Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-28T14:18:44.310Z Has data issue: false hasContentIssue false
  • English
  • Français

Modification of kaolinite by controlled hydrothermal deuteration – a DRIFT spectroscopic study

Published online by Cambridge University Press:  09 July 2018

Hui Ming
Hui Ming*
Affiliation:
Centre for Advanced Manufacturing Research, University of South Australia, Mawson Lakes, SA 5095, Australia
*
*E-mail: hui.ming@unisa.edu.au
Get access Rights & Permissions [Opens in a new window]

Abstract

Kaolinites were modified by controlled hydrothermal deuteration. Both infrared and near infrared vibration spectra of deuterated kaolinite were investigated by Diffuse Reflectance Infrared Fourier Transform spectroscopy. The stretching vibrations (v) of deuteroxyl groups of the kaolinite were observed at 2726, 2709, 2697 and 2667 cm-1, respectively. The overtone bands (2n) of the deuteroxyl groups were visible in NIR regions at 5454, 5419, 5388 and 5342 cm-1, respectively. The lattice vibrations of the kaolinite taking part in deuteration included 937, 915, 792, 751 and 690 cm-1 which are assigned to hydroxyl group-related deformation or translation-vibration mode. The hydroxyl band at 3435 cm-1 with its deuteroxyl band at 2542 cm-1 resulted from unevenly distributed structural defects, either due to the isomorphous substitution of foreign cations or the imperfections of the kaolinite lattice structure.

