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Spectroscopic properties ofMO-WO3-P2O5: Ho3+ glasses

Published online by Cambridge University Press:  11 May 2004

P. Subbalakshmi
Affiliation:
Department of Physics, Nagarjuna University P.G. Centre, Nuzvid – 521 201, India
B. V. Raghavaiah
Affiliation:
Department of Physics, Nagarjuna University P.G. Centre, Nuzvid – 521 201, India
R. Balaji Rao
Affiliation:
Department of Physics, Nagarjuna University P.G. Centre, Nuzvid – 521 201, India
N. Veeraiah*
Affiliation:
Department of Physics, Nagarjuna University P.G. Centre, Nuzvid – 521 201, India
P. Babu
Affiliation:
Department of Physics, Sri Venkateswara University, Tirupati – 517 502, India
C. K. Jayasankar
Affiliation:
Department of Physics, Sri Venkateswara University, Tirupati – 517 502, India
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Abstract

ESR, IR, optical absorption and photoluminescence spectra of Ho3+ doped tungsten phosphate glasses modified with three different modifier oxides viz., PbO, ZnO and CaO have been studied. The ESR spectral studies indicate tungsten ions are present in W5+ state in all the three glasses with the highest concentration in CaO modified glasses. From the measured intensities of various absorption bands of these glasses, the Judd-Ofelt (JO) parameters $\Omega_2$, $\Omega_4$ and $\Omega_6$ have been evaluated. The JO theory could successfully be applied to characterise the absorption and luminescence spectra of these glasses. From this theory various radiative properties like radiative transition probabilities, A, branching ratios, $\beta_r$, the radiative lifetimes, $\tau_R$, and the emission cross-sections, σE, for various emission levels of Ho3+ in these glasses have been determined and reported. An attempt has also been made to throw some light on the environment of Ho3+ ions in all the three glasses.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2004

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