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Sorptive Characteristics of Tetraalkylammonium-Exchanged Smectite Clays

Published online by Cambridge University Press:  01 January 2024

Yuan Chun ,
Guangyao Sheng  and
Stephen A. Boyd
Yuan Chun*
Affiliation:
Department of Crop, Soil and Environmental Sciences, University of Arkansas, Fayetteville, AR 72701, USA
Guangyao Sheng*
Affiliation:
Department of Crop, Soil and Environmental Sciences, University of Arkansas, Fayetteville, AR 72701, USA
Stephen A. Boyd
Affiliation:
Department of Crop and Soil Sciences, Michigan State University, East Lansing, MI 48824, USA
*
†Visiting scientist, Department of Chemistry, Nanjing University, Nanjing, 210093, P.R. China
*E-mail address of corresponding author: gsheng@uark.edu
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Abstract

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The size of quaternary NH4+ cations defines their packing configurations in the interlayers and the basal spacings of organoclays, and hence strongly influences the sorptive properties of organoclays. A series of organoclays (TAA-SACs) was prepared from a smectite (SAC) fully exchanged with symmetrical tetraalkylammonium (TAA) cations of progressively increasing sizes with the carbon number of single alkyl group from 1 to 6. X-ray diffraction analysis indicated the packing configurations of monolayer, monolayer-to-bilayer transition, bilayer, and bilayer-to-trilayer transition in the interlayers of SAC. Calculations of the interionic distances between TAA ions support such packing configurations. Sorption of benzene by TAA-SACs displayed a high-low-high uptake trend and progressively weaker sorptive interactions as the size of TAA ions increased. Both the siloxane surfaces and TAA ions contributed to the overall sorption, with their relative contributions dependent on the TAA interionic distances and the basal spacings of TAA-SACs. High benzene sorption by small TAA-SAC (tetramethylammonium(TMA)-SAC) was attributed to the strong interactions between the siloxane surfaces and benzene molecules. With large TAAs, high sorption was due to the effective solute partitioning. Compared to benzene sorption, TCE sorption by small TAA-SACs (TMA-SAC and tetraethylammonium(TEA)-SAC) was less effective and displayed an abnormal trend, due largely to the lack of the siloxane surface-TCE interactions and to the stronger hydration of TMA as compared to TEA ions. The results provide strong evidence to support the use of either small or large quaternary NH4+ cations in preparation of organoclays as effective sorbents for removing organic contaminants from water.

Keywords

NOCOrganoclaySmectiteSorptionTetraalkylammonium
Type
Research Article
Information
Clays and Clay Minerals , Volume 51 , Issue 4 , August 2003 , pp. 415 - 420
Copyright
Copyright © 2003, The Clay Minerals Society

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