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Design Approaches, Functionalization, and Environmental and Analytical Applications of Magnetic Halloysite Nanotubes: A Review

Published online by Cambridge University Press:  01 January 2024

Meriem Fizir Open the ORCID record for Meriem Fizir [Opens in a new window] ,
Wei Liu ,
Xue Tang ,
Fangqi Wang  and
Yassmine Benmokadem
Meriem Fizir*
Affiliation:
Laboratoire de Valorisation Des Substances Naturelles, Université Djilali Bounaâma, Khemis Miliana, Algérie Department of Chemistry, China Pharmaceutical University, Nanjing 211198, China
Wei Liu
Affiliation:
Nanjing Institute for Comprehensive Utilization of Wild Plants, Nanjing, China
Xue Tang
Affiliation:
Department of Chemistry, China Pharmaceutical University, Nanjing 211198, China
Fangqi Wang
Affiliation:
Department of Chemistry, China Pharmaceutical University, Nanjing 211198, China
Yassmine Benmokadem
Affiliation:
Laboratoire de Valorisation Des Substances Naturelles, Université Djilali Bounaâma, Khemis Miliana, Algérie
*
e-mail: meriem.fizir@univ-dbkm.dz; meriem_fizir@163.com
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Abstract

Researchers have long been committed to developing alternative, low-cost nanomaterials that have comparable capacity to carbon nanotubes. Halloysite nanotubes (HNTs) are naturally hollow, multi-walled, tubular structures that have high porosity, enlarged volumes and surface areas, and hydroxyl groups ready for modification. In addition, HNTs are non-toxic, biocompatible, inexpensive, abundant in nature, and easy to obtain. Magnetic nanocomposites have aroused widespread attention for their diverse potential applications in analytical fields and so magnetic halloysite nanotubes (MHNTs) have emerged as outstanding magnetic nano-adsorbent materials. Owing to their superparamagnetism, selective adsorption ability, and easy separation and surface modification, these captivating nanomaterials excel at extracting and enriching various analytes from environmental, biological, and food samples. The current review article gives an insight into recent advances in the design, functionalization, characterization, and application of MHNTs as magnetic, solid-phase extraction sorbents for separation of antibiotics, pesticides, proteins, carcinogens such as polycyclic aromatic hydrocarbons (PAHs), dyes, radioactive ions, and heavy-metal ions in complex matrices.

Keywords

Environmental applicationsFunctionalizationHalloysite nanotubesMagnetic nanocompositesMagnetic solid-phase extractionSynthesis

Information

Type
Review
Information
Clays and Clay Minerals , Volume 70 , Issue 5 , October 2022 , pp. 660 - 694
Copyright
Copyright © The Author(s), under exclusive licence to The Clay Minerals Society 2022

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Footnotes

Associate Editor: Lynda B. Williams

References

Abhinayaa, R., Jeevitha, G., Mangalaraj, D., Ponpandian, N., Vidhya, K., & Angayarkanni, J. (2018). Cytotoxic consequences of Halloysite nanotube/iron oxide nanocomposite and iron oxide nanoparticles upon interaction with bacterial, non-cancerous and cancerous cells. Colloids and Surfaces b: Biointerfaces, 169, 395–403.CrossRefGoogle ScholarPubMed
Abhinayaa, R., Jeevitha, G., Mangalaraj, D., Ponpandian, N., & Meena, P. (2019). Toxic influence of pristine and surfactant modified halloysite nanotubes on phytopathogenic bacteria. Applied Clay Science, 174, 57–68.CrossRefGoogle Scholar
