangenberg mass extinction event, widespread organic-rich mudrocks and anoxia: causes and consequences. Palaeogeography Palaeoclimatology Palaeoecology 149, 187–207.Google Scholar
Chen, K., Bowler, J.M., (1986). Late Pleistocene evolution of salt lakes in the Qaidam Basin, Qinghai Province, China. Palaeogeography Palaeoclimatology Palaeoecology 54, 87–104.Google Scholar
Chen, L.X., Zhu, Q.G., Luo, H.B., He, J.H., Dong, M., Feng, Z.Q., (1991). The East Asian Monsoon. Meteorological Press, Beijing.(362 pp. (in Chinese)).Google Scholar
Chen, W.P., Chen, C.Y., Na'belek, J.L., (1999). Present-day deformation of the Qaidam Basin with implications for intra-continental tectonics. Tectonophysics 305, 165–181.Google Scholar
Chester, R., Hughes, M.J., (1967). A chemical technique for the separation of ferro-manganese minerals, carbonate minerals and adsorbed trace elements from pelagic sediments. Chemical Geology 2, 249–262.Google Scholar
Davison, W., (1993). Iron and manganese in lakes. Earth-Science Reviews 34, 119–163.Google Scholar
De Vitre, R., Davison, W., (1993). Manganese particles in freshwater. van Leeuwen, H.P., Buffle, J. Environmental Particles vol. 2, Lewis, Boca Raton.317–352.Google Scholar
Dean, W.E., (1999). The carbon cycle and biogeochemical dynamics in lake sediments. Journal of Paleolimnology 21, 375–393.Google Scholar
Dean, W.E., Moore, W.S., Nealson, K.H., (1981). Manganese cycles and the origin of manganese nodules, Oneida Lake, New-York, USA. Chemical Geology 34, 53–64.Google Scholar
Ding, Y.H., (1991). Advanced synoptic meteorology. Meteorological Press, Beijing.(792 pp. (in Chinese)).Google Scholar
Ding, Z.L., Derbyshire, E., Yang, S.L., Sun, J.M., Liu, T.S., (2005). Stepwise expansion of desert environment across northern China in the past 3.5 Ma and implications for monsoon evolution. Earth and Planetary Science Letters 237, 45–55.Google Scholar
Fang, X.M., Li, J.J., Van der Voo, R., (1999). Rock magnetic and grain size evidence for intensified Asian atmospheric circulation since 800,000 yrs B.P. related to Tibetan uplift. Earth and Planetary Science Letters 165, 129–144.Google Scholar
Fang, X.M., Zhang, W.L., Meng, Q.Q., Gao, J.P., Wang, X.M., King, J., Song, C.H., Dai, S., Miao, Y.F., (2007). High-resolution magnetostratigraphy of the Neogene Huaitoutala section in the eastern Qaidam Basin on the NE Tibetan Plateau, Qinghai Province, China and its implication on tectonic uplift of the NE Tibetan Plateau. Earth and Planetary Science Letters 258, 293–306.Google Scholar
Gourlan, A.T., Meynadier, L., Allegre, C.J., Tapponnier, P., Birck, J.L., Joron, J.L., (2010). Northern Hemisphere climate control of the Bengali rivers discharge during the past 4 Ma. Quaternary Science Reviews 29, 2484–2498.Google Scholar
Graham, S.A., Chamberlain, C.P., Yue, Y., Ritts, B.D., Hanson, A.D., Horton, T.W., Waldbauer, J.R., Poage, M.A., (2005). Stable isotope records of Cenozoic climate and topography, Tibetan Plateau and Tarim Basin. American Journal of Science 305, 101–118.Google Scholar
Hamilton-Taylor, J., Davison, W., (1995). Redox-driven cycling of trace elements in lakes. Lerman, A., Imboden, D.M., Gat, J.R. Physics and chemistry of lakes. Springer-Verlag, Berlin.217–263.Google Scholar
Hanson, A.D., (1999). Organic geochemistry and petroleum geology, tectonics, and basin analysis of southern Tarim and northern Qaidam, northwest China. (Ph.D. thesis)Stanford University, .Google Scholar
Hild, E., Brumsack, H.J., (1998). Major and minor element geochemistry of Lower Aptian sediments from the NW German Basin (core Hoheneggelsen KB 40). Cretaceous Research 19, 615–633.Google Scholar
Huang, H.C., Huang, Q.H., Ma, Y.S., (1996). Geology of Qaidam and petroleum prediction. Geological Publishing House, Beijing.(257 pp. (in Chinese)).Google Scholar
Huckriede, H., Meischner, D., (1996). Origin and environment of manganese-rich sediments within black shale deeps. Geochimica et Cosmochimica Acta 60, 1399–1413.Google Scholar
Huerta-Diaz, M.A., Morse, J.W., (1992). Pyritisation of trace metals in anoxic marine sediments. Geochimica et Cosmochimica Acta 56, 2681–2702.Google Scholar
Jin, Z., You, C.-F., Wang, Y., Shi, Y., (2010). Hydrological and solute budgets of Lake Qinghai, the largest lake on the Tibetan Plateau. Quaternary International 218, 151–156.Google Scholar
