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9 - Quantum electrodynamics, angular momentum and chirality

Published online by Cambridge University Press:  05 December 2012

David L. Andrews
Affiliation:
School of Chemistry
Mohamed Babiker
Affiliation:
University of York
David L. Andrews
Affiliation:
University of East Anglia
Mohamed Babiker
Affiliation:
University of York
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Summary

Introduction

When light engages with matter, the interactions that take place at the photon level are subject to the operation of powerful underlying symmetry laws. Such principles underpin the physics of even the simplest photon interactions, as for instance in the familiar Planck- Einstein relation E = for the absorption or emission of radiation. As emerged from Noether's work [1], this manifestation of overall conservation of energy is a direct consequence of a system invariance under temporal translation [2]. In connection with specific atomic photophysics, the term ‘selection rule’ is often used in connection with other space or time symmetries, these frequently being manifest as constraints over the conservation of quantized angular momentum. Obvious examples are the rules that govern the ‘allowed’ and ‘forbidden’ lines in atomic spectra, where the associated conditions over the geometric disposition and flow of charge emerge in the form of transition multipoles [3, 4].

The angular momentum attributes of light are most familiar in connection with the integer spin of the photon. Circularly polarized states have well-defined spin angular momentum along the direction of propagation [5], and numerous chiral or gyrotropic interactions exploit the differences in behaviour – observed in a material that is itself chirally constituted – between light beams of left- and right-handedness [6–8]. The principles are well known, and their applications have a surprisingly wide compass.

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Publisher: Cambridge University Press
Print publication year: 2012