Afkhami, A., Sayari, S., Soltani-Felehgari, F., & Madrakian, T. (2015). Ni0.5Zn0.5Fe2O4 nanocomposite- modified carbon paste electrode for highly sensitive and selective simultaneous electrochemical determination of trace amounts of mercury (II) and cadmium (II). Journal of the Iranian Chemical Society, 12(2), 257–265.Google Scholar
Afzali, D., & Fayazi, M. (2016). Deposition of MnO2 nanoparticles on the magnetic halloysite nanotubes by hydrothermal method for lead (II) removal from aqueous solutions. Journal of the Taiwan Institute of Chemical Engineers, 63, 421–429.CrossRefGoogle Scholar
Ahangaran, F., & Navarchian, A. H. (2020). Recent advances in chemical surface modification of metal oxide nanoparticles with silane coupling agents: A review. Advances in Colloid and Interface Science, 102298.CrossRefGoogle Scholar
Alguacil, F. J., Alcaraz, L., García-Díaz, I., & López, F. A. (2018). Removal of Pb2+ in wastewater via adsorption onto an activated carbon produced from winemaking waste. Metals, 8(9), 697.CrossRefGoogle Scholar
Amjadi, M., Samadi, A., & Manzoori, J. L. (2015a). A composite prepared from halloysite nanotubes and magnetite (Fe3O4) as a new magnetic sorbent for the preconcentration of cadmium (II) prior to its determination by fame atomic absorption spectrometry. Microchimica Acta, 182(9), 1627–1633.CrossRefGoogle Scholar
Amjadi, M., Samadi, A., Manzoori, J. L., & Arsalani, N. (2015b). 5-(p-Dimethylaminobenzylidene) rhodaninemodified magnetic halloysite nanotubes as a new solid phase sorbent for silver ions. Analytical Methods, 7(14), 5847–5853.CrossRefGoogle Scholar
Ashrafzadeh Afshar, E., Taher, M. A., & Fazelirad, H. (2017). Ultra-trace determination of thallium(I) using a nano-composite consisting of magnetite, halloysite nanotubes and dibenzo-18-crown-6 for preconcentration prior to its quantitation by ET-AAS. Microchimica Acta. https://doi.org/10.1007/s00604-016-2040-zCrossRefGoogle Scholar
Aylaz, G., Kuhn, J., Lau, E. C., Yeung, C. C., Roy, V. A., Duman, M., & Yiu, H. H. (2021). Recent developments on magnetic molecular imprinted polymers (MMIPs) for sensing, capturing, and monitoring pharmaceutical and agricultural pollutants. Journal of Chemical Technology & Biotechnology. https://doi.org/10.1002/jctb.6681CrossRefGoogle Scholar
Bai, Y., Park, I. S., Lee, S. J., Bae, T. S., Watari, F., Uo, M., & Lee, M. H. (2011). Aqueous dispersion of surfactant-modified multiwalled carbon nanotubes and their application as an antibacterial agent. Carbon, 49(11), 3663–3671.CrossRefGoogle Scholar
Bilici, M., Badak, M. U., Zengin, A., Suludere, Z., & Aktas, N. (2020). Synthesis of magnetic halloysite nanotube-based molecularly imprinted polymers for sensitive spectrophotometric detection of metoclopramide in urine samples. Materials Science and Engineering: C, 106, 110223.CrossRefGoogle ScholarPubMed
Chen, L., Zhou, C. H., Fiore, S., Tong, D. S., Zhang, H., Li, C. S., Ji, S. F., & Yu, W. H. (2016). Functional magnetic nanoparticle/clay mineral nanocomposites: preparation, magnetism and versatile applications. Applied Clay Science, 127, 143163.Google Scholar
Cheng, D., Dai, X., Chen, L., Cui, Y., Qiang, C., Sun, Q., & Dai, J. (2019). Thiol–yne click synthesis of polyamide–amine dendritic magnetic halloysite nanotubes for the efficient removal of Pb (II). ACS Sustainable Chemistry & Engineering, 8(2), 771–781.CrossRefGoogle Scholar