Kapp, P., Pelletier, J.D., Rohrmann, A., Heermance, R., Russel, J., Ding, L., (2011). Wind erosion in the Qaidam basin, central Asia: implications for tectonic, paleoclimate, and the source of Loess Plateau. GSA Today 21, 10.1130/GSATG99A.1.CrossRefGoogle Scholar
Kent-Corson, M.L., Ritts, B.D., Zhuang, G.S., Bovet, P.M., Graham, S.A., Chamberlain, C.P., (2009). Stable isotopic constraints on the tectonic, topographic, and climatic evolution of the northern margin of the Tibetan Plateau. Earth and Planetary Science Letters 282, 158–166.Google Scholar
Lawrence, K.T., Herbert, T.D., Brown, C.M., Raymo, M.E., Haywood, A.M., (2009). High-amplitude variations in North Atlantic sea surface temperature during the early Pliocene warm period. Paleoceanography 24, PA2218 10.1029/2008PA001669.Google Scholar
Li, C.L., Kang, S.C., Zhang, Q.G., Wang, F.Y., (2009). Rare earth elements in the surface sediments of the Yarlung Tsangbo (Upper Brahmaputra River) sediments, southern Tibetan Plateau. Quaternary International 208, 151–157.CrossRefGoogle Scholar
Li, M.H., Fang, X.M., Yi, C.L., Gao, S.P., Zhang, W.L., Galy, A., (2010). Evaporite minerals and geochemistry of the upper 400 m sediments in a core from the Western Qaidam Basin, Tibet. Quaternary International 218, 176–189.Google Scholar
LIGCAS (Lanzhou Institute of Geology of Chinese Academy of Sciences), . ((Lanzhou Institute of Geology of Chinese Academy of Sciences), 1994). Evolution of Recent Environment in Qinghai Lake and its Prediction. Science Press, Beijing.(in Chinese).Google Scholar
Lisiecki, L.E., Raymo, M.E., (2005). A Pliocene–Pleistocene stack of 57 globally distributed benthic δ18O records. Paleoceanography 20, PA1003 10.1029/2005PA001164.Google Scholar
Lowenstein, T.K., Risacher, F., (2009). Closed basin brine evolution and the influence of Ca–Cl inflow waters: Death Valley and Bristol Dry Lake California, Qaidam Basin, China, and Salar de Atacama, Chile. Aquatic Geochemistry 15, 71–94.Google Scholar
Maynard, J.B., (2004). Manganiferous sediments, rocks, and ores. Holland, H.D., Turekian, K.K. Treatise on Geochemistry volume 7, (289–308. pp.).Google Scholar
Mehra, O.P., Jackson, M.L., (1960). Iron oxide removal from soils and clays by a dithionite–citrate -system buffered with sodium bicarbonate. Clays and Clay Minerals 3, 317–327.Google Scholar
Moore, C.D., Pape, I., Tanner, B.K., (1997). Triple-axis X-ray diffraction study of polishing damage in III–V semiconductors. Nuovo Cimento Della Societa Italiana Di Fisica D-Condensed Matter Atomic Molecular and Chemical Physics Fluids Plasmas Biophysics 19, 205–212.Google Scholar
Neumann, T., Christiansen, C., Clasen, S., Emeis, K.C., Kunzendorf, H., (1997). Geochemical records of salt-water inflows into the deeps of the Baltic Sea. Continental Shelf Research 17, 95–115.Google Scholar
Nuhfer, E.B., Anderson, R.Y., Bradbury, J.P., Dean, W.E., (1993). Modern sedimentation in Elk Lake, Clearwater County, Minnesota. Bradbury, J.P., Dean, W.E. Elk Lake, Minnesota: Evidence for Rapid Climate Change in the North-Central United States, Special Paper 276. Geological Society America, Boulder.(75–96. pp.).Google Scholar
Peltzer, G., Tapponier, P., Armijo, R., (1989). Magnitude of late quaternary left-lateral displacements along the north edge of Tibet. Science 246, 1285–1289.Google Scholar
Porter, S.C., An, Z.S., (1995). Correlation between climate events in the North Atlantic and China during the last glaciation. Nature 375, 305–308.Google Scholar
Pullen, A., Kapp, P., McCallister, A.T., Chang, H., Gehrels, G.E., Garzione, C.N., Heermance, R.V., Ding, L., (2011). Qaidam Basin and northern Tibetan Plateau as dust sources for the Chinese Loess Plateau and paleoclimatic implications. Geology 39, 1031–1034.CrossRefGoogle Scholar
Qiang, M., Lang, L., Wang, Z., (2010). Do fine-grained components of loess indicate westerlies: insights from observations of dust storm deposits at Lenghu (Qaidam Basin, China). Journal of Arid Environments 74, 1232–1239.CrossRefGoogle Scholar
Regional Geology and Mineral Resources Geological Division of Ministry of Geology and Mineral Resources. RGMRGD, Compilation on the Geology of Manganese Deposit in China, Geological Publishing House, Beijing.(1–11. pp. (in Chinese)).Google Scholar
