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Influence of dealloying solution on the microstructure of nanoporous copper through chemical dealloying of Al75Cu25 ribbons

Published online by Cambridge University Press:  20 April 2020

Hailan Ma ,
Bingge Zhao Open the ORCID record for Bingge Zhao [Opens in a new window] ,
Kai Ding ,
Yuanheng Zhang ,
Guanzhi Wu  and
Yulai Gao Open the ORCID record for Yulai Gao [Opens in a new window]
Hailan Ma
Affiliation:
Center for Advanced Solidification Technology (CAST), School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Bingge Zhao*
Affiliation:
Center for Advanced Solidification Technology (CAST), School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Kai Ding
Affiliation:
Center for Advanced Solidification Technology (CAST), School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Yuanheng Zhang
Affiliation:
Center for Advanced Solidification Technology (CAST), School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Guanzhi Wu
Affiliation:
Center for Advanced Solidification Technology (CAST), School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Yulai Gao*
Affiliation:
Center for Advanced Solidification Technology (CAST), School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People's Republic of China
*
a)Address all correspondence to these authors. e-mail: binggezhao@shu.edu.cn
b)e-mail: ylgao@shu.edu.cn
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Abstract

In this article, Al75Cu25 (at.%) ribbons were dealloyed by HCl, H2C2O4, H3PO4, and NaOH solutions, respectively, to prepare nanoporous copper (NPC). The dealloying behavior is varied with dealloying solutions, allowing modulating the microstructure and porosity of the NPC. Al75Cu25 ribbons are fully dealloyed in HCl, H2C2O4, and NaOH solutions, whereas they are partially dealloyed in H3PO4 solution. Except the NPC prepared in the NaOH solution, no obvious cracks are traced in other samples. The surface diffusivity (Ds) of Cu atoms along the alloy/solution interfaces is varied with solutions, producing the NPC with different microstructure. NPC with higher specific surface area can be obtained by dealloying the Al75Cu25 ribbons in the HCl solution. Compared with the dealloying in H2C2O4, H3PO4, and NaOH solutions, the dealloying in 10 wt% HCl solution for 25 min at 90 ± 1 °C facilitates the best NPC in this work.

Keywords

Alalloyporosity
Type
Article
Information
Journal of Materials Research , Volume 35 , Issue 19: Focus Issue: Porous Metals: From Nano to Macro , 14 October 2020 , pp. 2610 - 2619
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Copyright
Copyright © Materials Research Society 2020

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