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Preparation of Maya Blue analogues using natural zeolites

Published online by Cambridge University Press:  09 July 2018

S. Kowalak  and
A. Zywert
S. Kowalak*
Affiliation:
Faculty of Chemistry, A. Mickiewicz University, Faculty of Chemistry, Grunwaldzka 6, 60-780 Poznań, Poland
A. Zywert
Affiliation:
Faculty of Chemistry, A. Mickiewicz University, Faculty of Chemistry, Grunwaldzka 6, 60-780 Poznań, Poland
*
*E-mail: skowalak@amu.edu.pl
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Abstract

Pigments similar to the famous Maya Blue were prepared by entrapment of indigo inside the channels of natural zeolites such as clinoptilolite and mordenite. The zeolites were mixed and ground with indigo and then heated at 150°C. Surplus (unbound) dye was removed by solvent extraction or by vacuum sublimation. As is the case when synthetic zeolites are used as matrices, the colouration of the resulting pigments could be modified by the previous cation exchange of the zeolite.

Keywords

pigmentsMaya Blueindigozeolite matricesnatural zeolitescation modificationUV-vis spectra
Type
Research Article
Information
Clay Minerals , Volume 46 , Issue 2 , June 2011 , pp. 197 - 204
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2011

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References

Chiari, G. & Giustetto, R. (2005) Maya blue: a long lasting mystery revealed. Ada Crystallographica, A61, C77.Google Scholar
Chiari, G., Giustetto, R. & Ricchiardi, G. (2003) Crystal structure refinements of palygorskite and Maya Blue from molecular modelling and powder synchrotron diffraction. European Journal of Mineralogy, 15, 21–33.Google Scholar
Chiari, G., Giustetto, R., Druzik, J., Doehne, E. & Ricchiardi, G. (2008) Pre-Columbian nanotechnology: reconciling the mysteries of the Maya blue pigment. Journal of Applied Physics A: Materials Science & Processing, 90, 3–7.CrossRefGoogle Scholar
Doménech, A., Domenech-Carbo, M.T. & Vazquez de Agredos Pascual, M.L. (2006) Dehydroindigo: a new piece into the Maya blue puzzle from the voltammetry of microparticles approach. The Journal of Physical Chemistry B, 110, 6027–6039.CrossRefGoogle ScholarPubMed
Doménech, A., Domenech-Carbo, M.T., Sánchez del Rio, M., Vaquez de Agredos Pascual, M.L. & Lima, E. (2009) Maya blue as a nanostructured polyfunctional hybrid organic-inorganic material: the need to change paradigms. New Journal of Chemistry, 33, 2371–2379.Google Scholar
Fois, E. & Tilocca, A. (2009) The color and stability of Maya blue: TDDFT calculations. The Journal of Physical Chemistry C, 113, 8683–8687.Google Scholar
Fois, E., Gamba, A. & Tilocca, A. (2003) On the unusual stability of Maya blue paint: molecular dynamics simulations. Microporous and Mesoporous Materials, 57, 263–272.Google Scholar
Gettens, R. & Stout, G.L. (1942) Pp. 130–131 in: Painting Materials — A Short Encyclopedia. D. Van Nostrand, New York, USA.Google Scholar
Hubbard, B., Kuang, W., Moser, A., Facey, G.A. & Detellier, Ch. (2003) Structural study of Maya Blue: textural, thermal and solid-state multinuclear magnetic resonance characterization of the palygorskiteindigo and sepiolite-indigo adducts. Clays and Clay Minerals, 51, 318–326.Google Scholar
Kowalak, S. & Zywert, A. (2009) Encapsulation of indigo into zeolite inner voids, 3rd International Symposium on Advanced, Micro- and Mesoporous Materials, Albena 2009, Bulgaria.Google Scholar
Polette-Niewold, L.A., Manciu, F.S., Torres, B., Alvarado, M. Jr. & Chianelli, R.R. (2007) Organic/inorganic complex pigments: ancient colors, Maya Blue. Journal of Inorganic Biochemistry, 101, 1958–1973.Google Scholar
Reinen, D., Kohl, P. & Miiller, C. (2004) The nature of the colour centres in ‘Maya Blue’ — the incorporation of organic pigment molecules into the palygorskite lattice. Zeitschrifi für Anorganische und Allgemeine Chemie, 630, 97–103.CrossRefGoogle Scholar
Reyes-Valerio, C. (1993) De Bonampak al Templo Mayor. El azul maya en Mesoamerica. Coleccion America Nuestra, 40 (Siglo XXI Editores, Mexico D.F).Google Scholar
Schulz-Ekloff, G., Hoppe, R., Wohrle, D., Kirschhock, D. & Fuesslc, H. (1994) Synthesis, location, and photoinduced transformation of zeolite-encaged thioindigo. Langmuir, 10, 1517–1523.Google Scholar
Shepard, A. (1962) Maya blue: alternative hypotheses. American Antiquity. 27, 565–566.Google Scholar
Van Olphen, H. (1966) Maya Blue: a clay mineral-organic pigment. Science, 154, 645–646.Google Scholar