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ART. 158 - Iridescent Crystals

Published online by Cambridge University Press:  05 July 2011

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Summary

The principal subject of the lecture is the peculiar coloured reflection observed in certain specimens of chlorate of potash. Reflection implies a high degree of discontinuity. In some cases, as in decomposed glass, and probably in opals, the discontinuity is due to the interposition of layers of air; but, as was proved by Stokes, in the case of chlorate crystals the discontinuity is that known as twinning. The seat of the colour is a very thin layer situated in the interior of the crystal and parallel to its faces.

The following laws were discovered by Stokes:—

  1. (1) If one of the crystalline plates be turned round in its own plane, without alteration of the angle of incidence, the peculiar reflection vanishes twice in a revolution, viz. when the plane of incidence coincides with the plane of symmetry of the crystal. [Shown.]

  2. (2) As the angle of incidence is increased the reflected light becomes brighter and rises in refrangibility. [Shown.]

  3. (3) The colours are not due to absorption, the transmitted light being strictly complementary to the reflected.

  4. (4) The coloured light is not polarised. It is produced indifferently, whether the incident light be common light or light polarised in any plane, and is seen whether the reflected light be viewed directly or through a Nicol's prism turned in any way. [Shown.]

  5. […]

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Scientific Papers , pp. 264 - 266
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1902

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