Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-14T19:17:29.943Z Has data issue: false hasContentIssue false
  • English
  • Français

X-Ray Studies of Basic Lead Azides

Published online by Cambridge University Press:  06 March 2019

M. Stammler  and
J. E. Abel
M. Stammler
Affiliation:
Picatinny Arsenal, Dover, New Jersey
J. E. Abel
Affiliation:
Picatinny Arsenal, Dover, New Jersey
Get access

Abstract

Basic lead azides are obtained by the slow thermal decomposition of PbN6 at temperatures up to 200°C in oxygen, argon, and air containing varying amounts of moisture. The decomposition diagrams show several stages due to the formation of different phases, two of which have been separated. One phase can be identified as a tetragonal deformed cubic lattice. Further slow decompositions of the basic lead azide at 250°C lead to tetragonal lead oxide. The structure of the other isolated phase Is of lower symmetry and has not yet been classified. The results of this investigation are also compared with the work of previous investigators.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 4: Ninth Annual Conference on Applications of X-ray Analysis, August 10-12, 1960 , 1960 , pp. 130 - 139
Copyright
Copyright © International Centre for Diffraction Data 1960

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Feitknecht, W., and Sahli, M., “Zur Kenntnis der basischen Azide des Eleis,” Helv. Chim. Acta, Vol. 37, 1954, p. 1423.Google Scholar
2. Stammler, M., Abel, J. E., and Kaufman, J. V. R., “Products of Decomposition of Lead Azide,” Nature, Vol. 185, 1960, p. 456.Google Scholar
3. Stammler, M., Abel, J. E., and Ling, R. C., “The Reaction Kinetics of Lead Azide Decomposition” (to be published).Google Scholar
4. Niederl, J. B. and Niederl, V., Organic Quantitative Analysis, 2nd edition, John Wiley and Sons, New York, 1942.Google Scholar
5. Croom, R. and Pristera, F., “Investigation of Methods for the Analysis of Lead Azide,” PATH 2486, March 1958.Google Scholar
6. Bystrom, R., “The Decomposition Products of LeadPeroxideandOxtdation Products of Lead Oxide,” Ark. Kemi, Mineral. Geol., Vol. 20, No. 11, 1945.Google Scholar
7. Stammler, M., “Oxydphasen des Bleis und ihre Kristallstrukturen,” Metall., Vol. 8, 1959, p. 750.Google Scholar
8. Reitzner, B., “The Influence of Water on the Thermal Decomposition of Lead Azide,” (to be published).Google Scholar