Skip to main content Accessibility help
×
Hostname: page-component-7479d7b7d-fwgfc Total loading time: 0 Render date: 2024-07-12T00:32:47.999Z Has data issue: false hasContentIssue false

9 - Cohesion of atoms

Published online by Cambridge University Press:  14 August 2009

John J. Gilman
Affiliation:
University of California, Los Angeles
Get access

Summary

The ideas involved in the theory of cohesion which underlies the theory of strength are relatively simple, although the details may be intricate. The most important forces that give high cohesion, and therefore high strength, are electrostatic so the theory might be said to have begun with Benjamin Franklin (1752). He speculated, based on his studies of electrostatics, that charges were somehow involved in cohesion. Later, Berzelius (1819) proposed that atomic particles with net positive and negative charges attract one another thereby forming chemical bonds. However, this did not account for the binding between atomic particles of the same electrostatic sign.

Verification of these speculations came only after a century of advances in technology. Methods for conveniently generating, storing, and handling electricity had to be developed as well as improved methods for evacuating containers. During his search for effective incandescent filaments, the improved vacua that he developed led Thomas Edison (1884) to the discovery that hot conductive filaments emit electricity that can flow to positive collectors through vacua. One of the consequences of this discovery, occurring about ten years later, was that Wilhelm Roentgen (1895) discovered X-rays.

Although atomic theories of matter had been postulated for millennia, and estimates of atomic spacings and structures in crystals could be made on the basis of the work of Boyle, Dalton, and Faraday, definitive measurements did not exist. Then, 17 years after Roentgen's discovery, Max von Laue (1912) showed that X-rays can be diffracted by crystals.

Type
Chapter
Information
Publisher: Cambridge University Press
Print publication year: 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Atkins, P. W. (1991). Quanta, p. 380. Oxford: Oxford University Press
Bond, G. C. (2000). Relativistic phenomena in the chemistry of the platinum group metals, Platinum Met. Rev., 44 (4), 146Google Scholar
Brown, A. S. and Spackman, M. A. (1990). An electron-density study of germanium: evaluation of the available experimental data, Acta Crystallogr. A, 46, 381CrossRefGoogle Scholar
Coppens, P. (1997). X-Ray Charge Densities and Chemical Bonding. New York: Oxford University Press
Coulson, C. A. (1952). Valence, p. 70. Oxford: Clarendon Press
Craig, D. P. and Thirunamachandran, T. (1998). Molecular Quantum Electrodynamics. Mineola, NY: Dover Publications
Deutsch, M. (1992). Electronic charge distribution in crystalline silicon, Phys. Rev. B, 45, 646CrossRefGoogle ScholarPubMed
Gray, H. B. (1973). Chemical Bonds: An Introduction to Atomic and Molecular Structure. Menlo Park, CA: W. A. Benjamin
Heisenberg, W. (1930). The Physical Principles of the Quantum Theory, trans. C. Eckart and F. C. Hoyt. New York: Dover Publications
Lu, Z. W. and Zunger, A. (1993). Electronic charge distribution in crystalline diamond, silicon, and germanium, Phys. Rev. B, 47 (15), 9385CrossRefGoogle ScholarPubMed
Madelung, E. (1909). Gött. Nach., 100
Parr, R. G. and Yang, W. (1989). Density-Functional Theory of Atoms and Molecules, p. 229. New York: Oxford University Press
Spackman, M. A. (1991). The electron distribution in diamond: a comparison between experiment and theory, Acta Crystallogr. A, 47, 4200CrossRefGoogle Scholar
Stewart, R. F. and Spackman, M. A. (1981). Charge density distributions. In Structure and Bonding in Crystals, ed. M. O'Keefe and A. Navrotsky, Volume I, Chapter 12. New York: Academic PressCrossRef
Van Arkel, A. E. (1956). Molecules and Crystals in Inorganic Chemistry. New York: Interscience. Also, Ketelaar, J. E. (1958). Chemical Constitution, An Introduction to the Theory of the Chemical Bond, 2nd edn. New York: Elsevier
Vos, M. and McCarthy, I. E. (1995). Observing electron motion in solids, Rev. Mod. Phys., 67 (3), 713. See also, Am. J. Phys., 65 (6) (1997)CrossRefGoogle Scholar
Weiner, J. H. (1983). Statistical Mechanics of Elasticity. New York: Wiley

Save book to Kindle

To save this book to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

  • Cohesion of atoms
  • John J. Gilman, University of California, Los Angeles
  • Book: Electronic Basis of the Strength of Materials
  • Online publication: 14 August 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511541247.011
Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

  • Cohesion of atoms
  • John J. Gilman, University of California, Los Angeles
  • Book: Electronic Basis of the Strength of Materials
  • Online publication: 14 August 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511541247.011
Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Cohesion of atoms
  • John J. Gilman, University of California, Los Angeles
  • Book: Electronic Basis of the Strength of Materials
  • Online publication: 14 August 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511541247.011
Available formats
×