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CHAPTER XVII - SCHRÖDINGER'S WAVE EQUATION; HIS THEORY OF THE HYDROGEN SPECTRUM

Published online by Cambridge University Press:  05 July 2011

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Summary

Schrödinger's wave equation

The new theory was given in Schrödinger's first paper in much the same casual way as was that of Planck's radiation formula in his earliest papers. Both were arrived at by a process for which no particular justification was given; but the wave equation in the one case and the radiation formula in the other were so striking in their immediate consequences that a real theoretical basis had to be sought for them.

In this first paper the wave equation was found by a variation principle (it was rather like Hamilton's variation principle, but not much more could be said for it); but in the second paper Schrödinger shows it to be a real generalisation of the classical mechanics suggested by the waves of Louis de Broglie (§ 114).

In the former paper Schrödinger remarks that in his theory the ‘quantum numbers’ appear as naturally as do ‘integers’ in the theory of a vibrating string, where they are determined by certain boundary conditions to be satisfied by the solution of a differential equation; in quantum mechanics the corresponding differential equation is Schrödinger's wave equation.

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Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1928

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