Dai, J., Wei, X., Cao, Z., Zhou, Z., Yu, P., Pan, J., Zou, T., Li, C., & Yan, Y. (2014). Highly-controllable imprinted polymer nanoshell at the surface of magnetic halloysite nanotubes for selective recognition and rapid adsorption of tetracycline. RSC advances, 4(16), 7967. https://doi.org/10.1039/c3ra45779fCrossRefGoogle Scholar
Darvishnejad, M., & Ebrahimzadeh, H. (2018). Magnetic halloysite nanotube/polyaniline/copper composite coupled with gas chromatography–mass spectrometry: A rapid approach for determination of nitro-phenanthrenes in water and soil samples. Journal of Chromatography A, 1563, 1–9.CrossRefGoogle ScholarPubMed
Das, K., Maiti, S., Ghosh, M., Mandal, D., & Das, P. K. (2013). Graphene oxide in cetyltrimethylammonium bromide (CTAB) reverse micelle: A befitting soft nano-composite for improving efficiency of surface-active enzymes. Journal of Colloid and Interface Science, 395, 111–118.CrossRefGoogle Scholar
Di, S., Ning, T., Yu, J., Chen, P., Yu, H., Wang, J., Yang, H., & Zhu, S. (2020). Recent advances and applications of magnetic nanomaterials in environmental sample analysis. TrAC Trends in Analytical Chemistry, 126, 115864.CrossRefGoogle Scholar
Dramou, P., Fizir, M., Taleb, A., Itatahine, A., Dahiru, N. S., Mehdi, Y. A., Wei, L., Zhang, J., & He, H. (2018). Folic acid-conjugated chitosan oligosaccharide-magnetic halloysite nanotubes as a delivery system for camptothecin. Carbohydrate Polymers, 197, 117–127.CrossRefGoogle ScholarPubMed
Dramou, P., Wang, F., Sun, Y., Zhang, J., Yang, P., Liu, D., & He, H. (2022). Synthesis and characterization of superparamagnetic graphene oxide assembled halloysite composites for extraction of rutin. Applied Clay Science, 217, 106397.CrossRefGoogle Scholar
Dramou, P., Zuo, P., He, H., Pham-Huy, L. A., Zou, W., Xiao, D., & Pham-Huy, C. (2013). Development of novel amphiphilic magnetic molecularly imprinted polymers compatible with biological fluids for solid phase extraction and physicochemical behavior study. Journal of Chromatography A, 1317, 110–120.CrossRefGoogle ScholarPubMed
Duan, J., Liu, R., Chen, T., Zhang, B., & Liu, J. (2012). Halloysite nanotube-Fe3O4 composite for removal of methyl violet from aqueous solutions. Desalination, 293, 46–52. https://doi.org/10.1016/j.desal.2012.02.022CrossRefGoogle Scholar
Duan, X.-L., Yuan, C.-G., Guo, Q., Niu, S.-L., He, K.-Q., & Xia, G.-W. (2021). Preparation of halloysite nanotubes-encapsulated magnetic microspheres for elemental mercury removal from coal-fired flue gas. Journal of Hazardous Materials, 406, 124683.CrossRefGoogle ScholarPubMed
Eskandarloo, H., Arshadi, M., & Abbaspourrad, A. (2018). Magnetic dendritic halloysite nanotube for highly selective recovery of heparin digested from porcine intestinal mucosa. ACS Sustainable Chemistry & Engineering, 6(11), 14561–14573.CrossRefGoogle Scholar
Fakhrullin, R. F., & Lvov, Y. M. (2016). Halloysite clay nanotubes for tissue engineering. Nanomedicine, 11(17), 2243–2246. https://doi.org/10.2217/nnm-2016-0250CrossRefGoogle ScholarPubMed
Farooq, M. U., & Jalees, M. I. (2020). Application of magnetic graphene oxide for water purification: Heavy metals removal and disinfection. Journal of Water Process Engineering, 33, 101044.Google Scholar