Rimstidt, J.D., Balog, A., Webb, J., (1998). Distribution of trace elements between carbonate minerals and aqueous solutions. Geochimica et Cosmochimica Acta 62, 1851–1863.Google Scholar
Ruttenberg, K.C., (1992). Development of a sequential extraction method for different forms of phosphorus in marine sediments. Limnology and Oceanography 37, 1460–1482.CrossRefGoogle Scholar
Schaller, T., Wehrli, B., (1997). Geochemical-focusing of manganese in lake sediments–an indicator of deep-water oxygen conditions. Aquatic Geochemistry 2, 359–378.CrossRefGoogle Scholar
Stevens, L.R., Ito, E., Olson, D.E.L., (2000). Relationship of Mn-carbonates in varved lake-sediments to catchment vegetation in Big Watab Lake, MN, USA. Journal of Paleolimnology 24, 199–211.CrossRefGoogle Scholar
Sun, J.M., (2002). Provenance of loess material and formation of loess deposits on the Chinese Loess Plateau. Earth and Planetary Science Letters 203, 845–859.CrossRefGoogle Scholar
Sun, Y.B., An, Z.S., (2005). Late Pliocene–Pleistocene changes in mass accumulation rates of eolian deposits on the central Chinese Loess Plateau. Journal of Geophysical Research-Atmospheres 110, D23101 10.1029/2005JD006064.Google Scholar
Taylor, S.R., McLennan, S.M., (1985). The Continental Crust: its Composition and Evolution. Blackwell Scientific Publications, Oxford.Google Scholar
Tribovillard, N., Algeo, T.J., Lyons, T., Riboulleau, A., (2006). Trace metals as paleoredox and paleoproductivity proxies: an update. Chemical Geology 232, 12–32.Google Scholar
Tuo, J.C., Philp, R.P., (2003). Occurrence and distribution of high molecular weight hydrocarbons in selected non-marine source rocks from the Liaohe, Qaidam and Tarim Basins, China. Organic Geochemistry 34, 1543–1558.Google Scholar
Van der Zee, C., Van Raaphorst, W., (2004). Manganese oxide reactivity in North Sea sediments. Journal of Sea Research 52, 73–85.Google Scholar
Wang, Q., Coward, M.P., (1990). The Chaidam Basin (NW China): formation and hydrocarbon potential. Journal of Petroleum Geology 13, 93–112.Google Scholar
Wang, C.N., Guo, X.H., Ma, M.Z., Li, J.D., Li, J., (2008). Ore-forming geological background of K–Mg Salt in Qarhan Salt Lake. Northwestern Geology 41, 1 97–106.(in Chinese).Google Scholar
Wang, J.Y., Fang, X., Appel, E., Song, C., (2012). Pliocene–Pleistocene climate change at the NE Tibetan Plateau deduced from lithofacies variation in the drilling core SG-1, western Qaidam Basin. Journal of Sedimentary Research 82, 933–952.Google Scholar
Wetzel, R.G., (2001). Limnology: Lake and River Ecosystems. 3rd ed.Academic Press, San Diego.289–305.Google Scholar
Xia, W.C., Zhang, N., Yuan, X.P., Fan, L.S., Zhang, B.S., (2001). Cenozoic Qaidam Basin, China: a stronger tectonic inversed, extensional rifted basin. American Association of Petroleum Geologists Bulletin 85, 715–736.Google Scholar
Xuan, Z., (1995). Basic characteristic of potassium and magnesium solid deposit in Kunteyi and Mahai salt lake of Qinghai province. Journal of Salt Lake Sciences 3, 1–9.(in Chinese).Google Scholar
Yang, J.D., Chen, J., An, Z.S., Shields, G., Tao, X.C., Zhu, H.B., Ji, J.F., Chen, Y., (2000). Variations in 87Sr/86Sr ratios of calcites in Chinese loess: a proxy for chemical weathering associated with the East Asian summer monsoon. Palaeogeography Palaeoclimatology Palaeoecology 157, 151–159.Google Scholar
Yuan, J., Yang, Q., Sun, D., Huo, C., Cai, K., Wang, W., Liu, X., (1995). The Formation Conditions of the Potash Deposits in Charhan Saline Lake, Caidamu Basin, China. Geological Publishing House, Beijing.(23–50. pp. (in Chinese)).Google Scholar
Zhang, P.X., (1987). Saline Lakes in Qaidam Basin. Science Press, Beijing.(1–25. pp. (in Chinese)).Google Scholar
Zhang, W., Appel, E., Fang, X., Song, C., (2012a). Magnetostratigraphy of Deep Drilling Core SG-1 in the Western Qaidam Basin (NE Tibetan Plateau) and its Tectonic Implications. Quaternary Research 10.1016/j.yqres.2012.03.011.CrossRefGoogle Scholar
Zhang, W., Appel, E., Fang, X., Yan, M., Song, C., Cao, L., (2012b). Paleoclimatic implications of magnetic susceptibility in Late Pliocene–Quaternary sediments from deep drilling core SG-1 in the western Qaidam Basin (NE Tibetan Plateau). Journal of Geophysical Research 17, B6 10.1029/2011JB008949.Google Scholar