Keywords

DRIFTNIRkaolinitehydrothermal deuterationhydrogen bonding
Type
Research Article
Information
Clay Minerals , Volume 39 , Issue 3 , September 2004 , pp. 349 - 362
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Abendroth, R.P. (1972) Surface charge development of porous silica in aqueous solution. The Journal of Physical Chemistry, 76, 2547–2949.Google Scholar
Aparicio, P. & Galán, E. (1999) Mineralogical inter-ference on kaolinite crystallinity index measurements. Clays and Clay Minerals, 47, 12–27.Google Scholar
Braggs, B., Fornasiero, D., Ralston, J. and Smart, R.St.C. (1994) The effect of surface modification by an organosilane on the electrochemical properties of kaolinite. Clays and Clay Minerals, 42, 123–136.Google Scholar
Ciurczak, E.W. (2001) Principles of near-infrared spectrosocopy Pp 7–18 in: Handbook of Near-Infrared Analysis, 2nd edition (Burns, D.A. and Ciurczak, E.W., editors). Marcel Dekker, Inc., New York.Google Scholar
Delineau, T., Allard, T., Muller, J., Barres, O., Yvon, J. & Cases, J. (1994) FTIR reflectance vs. EPR studies of structural iron in kaolinites. Clays and Clay Minerals, 42, 308–320.CrossRefGoogle Scholar
Deng, Y., White, G.N. & Dixon, J.B. (2002) Effect of structural stress on the intercalation rate of kaolinite. Journal of Colloid and Interface Science, 250, 379–393.CrossRefGoogle ScholarPubMed
Dixon, J.B. (1989) Minerals in Soil Environments, 2nd edition (Dixon, J.B. and Weed, S.B., editors). SSSA book series 1, pp. 467–518. Soil Science Society of America, New York.CrossRefGoogle Scholar
Donini, J.C. & Michaelian, K.H. (1986) Near-infrared photoacoustic FTIR spectroscopy of clay minerals and coal. Infrared Physics, 26, 135–140.Google Scholar
Faucher, J.A. & Thomas, H.C. (1955) Exchange between heavy water and clay minerals. The Journal of Physical Chemistry, 59, 189–191.Google Scholar
Frost, R.L. (1997) Structure of the kaolinite minerals–a FT-Raman study. Clay Minerals, 32, 65–77.Google Scholar
Frost, R.L. (1998) Hydroxyl deformation in kaolins. Clays and Clay Minerals, 46, 280–289.Google Scholar
Frost, R.L. & Johansson, U. (1998) Combination bands in the infrared spectroscopy of kaolins–a drift spectroscopic study. Clays and Clay Minerals, 46, 466–477.Google Scholar
Frost, R.J. & van der Gaast, S.J. (1997) Kaolinite hydroxyls–a Raman microscopy study. Clay Minerals, 32, 471–484.Google Scholar
Frost, R.L. & Vassallo, A.M. (1996) The dehydroxylation of the kaolinite using infrared emission spectroscopy. Clays and Clay Minerals, 44, 635–651.CrossRefGoogle Scholar
Gans, P. (1971) Vibrating Molecules–an Introduction to the Interpretation of Infrared and Raman Spectra. Chapman & Hall, London, pp. 13–19.Google Scholar
Hair, M.L. (1967) Infrared Spectroscopy in Surface Chemistry. Marcel Dekker, New York, pp. 191-197.Google Scholar
Hamilton, W.C. & Ibers, J.A. (1968) Hydrogen Bonding in Solids. Methods of Molecular Structure Determination. W.A. Benjamin Inc., New York, pp. 73-127.Google Scholar
Hollins, P. (1992) The influence of surface defects on the infrared spectra of adsorbed species. Surface Science Report, 16, 53–94.Google Scholar
Hunt, G.R. & Salisbury, J.W. (1970) Visible and near-infrared spectra of minerals and rocks. I. Silicate minerals. Modern Geology, 1, 283–300.Google Scholar
Iler, R.K. (1955) The Colloid Chemistry of Silica and Silicate. Ithaca, New York, Pp. 181-227.CrossRefGoogle Scholar
Jepson, W.B. (1984) Kaolins: their Properties and Uses. Philosophical Transactions of the Royal Society of London, A311, 411–432.Google Scholar
Johansson, U., Frost, R.L., Forsling, W. & Kloprogge, J.T. (1998a) Raman spectroscopy of the kaolinite hydroxyls at 77 K. Applied Spectroscopy, 52, 1277–1282.Google Scholar
Johansson, U., Holmgren, A., Forsling, W. & Frost, R.L. (1998b) Isotopic exchange of kaolinite hydroxyl protons: a diffuse reflectance infrared Fourier trans-form spectroscopy study. The Analyst, 123, 641–645.Google Scholar
Ledoux, R.L. & White, J.L. (1964) Infrared study of the OH groups in expended kaolinite. Science, 143, 244–246.Google Scholar
Ledoux, R.L. & White, J.L. (1964) Infrared study of selective deuteration of kaolinite and halloysite at room temperature. Science, 145, 47–49.Google Scholar
Ma, C. and Eggleton, R.A. (1999) Surface layer types of kaolinite: a high-resolution transmission electron microscope study. Clays and Clay Minerals, 47, 181–191.Google Scholar
Michaelian, K.H. (1986) The Raman spectrum of kaolinite #9 at 21 degrees C.. Canadian Journal of Chemistry, 64, 285–289.Google Scholar
Michaelian, K.H., Bukka, K. & Permann, D.N.S. (1987) Photoacoustic infrared spectra (250–10000 cm” ) of partially deuterated kaolinite #9. Canadian Journal of Chemistry, 65, 1420–1423.Google Scholar
Miller, J.G. (1961) An infrared spectroscopic study of the isothermal dehydroxylation of kaolinite at 470°. The Journal of Physical Chemistry, 65, 800–840.Google Scholar
Ming, H. & Spark, K.M. (2003) Radio frequency plasma induced hydrogen bonding on kaolinite. The Journal of Physical Chemistry B, 107, 694–702.Google Scholar
Ming, H., Spark, K.M. & Smart, R.St.C. (2001) Comparison of radio-rrequency-plasma- and ion-beam-induced surface modification of kaolinite. The Journal of Physical Chemistry B, 105, 3196–3203.Google Scholar
Petit, S., Madejová, J., Decarreau, A. & Martin, E. (1999) Characterization of octahedral substitutions in kao-linites using near infrared spectroscopy. Clays and Clay Minerals, 47, 103–108.Google Scholar
Romo, L.A. (1956) The exchange of hydrogen by deuterium in hydroxyls of kaolinite. The Journal of Physical Chemistry, 60, 987–989.Google Scholar
Rouxhet, P.G., Samudacheate, N., Jacobs, H. & Anton, O. (1977) Attribution of the OH stretching bands of kaolinite. Clay Minerals, 12, 171–180.Google Scholar
Roy, D.M. & Roy, R. (1957) Hydrogen-deuterium exchange in clays and problems in the assignment of infra-red frequencies in the hydroxyl region. Geochimica et Cosmochimica Ada, 11, 72–85.Google Scholar
Russell, J.D. & Fraser, A.R. (1994) Infrared methods. Pp. 11–67 in: Clay Mineralogy: Spectroscopic and Chemical Determinative Methods (Wilson, M.J., editor). Chapman & Hall, London.Google Scholar
Stubican, V. & Roy, R. (1961) Proton retention in heated 1:1 clays studied by infrared spectroscopy, weight loss and deuterium uptake. The Journal of Physical Chemistry, 65, 1348–1351.Google Scholar
Van der Marel, H.W. & Beutelspucher, H. (1976) Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures. Elsevier, New York, pp. 33 and 71–83.Google Scholar
Wada, K. (1967) A study of hydroxyl groups in kaolin minerals utilizing selective deuteration and infrared spectroscopy. Clay Minerals, 7, 51–61.Google Scholar