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4 - Macroscopic symmetries : crystal morphology

from Part I - Structural features of minerals

Hans-Rudolf Wenk
Affiliation:
University of California, Berkeley
Andrei Bulakh
Affiliation:
St Petersburg State University
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Summary

Introduction

In the previous chapters we have become familiar with the extraordinary regularity of the internal structure of crystals. The local balancing of bonding forces between atoms leads to a periodic repetition of elementary units. We have seen that these unit cells and the corresponding lattice arrays are diagnostic for specific minerals and have classified them according to their symmetry. Symmetry emerged as a central feature of minerals and crystals. In Chapter 3, we recognized seven crystal systems, ranging from the highest cubic symmetry to the lowest triclinic symmetry. In this chapter we will look at symmetry more formally, particularly in view of the possible symmetries that are present in the external morphology of crystals.

A characteristic feature of crystals is “directionality”: specific directions in crystals are inherently different, and these differences are implicit in the lattice structure. Take, for example, a cubic crystal of galena (Figure 4.1a, e): if we view it along a crystal axis (e.g. [100]), we observe a 4-fold symmetry (Figure 4.1b); if the crystal is viewed along a body diagonal (e.g. [111]), it displays 3-fold symmetry (Figure 4.1c); if the cube is viewed along the bisectrix of two faces (e.g. [110]), two different mirror planes are observed (Figure 4.1d). If the growth velocity were isotropic, or equal in all directions, crystals would occur as spheres. Instead they display a regular morphology with planar surfaces. The largest faces are indicative of directions in which the growth velocity is slowest.

Type
Chapter
Information
Minerals
Their Constitution and Origin
, pp. 54 - 83
Publisher: Cambridge University Press
Print publication year: 2004

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References

Buerger, M. J. (1971). Introduction to Crystal Geometry. McGraw-Hill, New York, 204pp
De Jong, W. F. (1959). General Crystallography. A Brief Compendium. W. H. Freeman and Co., San Francisco, 281pp
Klein, C. (2002). Manual of Mineral Science, 22nd edn. Wiley, New York, 641pp
Phillips, F. C. (1971). An Introduction to Crystallography, 3rd edn. Wiley, New York, 351pp
Rousseau, J.-J. (1999). Basic Crystallography. Wiley, New York, 414pp
Sands, D. E. (1975). Introduction to Crystallography. Dover Publ., New York, 160pp

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