Hostname: page-component-5c6d5d7d68-ckgrl Total loading time: 0 Render date: 2024-08-09T01:21:32.477Z Has data issue: false hasContentIssue false

Breakdown and Movement of 2,4-D in the Soil Under Field Conditions

Published online by Cambridge University Press:  12 June 2017

R. G. Wilson Jr.
Affiliation:
Dep. Agron. and Soils, Washington State Univ., Pullman, WA 99163
H. H. Cheng
Affiliation:
Dep. Agron. and Soils, Washington State Univ., Pullman, WA 99163

Abstract

The fate of 2,4-D [(2,4-dichlorophenoxy)acetic acid] in the soil under winter wheat (Triticum aestivum L. ‘Nugaines’) and fallow cropping schemes was studied under the field conditions of eastern Washington in 1973 and 1974 using formulated dimethylamine salt and isooctyl ester of 2,4-D. Soil samples taken 1 hour after herbicide application showed that amine-treated plots retained considerably more applied 2,4-D than ester-treated plots. The rapidity of 2,4-D breakdown decreased gradually with time, and at the end of 6 months, an average of 0.04 ppm of 2,4-D remained in the sampled soil profile regardless of formulation, application rate, or cropping scheme. Loss of 2,4-D from the soil surface in runoff occurred when the plots were irrigated heavily one day after the herbicide application. The herbicide was also leached into the soil profile by both irrigation and natural precipitation. Herbicide concentrations in the sampled portion of the upper soil profile decreased during the summer and then increased slightly in the fall.

Type
Research Article
Copyright
Copyright © 1976 by the Weed Science Society of America 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature Cited

1. Barnett, A.P., Hauser, E.W., White, A.W., and Holladay, J.H. 1967. Loss of 2,4-D in washoff from cultivated fallow land. Weeds 15:133137.Google Scholar
2. Crafts, A.S. 1949. Toxicity of 2,4-D in California soils. Hilgardia 19:141157.Google Scholar
3. Day, B.E., Jordan, L.S., and Russell, R.C. 1963. Volatility of formulations of 2,4-D under field conditions. Res. Prog. Rept. West. Weed Control Conf., p. 8081.Google Scholar
4. Gellerman, J.L. and Schlenk, H. 1960. Esterification of fatty acid with diazomethane on a small scale. Anal. Chem. 32:14121417.Google Scholar
5. Grover, R., Maybank, J., and Yoshida, K. 1972. Droplet and vapor drift from butyl ester and dimethylamine salt of 2,4-D. Weed Sci. 20:320324.Google Scholar
6. Hernandez, T.P. and Warren, G.F. 1950. Some factors affecting the rate of inactivation and leaching of 2,4-D in different soils. Proc. Am. Soc. Hortic. Sci. 56:287293.Google Scholar
7. Jorgensen, C.J. and Hamner, C.L. 1948. Weed control in soils with 2,4-dichlorophenoxyacetic acid and related compounds and their residual effects under varying environmental conditions. Bot. Gaz. 110:324333.Google Scholar
8. Lavy, T.L., Roeth, F.W., and Fenster, C.R. 1973. Degradation of 2,4-D and atrazine at three soil depths in the field. J. Environ. Qual. 2:132137.CrossRefGoogle Scholar
9. Newman, A.S., Thomas, J.R., and Walker, R.L. 1952. Disappearance of 2,4-dichlorophenoxyacetic acid and 2,4,5-trichlorophenoxyacetic acid from soil. Soil Sci. Soc. Am. Proc. 16:2124.Google Scholar
10. Vernetti, J.B. and Freed, V.H. 1963. Vapor losses of thiolcarbamates and 2,4-D esters from soil as a function of vapor pressure. Res. Prog. Rept. West. Weed Control Conf. p. 8283.Google Scholar
11. Wiese, A.F. and Davis, R.G. 1964. Herbicide movement in soil with various amounts of water. Weeds 12:101103.Google Scholar