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Enhanced fluorescence of selected cationic dyes adsorbed on reduced-charge montmorillonite

Published online by Cambridge University Press:  09 July 2018

P. Pustková ,
Z. Klika ,
J. Preclíková  and
T. M. Grygar
P. Pustková*
Affiliation:
Department of Analytical Chemistry and Material Testing, VŠB-Technical University of Ostrava, 17 Listopadu 15, 708 33 Ostrava-Poruba, Czech Republic
Z. Klika
Affiliation:
Department of Analytical Chemistry and Material Testing, VŠB-Technical University of Ostrava, 17 Listopadu 15, 708 33 Ostrava-Poruba, Czech Republic
J. Preclíková
Affiliation:
Department of Chemical Physics and Optics, Charles University Prague, Ke Karlovu 3, 121 16 Prague, Czech Republic
T. M. Grygar
Affiliation:
Institute of Inorganic Chemistry AS CR, v.v.i., Husinec-Řež 1001, 250 68 Řež, Czech Republic
*
*E-mail: petra.pustkova@vsb.cz
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Abstract

The aggregation of three cationic dyes (CD), crystal violet (CV), Nile blue (NB) and rhodamine B (RB) in aqueous solution was studied by visible absorption spectrophotometry and compared with methylene blue (MB). The distribution of the dye species (monomers, dimers, trimers, and tetramers) in aqueous solutions with different concentrations of dye was calculated using equilibrium stepwise aggregation constants Kn. These cationic dyes were intercalated into montmorillonite (SAz-1) and its reduced charge form (RC-SAz(210)) prepared by heating lithium montmorillonite (Li/SAz-1) at 210ºC. The fluorescence of fully saturated CD/SAz and low-CD loaded CD/RC-SAz(210) complexes was studied. Visible absorption spectra of CD aqueous solutions and visible absorption spectra and X-ray diffraction patterns (d001) of the CD/SAz and CD/RC-SAz( 210) solid complexes were obtained and evaluated. Large fluorescence intensities were found for CV/RC-SAz(210) and NB/RC-SAz(210) complexes in the same way as for the complex of methylene blue with reduced-charge montmorillonite MB/RCM(210) described previously.

Keywords

cationic dyecrystal violetNile bluerhodamine Breduced-charge montmorillonitevisible spectrophotometryfluorescence
Type
Research Papers
Information
Clay Minerals , Volume 46 , Issue 1 , March 2011 , pp. 93 - 103
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2011

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