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On the melting of polyhedral elemental nanosolids

Published online by Cambridge University Press:  30 August 2004

M. Wautelet*
Affiliation:
Université de Mons-Hainaut, 23 avenue Maistriau, 7000 Mons, Belgium
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Abstract

The phase diagram of nanoparticles is known to be a function of their size. Since this dependence is also a function of the surface to volume ratio and of the surface tensions, it is expected that it varies with the shape of the nanoparticles. The variation of the melting temperature of polyhedral elemental nanosolids is studied theoretically. It turns out that, in most cases, the size variation of the melting temperature of a sphere is less than for the other shapes. However, there is no general rule regarding the order of the shape parameters of the polyhedra.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2005

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References

Ph. Buffat, J.-P. Borel, Phys. Rev. A 13, 2287 (1976) CrossRef
Damodara Da, V.s, D. Karunakaran, J. Appl. Phys. 68, 2105 (1990)
Allen, G.L., Bayles, R.A., Gile, W.W., Jesser, W.A., Thin Solid Films 144, 297 (1986) CrossRef
Sheng, H.W., Xu, J., Yu, L.G., Sun, X.K., Hu, Z.Q., Lu, K., J. Mater. Res. 11, 2841 (1996) CrossRef
Radloff, C., Halas, N.J., Appl. Phys. Lett. 79, 674 (2001) CrossRef
Pawlow, P., Z. Phys. Chem. 65, 1 (1909) CrossRef
Couchman, P.R., Ryan, C.L., Philos. Mag. A 37, 369 (1978) CrossRef
Hoshino, K., Shimanura, S., Philos. Mag. A 40, 137 (1979) CrossRef
Wautelet, M., J. Phys. D: Appl. Phys. 24, 343 (1991) CrossRef
Vanfleet, R.R., Mochel, J.M., Surf. Sci. 341, 40 (1995) CrossRef
Nanda, K.K., Sahu, S.N., Behera, S.N., Phys. Rev. A 66, 013208 (2002) CrossRef
Sun, C.Q., Tay, B.K., Zeng, X.T., Li, S., Chen, T.P., Zhou, J.I., Bai, H.L., Jiang, E.Y., J. Phys.-Cond. Matter 14, 7781 (2002) CrossRef
Celestini, F., Ten Bosch, A., Phys. Lett. A 207, 307 (1995) CrossRef
Wautelet, M., Phys. Lett. A 246, 341 (1998) CrossRef
Wautelet, M., Nanotechnology 3, 42 (1992) CrossRef
Zhao, M., Zhou, X.H., Jiang, Q., J. Mater. Res. 16, 3304 (2001) CrossRef
Wautelet, M., Dauchot, J.P., Hecq, M., J. Phys.-Cond. Matter 15, 3651 (2003) CrossRef
Link, S., Burda, C., Nikoobakht, B., El-Sayed, M.A., J. Phys. Chem. B 104, 6152 (2000) CrossRef
Bozon-Verduraz, F., Brayner, R., Voronov, V.V., Kirichenko, N.A., Simakin, A.V., Shafeev, G.A., Quant. Electron. 33, 714 (2003) CrossRef
Yacaman, M.J., Ascencio, J.A., Liu, H.B., Gardea-Torresdey, J., J. Vac. Sci. Technol. B 19, 1091 (2001)
Jiang, Q., Lu, H.M., Zhao, M., J. Phys.-Cond. Matter 16, 521 (2004) CrossRef
M.C. Desjonquières, D. Spanjaard, Concepts in Surface Science (Springer-Verlag, Berlin, 1993)
K.L. Chopra, Thin Film Phenomena, (McGraw Hill, New York, 1969)
Vitos, L., Ruban, A.V., Skriver, H.L., Kollàr, J., Surf. Sci. 411, 186 (1998) CrossRef
R.C. Weast (Ed.), CRC Handbook of Chemistry and Physics, 67th edn. (CRC Press, Boca Raton, Florida, 1987)