Book contents
- Frontmatter
- Contents
- Preface
- Acknowledgments
- THERMODYNAMICS: Fundamental for Applications
- 0 Introduction
- PART I THE BASICS
- PART II SINGLE-PHASE SYSTEMS
- PART III MULTIPHASE AND REACTING SYSTEMS
- PART IV ENGINEERING CALCULATIONS
- 10 Options for Equilibrium Calculations
- 11 Elementary Computational Procedures
- 12 Selected Applications
- AFTERWORD
- APPENDICES
- Notation
- Index
AFTERWORD
Published online by Cambridge University Press: 05 June 2012
- Frontmatter
- Contents
- Preface
- Acknowledgments
- THERMODYNAMICS: Fundamental for Applications
- 0 Introduction
- PART I THE BASICS
- PART II SINGLE-PHASE SYSTEMS
- PART III MULTIPHASE AND REACTING SYSTEMS
- PART IV ENGINEERING CALCULATIONS
- 10 Options for Equilibrium Calculations
- 11 Elementary Computational Procedures
- 12 Selected Applications
- AFTERWORD
- APPENDICES
- Notation
- Index
Summary
You are part of a development group assigned to determine the properties and phase behavior of certain mixtures that are to be used in a new process for your company. Your supervisor is relying on the group to provide a quick and thorough assessment of the proposed process: each day of production delay costs the company one million dollars.
You begin by asking how the information will be used: Is it for exploratory research, conceptual design, process development, equipment sizing, troubleshooting? You next ask what processing steps are involved: reactions, separations, heating, cooling, pumping, expansions, recycles? And which steps could affect business decisions for commercialization: Are reaction yields limited by rates or by equilibrium conversions? Are separations hindered by formation of azeotropes or solutropes? If additional solvents are introduced, how will they be removed, so the product is not contaminated? Can any solvents be recycled to avoid disposal and waste? Finally, you ask precisely what properties are being requested. Are they compositions of phases in equilibrium? Densities and enthalpies of single phase liquids, gases, or solids? Reaction rate constants? In short, you must decide what properties are to be quantified and then decide how those values will be used: in appropriate hand calculations or in a process simulator.
At this preliminary stage, you may be tempted to skimp on the quality of property data, but then you remember that inadequate thermodynamic information can lead to improper designs and process failures.
- Type
- Chapter
- Information
- ThermodynamicsFundamentals for Applications, pp. 585 - 588Publisher: Cambridge University PressPrint publication year: 2005