Fayazi, M., Taher, M. A., Afzali, D., & Mostafavi, A. (2016). Fe3O4 and MnO2 assembled on halloysite nanotubes: A highly efficient solid-phase extractant for electrochemical detection of mercury (II) ions. Sensors and Actuators b: Chemical, 228, 1–9.CrossRefGoogle Scholar
Fizir, M., Dramou, P., Zhang, K., Sun, C., Pham-Huy, C., & He, H. (2017). Polymer grafted-magnetic halloysite nanotube for controlled and sustained release of cationic drug. Journal of Colloid and Interface Science, 505, 476–488.CrossRefGoogle ScholarPubMed
Fizir, M., Dramou, P., Nasiru Sintali, D., Ruya, W., Huang, T., & He, H. (2018a). Halloysite nanotubes in analytical sciences and in drug delivery: A review. Microchimica Acta, 185, article number 389, https://doi.org/10.1007/s00604-018-2908-1.CrossRefGoogle ScholarPubMed
Fizir, M., Wei, L., Muchuan, N., Itatahine, A., mehdi, Y. A., He, H., & Dramou, P. (2018b). QbD approach by computer aided design and response surface methodology for molecularly imprinted polymer based on magnetic halloysite nanotubes for extraction of norfloxacin from real samples. Talanta, 184, 266–276.https://doi.org/10.1016/j.talanta.2018b.02.056CrossRefGoogle ScholarPubMed
Fizir, M., Richa, A., He, H., Touil, S., Brada, M., & Fizir, L. (2020). A mini review on molecularly imprinted polymer based halloysite nanotubes composites: Innovative materials for analytical and environmental applications. Reviews in Environmental Science and Biotechnology, 19, 241–258.CrossRefGoogle Scholar
Fizir, M., Dahiru, N. S., Cui, Y., Zhi, H., Dramou, P., & He, H. (2021). Simple and Efficient Detection Approach of Quercetin from Biological Matrix by Novel Surface Imprinted Polymer Based Magnetic Halloysite Nanotubes Prepared by a Sol-Gel Method. Journal of Chromatographic Science, 59, 681–695. https://doi.org/10.1093/chromsci/bmaa120CrossRefGoogle ScholarPubMed
Foroughirad, S., Haddadi-Asl, V., Khosravi, A., & Salami-Kalajahi, M. (2020a). Effect of porogenic solvent in synthesis of mesoporous and microporous molecularly imprinted polymer based on magnetic halloysite nanotubes. Materials Today Communications, 101780.CrossRefGoogle Scholar
Foroughirad, S., Haddadi-Asl, V., Khosravi, A., & Salami-Kalajahi, M. (2020b). Synthesis of magnetic nanoparticles-decorated halloysite nanotubes/poly ([2-(acryloyloxy) ethyl] trimethylammonium chloride) hybrid nanoparticles for removal of Sunset Yellow from water. Journal of Polymer Research, 27(10), 1–10.CrossRefGoogle Scholar
Foroughirad, S., Haddadi-Asl, V., Khosravi, A., & Salami-Kalajahi, M. (2021). Magnetic halloysite-based molecularly imprinted polymer for specific recognition of sunset yellow in dyes mixture. Polymers for Advanced Technologies, 32(2), 803–814.CrossRefGoogle Scholar
Fu, H., Liao, L., Li, X., & Chen, W. (2016). Preparation and characterization of novel modified halloysite-Fe3O4-Ag/polyurea nanocomposites with antibacterial property. International Journal of Polymeric Materials and Polymeric Biomaterials, 65(17), 863–871.CrossRefGoogle Scholar
Gabal, M., El-Shishtawy, R. M., & Al Angari, Y. (2012). Structural and magnetic properties of nano-crystalline Ni–Zn ferrites synthesized using egg-white precursor. Journal of Magnetism and Magnetic Materials, 324(14), 2258–2264.CrossRefGoogle Scholar
Gabal, M. A. (2010). Magnetic properties of NiCuZn ferrite nanoparticles synthesized using egg-white. Materials Research Bulletin, 45(5), 589–593.CrossRefGoogle Scholar
Gan, M., Huang, Y., Zhang, Y., Pan, J., Shi, W., & Yan, Y. (2015). Fabrication of Ag/halloysite nanotubes/Fe3O4 nanocatalyst and their catalytic performance in 4-nitrophenol reduction. Desalination and Water Treatment, 56(2), 425–434.CrossRefGoogle Scholar
Ganganboina, A. B., Chowdhury, A. D., & Doong, R.-A. (2017). Nano assembly of N-doped graphene quantum dots anchored Fe3O4/halloysite nanotubes for high performance supercapacitor. Electrochimica Acta, 245, 912–923.CrossRefGoogle Scholar
Gao, C., Li, W., Morimoto, H., Nagaoka, Y., & Maekawa, T. (2006). Magnetic carbon nanotubes: Synthesis by electrostatic self-assembly approach and application in biomanipulations. The Journal of Physical Chemistry B, 110(14), 7213–7220.CrossRefGoogle ScholarPubMed
Gao, C., Lyu, F., & Yin, Y. (2020). Encapsulated metal nano-particles for catalysis. Chemical Reviews.Google Scholar
Gao, F. (2019). An overview of surface-functionalized magnetic nanoparticles: Preparation and application for wastewater treatment. ChemistrySelect, 4(22), 6805–6811.CrossRefGoogle Scholar
Garcia, M., Scheffczyk, A., Garcia, T., & Römbke, J. (2011). The effects of the insecticide lambda-Cyhalothrin on the earthworm Eisenia fetida under experimental conditions of tropical and temperate regions. Environmental Pollution, 159(2), 398–400.CrossRefGoogle ScholarPubMed
Ghandi, K. (2014). A review of ionic liquids, their limits and applications. Green and Sustainable Chemistry, 4, 44–53.CrossRefGoogle Scholar
Guan, W., Wang, X., Pan, J., Lei, J., Zhou, Y., Lu, C., & Yan, Y. (2012). Synthesis of magnetic halloysite composites for the effective removal of tetracycline hydrochloride from aqueous solutions. Adsorption Science & Technology, 30(7), 579–591.CrossRefGoogle Scholar
Guć, M., Messyasz, B., & Schroeder, G. (2021). Environmental impact of molecularly imprinted polymers used as analyte sorbents in mass spectrometry. Science of the Total Environment, 772, 145074.CrossRefGoogle ScholarPubMed
Hajizadeh, Z., & Maleki, A. (2018). Poly (ethylene imine)-modified magnetic halloysite nanotubes: A novel, efficient and recyclable catalyst for the synthesis of dihydropyrano [2, 3-c] pyrazole derivatives. Molecular Catalysis, 460, 87–93.CrossRefGoogle Scholar
Hajizadeh, Z., Hassanzadeh-Afruzi, F., Jelodar, D. F., Ahghari, M. R., & Maleki, A. (2020a). Cu (ii) immobilized on Fe3O4@HNTs–tetrazole (CFHT) nanocomposite: Synthesis, characterization, investigation of its catalytic role for the 1, 3 dipolar cycloaddition reaction, and antibacterial activity. RSC Advances, 10(44), 26467–26478.CrossRefGoogle ScholarPubMed
Hajizadeh, Z., Maleki, A., Rahimi, J., & Eivazzadeh-Keihan, R. (2020b). Halloysite nanotubes modified by Fe3O4 nan-oparticles and applied as a natural and efficient nanocatalyst for the symmetricalhantzsch reaction. Silicon, 12(5), 1247–1256.CrossRefGoogle Scholar
Hamza, H., Ferretti, A. M., Innocenti, C., Fidecka, K., Licandro, E., Sangregorio, C., & Maggioni, D. (2020). An Approach for Magnetic Halloysite Nanocomposite with Selective Loading of Superparamagnetic Magnetite Nanoparticles in the Lumen. Inorganic Chemistry, 59(17), 12086–12096.CrossRefGoogle ScholarPubMed
Hang, H., Li, C., Pan, J., Li, L., Dai, J., Dai, X., Yu, P., & Feng, Y. (2013). Selective separation of lambdacyhalothrin by porous/magnetic molecularly imprinted polymers prepared by Pickering emulsion polymerization. Journal of Separation Science, 36(19), 3285–3294.CrossRefGoogle ScholarPubMed
He, J., Zou, T., Chen, X., Dai, J., Xie, A., Zhou, Z., & Yan, Y. (2016a). Magnetic organic–inorganic nanocomposite with ultrathin imprinted polymers via an in situ surface-initiated approach for specific separation of chloramphenicol. RSC Advances, 6(74), 70383–70393.CrossRefGoogle Scholar
He, W., Chen, Y., Zhang, W., Hu, C., Wang, J., & Wang, P. (2015). Removal of UO22 from aqueous solution using halloysite nanotube-Fe3O4 composite. Korean Journal of Chemical Engineering, 33(1), 170–177. https://doi.org/10.1007/s11814-015-0111-1CrossRefGoogle Scholar
He, W., Chen, Y., Zhang, W., Hu, C., Wang, J., & Wang, P. (2016b). Removal of UO22+ from aqueous solution using halloysite nanotube-Fe3O4 composite. Korean Journal of Chemical Engineering, 33(1), 170–177.CrossRefGoogle Scholar
He, Y., Yi, C., Zhang, X., Zhao, W., & Yu, D. (2021). Magnetic graphene oxide: Synthesis approaches, physico-chemical characteristics, and biomedical applications. TrAC Trends in Analytical Chemistry, 116191.CrossRefGoogle Scholar
Huang, Z., He, J., Li, H., Zhang, M., Wang, H., Zhang, Y., Li, Y., You, L., & Zhang, S. (2020). Synthesis and application of magnetic-surfaced pseudo molecularly imprinted polymers for zearalenone pretreatment in cereal samples. Food Chemistry, 308, 125696.CrossRefGoogle ScholarPubMed
Itatahine, A., Mehdi, Y. A., Fizir, M., Qi, M., Dramou, P., & He, H. (2017). Multifunctional carbon nanomateriels for camptothecine low-water soluble anticancer drug delivery. New Journal of Chemistry.Google Scholar
Jee, S.-C., Kim, M., Shinde, S. K., Ghodake, G. S., Sung, J.-S., & Kadam, A. A. (2020). Assembling ZnO and Fe3O4 nanostructures on halloysite nanotubes for antibacterial assessments. Applied Surface Science, 509, 145358.CrossRefGoogle Scholar
Jia, L., Zhou, T., Xu, J., Li, F., Xu, Z., Zhang, B., Guo, S., Shen, X., & Zhang, W. (2017). AuPd bimetallic nanocrystals embedded in magnetic halloysite nanotubes: Facile synthesis and catalytic reduction of nitroaromatic compounds. Nanomaterials, 7(10), 333.CrossRefGoogle ScholarPubMed
Jia, L., Zhou, T., Xu, J., Li, X., Dong, K., Huang, J., & Xu, Z. (2016). The enhanced catalytic activities of asymmetric Au-Ni nanoparticle decorated halloysite-based nanocomposite for the degradation of organic dyes. Nanoscale Research Letters, 11(1), 1–7.CrossRefGoogle ScholarPubMed
Jia, P., Ma, Y., Rahman, R., & Ma, Y. (2011). Synthesis of Magnetic Ferriferrous Oxide/Halloysite Composite. Integrated Ferroelectrics, 127(1), 116–120.CrossRefGoogle Scholar
Jia, X., Xu, M., Wang, Y., Ran, D., Yang, S., & Zhang, M. (2013). Polydopamine-based molecular imprinting on silica-modified magnetic nanoparticles for recognition and separation of bovine hemoglobin. The Analyst, 138(2), 651–658.CrossRefGoogle ScholarPubMed
Jiang, L., Zhang, C., Wei, J., Tjiu, W., Pan, J., Chen, Y., & Liu, T. (2014a). Surface modifications of halloysite nanotubes with superparamagnetic Fe3O4 nanoparticles and carbonaceous layers for efficient adsorption of dyes in water treatment. Chemical Research in Chinese Universities, 30(6), 971–977. https://doi.org/10.1007/s40242-014-4218-4CrossRefGoogle Scholar
Jiang, L., Zhang, C., Wei, J., Tjiu, W., Pan, J., Chen, Y., & Liu, T. (2014b). Surface modifications of halloysite nanotubes with superparamagnetic Fe3O4 nanoparticles and carbonaceous layers for efficient adsorption of dyes in water treatment. Chemical Research in Chinese Universities, 30(6), 971–977.CrossRefGoogle Scholar
Jomova, K., Jenisova, Z., Feszterova, M., Baros, S., Liska, J., Hudecova, D., Rhodes, C. J., & Valko, M. (2011). Arsenic: Toxicity, oxidative stress and human disease. Journal of Applied Toxicology, 31(2), 95–107.CrossRefGoogle Scholar
Joussein, E., Petit, S., Churchman, J., Theng, B., Righi, D., & Delvaux, B. (2005). Halloysite clay minerals–A review. Clay Minerals, 40, 383–426.CrossRefGoogle Scholar
Kadam, A. A., Jang, J., & Lee, D. S. (2017). Supermagnetically tuned halloysite nanotubes functionalized with aminosilane for covalent laccase immobilization. ACS Applied Materials & Interfaces, 9(18), 15492–15501.CrossRefGoogle ScholarPubMed
Kadam, A. A., Jang, J., Jee, S. C., Sung, J.-S., & Lee, D. S. (2018). Chitosan-functionalized supermagnetic halloysite nanotubes for covalent laccase immobilization. Carbohydrate Polymers, 194, 208–216.CrossRefGoogle ScholarPubMed
Kadam, A. A., Sharma, B., Shinde, S. K., Ghodake, G. S., Saratale, G. D., Saratale, R. G., Kim, D. Y., & Sung, J. S. (2020a). Thiolation of Chitosan Loaded over Super-Magnetic Halloysite Nanotubes for Enhanced Laccase Immobilization. Nanomaterials, 10(12), 2560.CrossRefGoogle ScholarPubMed
Kadam, A. A., Shinde, S. K., Ghodake, G. S., Saratale, G. D., Saratale, R. G., Sharma, B., Hyun, S., & Sung, J. S. (2020b). Chitosan-Grafted Halloysite Nanotubes-Fe3O4 Composite for Laccase-Immobilization and Sulfamethoxazole-Degradation. Polymers, 12(10), 2221.CrossRefGoogle Scholar
Kharissova, O. V., Dias, H. R., & Kharisov, B. I. (2015). Magnetic adsorbents based on micro-and nano-structured materials. RSC Advances, 5(9), 6695–6719.CrossRefGoogle Scholar
Khunová, V., Šafařík, I., Škrátek, M., Kelnar, I., & Tomanová, K. (2016). Biodegradable polymer nanocomposites based on natural nanotubes: Effect of magnetically modified halloysite on the behaviour of polycaprolactone. Clay Minerals, 51(3), 435–444.CrossRefGoogle Scholar
Khunová, V., Pavliňáková, V., Škrátek, M., Šafařík, I., & Pavliňák, D. (2018). Magnetic halloysite reinforced biodegradable nanofibres: new challenge for medical applications. AIP Conference Proceedings.CrossRefGoogle Scholar
Kim, M., Jee, S. C., Sung, J.-S., & Kadam, A. A. (2018). Anti-proliferative applications of laccase immobilized on super-magnetic chitosan-functionalized halloysite nanotubes. International Journal of Biological Macromolecules, 118, 228–237.CrossRefGoogle ScholarPubMed
Konnova, S., Lvov, Y., & Fakhrullin, R. (2016). Magnetic halloysite nanotubes for yeast cell surface engineering. Clay Minerals, 51(3), 429–433.CrossRefGoogle Scholar
Kurmoo, M. (2009). Magnetic metal–organic frameworks. Chemical Society Reviews, 38(5), 1353–1379.CrossRefGoogle ScholarPubMed
Lee, Y.-J., Lee, S.-C., Jee, S. C., Sung, J.-S., & Kadam, A. A. (2019). Surface functionalization of halloysite nanotubes with supermagnetic iron oxide, chitosan and 2-D calcium-phosphate nanoflakes for synergistic osteoconduction enhancement of human adipose tissue-derived mesenchymal stem cells. Colloids and Surfaces b: Biointerfaces, 173, 18–26.CrossRefGoogle ScholarPubMed
Li, F., Huang, Y., Huang, K., Lin, J., & Huang, P. (2020a). Functional magnetic graphene composites for biosensing. International Journal of Molecular Sciences, 21(2), 390.CrossRefGoogle ScholarPubMed
Li, G., Zha, J., Niu, M., Hu, F., Hui, X., Tang, T., Fizir, M., & He, H. (2018a). Bifunctional monomer molecularly imprinted sol-gel polymers based on the surface of magnetic halloysite nanotubes as an effective extraction approach for norfloxacin. Applied Clay Science, 162, 409–417.CrossRefGoogle Scholar
Li, L., Wang, F., Lv, Y., Liu, J., Zhang, D., & Shao, Z. (2018b). Halloysite nanotubes and Fe3O4 nanoparticles enhanced adsorption removal of heavy metal using electrospun membranes. Applied Clay Science, 161, 225–234.CrossRefGoogle Scholar
Li, X., Chen, J., Liu, H., Deng, Z., Li, J., Ren, T., Huang, L., Chen, W., Yang, Y., & Zhong, S. (2019). β-Cyclodextrin coated and folic acid conjugated magnetic halloysite nanotubes for targeting and isolating of cancer cells. Colloids and Surfaces B: Biointerfaces, 181, 379–388.CrossRefGoogle ScholarPubMed
Li, X., Liu, H., Deng, Z., Chen, W., Li, T., Zhang, Y., He, Y., Tan, Z., & Zhong, S. (2020b). PEGylated Thermo-Sensitive Bionic Magnetic Core-Shell Structure Molecularly Imprinted Polymers Based on Halloysite Nanotubes for Specific Adsorption and Separation of Bovine Serum Albumin. Polymers, 12(3), 536.CrossRefGoogle ScholarPubMed
Li, Y., Yuan, X., Jiang, L., Dai, H., Zhao, Y., Guan, X., Bai, J., & Wang, H. (2022). Manipulation of halloysite clay nanotube lumen for environmental remediation: A review. Environmental Science: Nano.Google Scholar
Liang, M., Chen, R., Xian, Y., Hu, J., Hou, X., Wang, B., Wu, Y., & Wang, L. (2021). Determination of bongkrekic acid and isobongkrekic acid in rice noodles by HPLC-Orbitrap HRMS technology using magnetic halloysite nanotubes. Food chemistry, 344, 128682.CrossRefGoogle ScholarPubMed
Liu, M., Jia, Z., Jia, D., & Zhou, C. (2014). Recent advance in research on halloysite nanotubes-polymer nanocomposite. Progress in Polymer Science, 39(8), 1498–1525.CrossRefGoogle Scholar
Liu, W., Fizir, M., Hu, F., Li, A., Hui, X., Zha, J., & He, H. (2018a). Mixed hemimicelle solid-phase extraction based on magnetic halloysite nanotubes and ionic liquids for the determination and extraction of azo dyes in environmental water samples. Journal of Chromatography A, 1551, 10–20.CrossRefGoogle ScholarPubMed
Liu, W., Wang, R., Hu, F., Wu, P., Huang, T., Fizir, M., & He, H. (2018b). Novel mixed hemimicelles based on non-ionic surfactant–imidazolium ionic liquid and magnetic halloysite nanotubes as efficient approach for analytical determination. Analytical and Bioanalytical Chemistry, 410(28), 7357–7371.CrossRefGoogle Scholar
López-López, M., Durán, J., Delgado, A., & González-Caballero, F. (2005). Stability and magnetic characterization of oleate-covered magnetite ferrofluids in different non-polar carriers. Journal of Colloid and Interface Science, 291(1), 144–151.CrossRefGoogle Scholar
Lvov, Y. M., DeVilliers, M. M., & Fakhrullin, R. F. (2016). The application of halloysite tubule nanoclay in drug delivery. Expert Opinion on Drug Delivery, 13(7), 977–986. https://doi.org/10.1517/17425247.2016.1169271CrossRefGoogle ScholarPubMed
Lvov, Y. M., Shchukin, D. G., Mohwald, H., & Price, R. R. (2008). Halloysite clay nanotubes for controlled release of protective agents. ACS Nano, 2(5), 814–820. https://doi.org/10.1021/nn800259qCrossRefGoogle ScholarPubMed
Ma, P., Zhou, Z., Dai, J., