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Adsorption of crystal violet on kaolinite clay: kinetic and equilibrium study using non-linear models

Published online by Cambridge University Press:  24 August 2022

Ali Boukhemkhem ,
Bamhammed Aissa-Ouaissi-Sekkouti ,
Jorge Bedia Open the ORCID record for Jorge Bedia [Opens in a new window] ,
Carolina Belver  and
Carmen B. Molina Open the ORCID record for Carmen B. Molina [Opens in a new window]
Ali Boukhemkhem
Affiliation:
Laboratory Interactions Materials – Environment (LIME), University of Mohamed Seddik Ben Yahia, Jijel, 18000, Algeria
Bamhammed Aissa-Ouaissi-Sekkouti
Affiliation:
Department of Process Engineering, University of Ammar Telidji, Laghouate, 03000, Algeria
Jorge Bedia
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
Carolina Belver
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
Carmen B. Molina*
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
*
*E-mail: carmenbelen.molina@uam.es
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Abstract

This work studied the efficiency of Tamazert kaolinite clay for adsorbing the cationic dye crystal violet from an aqueous solution in a batch system. The kinetics of the process and the equilibrium of adsorption were studied using non-linear models. The characterization of Tamazert kaolinite clay showed that it has structural, textural and surface properties that are suitable for adsorption. The effects of various process parameters such as contact time, initial dye concentration, initial pH, adsorbent dose and temperature were tested. The kinetic study using non-linear regression showed that the pseudo-second order model best fitted the experimental data. The intra-particle model was also used to estimate the contribution of intra-particle diffusion to this process. The adsorption isotherms were fitted to Freundlich, Langmuir and Redlich–Peterson models, showing that the adsorption is limited to a monolayer with a monolayer adsorption capacity of 44.2 mg g–1. The thermodynamic study indicated that the process is exothermic, spontaneous and accompanied by a decrease in entropy.

Keywords

adsorptioncrystal violetequilibriumkineticsLangmuirTamazert kaolinite claythermodynamics
Type
Article
Information
Clay Minerals , Volume 57 , Issue 1 , March 2022 , pp. 41 - 50
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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