Hostname: page-component-848d4c4894-x24gv Total loading time: 0 Render date: 2024-05-18T09:02:29.329Z Has data issue: false hasContentIssue false

Synthesis and characterization of nano-silica from locally available laterite clay

Published online by Cambridge University Press:  12 March 2024

Safeena Khattak
Affiliation:
Department of Chemistry, Abdul Wali Khan University, Mardan, Pakistan
Saeed Gul
Affiliation:
Department of Chemical Engineering, University of Engineering and Technology, Peshawar, Pakistan
Sabiha Sultana
Affiliation:
Department of Chemistry, Islamia College University, Peshawar, Pakistan University of Exeter, Penryn Campus, Penryn, UK
Noor-ul-Amin*
Affiliation:
Department of Chemistry, Abdul Wali Khan University, Mardan, Pakistan
*
Corresponding author: Noor-ul-Amin; Email: noorulamin@awkum.edu.pk

Abstract

The synthesis of nano-silica is gaining the attention of researchers due to its numerous applications in various fields such as medicine, the food industry, catalysis, agriculture and construction, amongst others, because of its unique physicochemical features. However, achieving its facile synthesis and finding inexpensive source material that is locally available requires further exploration for its large-scale production. This paper reports the synthesis and characterization of nano-silica from locally available laterite clay using the sol-gel method. The product was analysed using X-ray florescence, X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy. It was observed that the product was spherical, agglomerated and amorphous in nature. The obtained nano-silica was found to have 97% and 95% purity for sodium hydroxide and potassium hydroxide, respectively. The synthesized nano-silica is expected to play pivotal role as a pozzolanic activator in the construction industry.

Type
Article
Copyright
Copyright © The Author(s), 2024. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Chunhui Zhou

References

Amin, N., Khattak, S., Noor, S. & Ferroze, I. (2016) Synthesis and characterization of silica from bottom ash of sugar industry. Journal of Cleaner Production, 117, 207211.CrossRefGoogle Scholar
Ghorbani, F., Younesi, H., Mehraban, Z., Çelik, M.S., Ghoreyshi, A.A. & Anbia, M. (2013) Preparation and characterization of highly pure silica from sedge as agricultural waste and its utilization in the synthesis of mesoporous silica MCM-41. Journal of the Taiwan Institute of Chemical Engineers, 44, 821828.CrossRefGoogle Scholar
Gu, S., Zhou, J., Yu, C., Luo, Z., Wang, Q. & Shi, Z. (2015) A novel two-staged thermal synthesis method of generating nanosilica from rice husk via pre-pyrolysis combined with calcination. Industrial Crops and Products, 65, 16.CrossRefGoogle Scholar
Heikal, M. (2016) Characteristics, textural properties and fire resistance of cement pastes containing Fe2O3 nano-particles. Journal of Thermal Analysis and Calorimetry, 126, 10771087.CrossRefGoogle Scholar
Heikal, M., Ismail, M.N. & Ibrahim, N.S. (2015) Physico-mechanical, microstructure characteristics and fire resistance of cement pastes containing Al2O3 nanoparticles. Construction and Building Materials, 91, 232242.CrossRefGoogle Scholar
Jafarzadeh, M., Rahman, I. & Sipaut, C. (2009) Synthesis of silica nanoparticles by modified sol-gel process: the effect of mixing modes of the reactants and drying techniques. Journal of Sol-Gel Science and Technology, 50, 328336.CrossRefGoogle Scholar
Kanchanason, V. & Plank, J. (2017) Role of pH on the structure, composition and morphology of C-S-H–PCE nanocomposites and their effect on early strength development of Portland cement. Cement and Concrete Research, 102, 9098.CrossRefGoogle Scholar
Luo, K., Li, J., Lu, Z. Jiang, J. & Niu, Y. (2019) Effect of nano-SiO2 on early hydration of natural hydraulic lime. Construction and Building Material, 216, 119127.CrossRefGoogle Scholar
Meng, T., Qiang, Y., Hu, A., Xu, C. & Lin, L. (2017) Effect of compound nano-CaCO3 addition on strength development and microstructure of cement-stabilized soil in the marine environment. Construction and Building Material, 151, 775781.CrossRefGoogle Scholar
Norsuraya, S., Fazlena, H. & Norhasyimi, R. (2016) Sugarcane bagasse as a renewable source of silica to synthesize Santa Barbara Amorphous-15 (SBA-15). Procedia Engineering, 148, 839846.CrossRefGoogle Scholar
Paya, J., Monzo, J., Borrachero, M.V., Mellado, A. & Ordonez, L.M. (2001) Determination of amorphous silica in rice husk ash by a rapid analytical method. Cement and Concrete Research, 31, 227231.CrossRefGoogle Scholar
She, W., Du, Y., Miao, C., Liu, J., Zhao, G., Jiang, J. & Zhang, Y. (2018) Application of organicand nanoparticle-modified foams in foamed concrete: reinforcement and stabilization mechanisms. Cement and Concrete Research, 106, 1222.CrossRefGoogle Scholar
Sikora, P., Elrahman, M.A., Chung, S.Y., Cendrowski, K., Mijowska, E. & Stephan, D. (2019) Mechanical and microstructu]ral properties of cement pastes containing carbon nanotubes and carbon nanotube–silica core–shell structures, exposed to elevated temperature. Cement and Concrete Research, 95, 193204.CrossRefGoogle Scholar
Singh, N.B., Kalra, M. & Saxena, S.K. (2017) Nanoscience of cement and concrete. Materials Today: Proceedings, 4, 54785487.Google Scholar
Sun, W., Zeng, Q. & Yu, A. (2013) Calculation of noncontact forces between silica nanospheres. Langmuir, 29, 21752184.CrossRefGoogle ScholarPubMed
Tang, Z., Zhang, L., Feng, W., Guo, B., Liu, F. & Jia, D. (2014) Rational design of graphene surface chemistry for high-performance rubber/graphene composites. Macromolecules, 47, 86638673.CrossRefGoogle Scholar
Tang, Z., Zhang, C., Wei, Q., Weng, P. & Guo, B. (2016) Remarkably improving performance of carbon black-filled rubber composites by incorporating MoS2 nanoplatelets. Composites Science and Technology, 132, 93100.CrossRefGoogle Scholar
Velmurugan, P., Shim, J., Lee, K.J., Cho, M., Lim, S.S., Seo, S.K. et al. (2015) Extraction, characterization, and catalytic potential of amorphous silica from corn cobs by sol-gel method. Journal of Industrial and Engineering Chemistry, 29, 298303.CrossRefGoogle Scholar
Wang, X.D., Shen, Z.X., Sang, T., Cheng, X.B., Li, M.F., Chen, L.Y. & Wang, Z.S. (2010) Preparation of spherical silica particles by Stöber process with high concentration of tetra-ethyl-orthosilicate. Journal of Colloid and Interface Science, 341, 2329.CrossRefGoogle ScholarPubMed
Wassie, A.B. & Srivastava, V.C. (2017) Synthesis and characterization of nano-silica from teff straw. Journal of Nano Research, 46, 6472.CrossRefGoogle Scholar
Yuvakkumar, R., Elango, V., Rajendran, V. & Kannan, N. (2014) High-purity nano-silica powder from rice husk using a simple chemical method. Journal of Experimental Nanoscience, 9, 272281.CrossRefGoogle Scholar
Zhang, X., Luo, S., Wu, X., Feng, M., Li, Y., Han, H. & Li, W. (2021) Effect of alkali bases on the synthesis of ZnO quantum dots. Open Chemistry Journal, 19, 377384.CrossRefGoogle Scholar