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References

[1] E., Noether, Invariante Variationsprobleme, Nachr. v. d. Ges. d. Wiss. zu Göttingen, Math-phys. Klasse, 235–57 (1918).
[2] J., Hanc, S., Tuleja and M., Hancova, Symmetries and conservation laws: consequences of Noether's theorem, Amer. J. Phys. 72, 428–35 (2004).Google Scholar
[3] B. W., Shore and D. H., MenzelPrinciples of Atomic Spectra (New York: Wiley, 1968), p. 290 ff.
[4] V. B., Berestetskii, E. M., Lifshitz and L. P., Pitaevskii, Quantum Electrodynamics, 2nd edn. (Oxford: Butterworth, 1982), p. 18 ff.
[5] L., Mandel and E., Wolf, Optical Coherence and Quantum Optics (Cambridge: Cambridge University press 1995), p. 490.
[6] S. F., Mason, Molecular Optical Activity and the Chiral Discriminations (Cambridge: Cambridge University Press 1982).
[7] N., Berova, K., Nakanishi and R. W., Woody, Circular Dichroism: Principles and Applications (Weinheim: Wiley-VCH, 2000).
[8] L. D., Barron, Molecular Light Scattering and Optical Activity 2nd edn. (Cambridge: Cambridge University Press 2004).
[9] W. R., Mason, A Practical Guide to Magnetic Circular Dichroism Spectroscopy (Hoboken, NJ: Wiley, 2007).
[10] L. D., Barron, L., Hecht, I. H., McColl and E. W., Blanch, Raman optical activity comes of age, Mol. Phys. 102, 731–44 (2004).Google Scholar
[11] M. J., Huttunen, M., Virkki, M., Erkintalo, et al. Absolute probe of surface chirality based on focused circularly polarized light, J. Phys. Chem. Lett. 1, 1826–29 (2010).Google Scholar
[12] P. C., Deguzman and G. P., Nordin, Stacked subwavelength gratings as circular polarization filters, Appl. Opt. 40, 5731–7 (2001).Google Scholar
[13] Z., Bomzon, G., Biener, V., Kleiner and E., Hasman, Radially and azimuthally polarized beams generated by space-variant dielectric subwavelength gratings, Opt. Lett. 27, 285–7 (2002).Google Scholar
[14] A., Lakhtakia and M., McCall, Sculptured thin films as ultranarrow-bandpass circular-polarization filters, Opt. Commun. 168, 457–65 (1999).Google Scholar
[15] L., Allen, M. W., Beijersbergen, R. J. C., Spreeuw and J. P., Woerdman, Orbital angular momentum of light and the transformation of Laguerre-Gaussian laser modes, Phys. Rev.A 45, 8185–9 (1992).Google Scholar
[16] W. H., Louisell, Quantum Statistical Properties of Radiation (New York: Wiley, 1973).
[17] D. P., Craig and T., Thirunamachandran, Molecular Quantum Electrodynamics (New York: Dover, 1998).
[18] A., Bekshaev and M., Soskin, Transverse energy flows in vectorial fields of paraxial beams, Proc. SPIE 6729, 67290G (2007).
[19] S. M., Barnett and L., Allen, Orbital angular momentum and nonparaxial light beams, Opt. Commun. 110, 670–8 (1994)Google Scholar
[20] S. J., van Enk and G., Nienhuis, Spin and orbital angular momentum of photons, Europhys. Lett. 25, 497–501 (1994).Google Scholar
[21] E., Santamato, Photon orbital angular momentum: problems and perspectives, Fortschr. Phys. 52, 1141–53 (2004).Google Scholar
[22] K. Y., Bliokh, M. A., Alonso, E. A., Ostrovskaya and A., Aiello, Angular momenta and spin-orbit interaction of nonparaxial light in free space, Phys. Rev. A 82, 063825 (2010).Google Scholar
[23] A. Ya., Bekshaev, A simple analytical model of the angular momentum transformation in strongly focused light beams, Cent. Eur. J. Phys. 8, 947–60 (2010).Google Scholar
[24] I., Bialynicki-Birula and Z., Bialynicka-Birula, Canonical separation of angular momentum of light into its orbital and spin parts, J. Opt. 13, 064014 (2011).Google Scholar
[25] C. G., Darwin, Notes on the theory of radiation, Proc. R. Soc. Lond.A 136, 36–52 (1932).Google Scholar
[26] L., Allen, M. J., Padgett and M., Babiker, The orbital angular momentum of light, Prog. Opt. 39, 291–372 (1999).Google Scholar
[27] G., Nienhuis, Angular momentum and vortices in optics, in Structured Light and Its Applications, ed. D. L., Andrews (Boston, MA: Academic Press, 2008), Chapter 2.
[28] L., Allen, V. E., Lembessis and M., Babiker, Spin-orbit coupling in free-space Laguerre-Gaussian light beams, Phys. Rev.A 53, R2937–9 (1996).Google Scholar
[29] L., Allen and M., Padgett, Introduction to phase-structured electromagnetic waves, in Structured Light and Its Applications, ed. D. L., Andrews (Boston, MA: Academic Press, 2008), Chapter 1.
[30] S., Chávez-Cerda, M. J., Padgett, I., Allison, et al. Holographic generation and orbital angular momentum of high-order Mathieu beams, J. Opt. B: Quantum Semiclass. Opt. 4, S52–7 (2002).Google Scholar
[31] E., Nagali, F., Sciarrino, F., De Martini, et al. Quantum information transfer from spin to orbital angular momentum of photons, Phys. Rev. Lett. 103, 013601 (2009).Google Scholar
[32] J., Leach, E., Yao and M. J., Padgett, Observation of the vortex structure of a non-integer vortex beam, New J. Phys. 6, 71 (2004).Google Scholar
[33] R. G., Woolley, Reformulation of molecular quantum electrodynamics, J. Phys. B: At. Mol. Opt. Phys. 7, 488–99 (1974).Google Scholar
[34] R. G., Woolley, Charged particles, gauge invariance, and molecular electrodynamics, Int. J. Quantum. Chem. 74, 531–45 (1999).Google Scholar
[35] C., Cohen-Tannoudji, J., Dupont-Roc and G., Grynberg, Photons and Atoms: Introduction to Quantum Electrodynamics (New York: Wiley-Interscience, 1989).
[36] G., Compagno and E. A., Power, Alternative effective-Hamiltonians in non-relativistic quantum electrodynamics, Phys. Rev.A 38, 4340–3 (1988).Google Scholar
[37] E. A., Power and T., Thirunamachandran, Maxwell's equations and the multipolar Hamiltonian, Phys. Rev.A 26, 1800–1 (1982).Google Scholar
[38] D. L., Andrews, Symmetry characterisation in molecular multiphoton spectroscopy, Spectrochim. Acta 46A, 871–85 (1990).Google Scholar
[39] M., Hamermesh, Group Theory and Its Application to Physical Problems, (Mineola, NY: Dover, 1989).
[40] S., Franke and S. M., Barnett, Angular momentum in spontaneous emission, J. Phys. B: At. Mol. Opt. Phys. 29, 2141–50 (1996).Google Scholar
[41] S., Franke-Arnold, S. M., Barnett, E., Yao, J., Leach, J., CourtialJ, and M., Padgett, Uncertainty principle for angular position and angular momentum, New. J. Phys. 6, 103 (2004).Google Scholar
[42] B., Jack, P., Aursand, S., Franke-Arnold, et al. Demonstration of the angular uncertainty principle for single photons, J. Opt. 13, 064017 (2011).Google Scholar
[43] D. L., Andrews, Optical angular momentum: multipole transitions and photonics, Phys. Rev.A 81, 033825 (2010).Google Scholar
[44] S., Werbowy and J., Kwela, M1-E2 interference in the Zeeman spectra of PbI and PbII, J. Phys. B: At. Mol. Opt. Phys. 42, 065002 (2009).Google Scholar
[45] D. L., Andrews and P., Allcock, Optical Harmonics in Molecular Systems (Weinheim: Wiley-VCH, 2002), Chapter 5.
[46] D. L., Andrews, Harmonic generation in free molecules, J. Phys. B: Atom. Mol. Phys. 13, 4091–9 (1980).Google Scholar
[47] D. L., Andrews, The role of longitudinal polarization in surface second harmonic generation, J. Mod. Opt. 40, 939–46 (1993).Google Scholar
[48] J., Courtial, K., Dholakia, L., Allen and M. J., Padgett, Second-harmonic generation and the conservation of orbital angular momentum with high-order Laguerre-Gaussian modes, Phys. Rev.A 56 4193–6 (1997).Google Scholar
[49] L. C. Dávila, Romero, D. L., Andrews and M., Babiker, A quantum electrodynamics framework for the nonlinear optics of twisted beams, J. Opt. B: Quantum Semiclass. Opt. 4, S66–72 (2002).Google Scholar
[50] S., Naguleswaran and G. E., Stedman, Time reversal selection rules and gauge invariance in nonlinear optics, J. Phys. B: At. Mol. Opt. Phys. 29, 4027–40 (1996).Google Scholar
[51] B. J., McKenzie and G. E., Stedman, Virtual phonon exchange between Kramers ions in a field theoretic formalism, J. Phys. C: Solid State Phys. 12, 5061–75 (1979).Google Scholar
[52] D. L., Andrews, L. C. Dávila, Romero and M., Babiker, Twisted laser beams and their optical interactions with chiral matter, in Trends in Chemical Physics Research, ed. A. N., Linke (Hauppauge, NY: Nova Science, 2006), pp. 155–76.
[53] D. L., Andrews, L. C. Dávila, Romero and M., Babiker, On optical vortex interactions with chiral matter, Opt. Commun. 237, 133–9 (2004).Google Scholar
[54] F., Araoka, T., Verbiest, K., Clays and A., Persoons, Interactions of twisted light with chiral molecules: an experimental investigation, Phys. Rev.A 71, 055401 (2005).Google Scholar
[55] G., Milione, J., Secor, G., Michel, S., Evans and R. R., Alfano, Raman optical activity by light with spin and orbital angular momentum, Proc. SPIE 7950, 79500H (2011).
[56] S. M., Barnett, Optical angular-momentum flux, J. Opt. B: Quantum Semiclass. Opt. 4, S7–16 (2002).Google Scholar
[57] G., Molina-Terriza, J. P., Torres and L., Torner, Management of the angular momentum of light: preparation of photons in multidimensional vector states of angular momentum, Phys. Rev. Lett. 88, 013601 (2002).Google Scholar
[58] G., Gibson, J., Courtial, M. J., Padgett, et al. Free-space information transfer using light beams carrying orbital angular momentum, Opt. Express 12, 5448–56 (2004).Google Scholar
[59] S., Franke-Arnold and J., Jeffers, Orbital angular momentum in quantum communication and information, Structured Light and Its Applications ed. D. L., Andrews, (Burlington, MA: Academic Press, 2008), pp. 271–93.
[60] J. C., Garcia-Escartin and P., Chamorro-Posada, Quantum multiplexing with the orbital angular momentum of light, Phys. Rev.A 78, 062320 (2008).Google Scholar
[61] D. L., Andrews, The effect of scattering on single photon transmission of optical angular momentum, J. Opt. 13, 064003 (2011).Google Scholar
[62] V. E., Lembessis, M., Babiker and D. L., Andrews, Surface optical vortices, Phys. Rev.A 79, 011806(R) (2009).Google Scholar
[63] D. L., Andrews, M., Babiker, V. E., Lembessis and S., Al-Awfi, Surface plasmons with phase singularities and their effects on matter, Phys. Status Solidi RRL 4, 241–3 (2010).Google Scholar
[64] V. E., Lembessis, S., Al-Awfi, M., Babiker and D. L., Andrews, Surface plasmon optical vortices and their influence on atoms, J. Opt. 13, 064002 (2011).Google Scholar

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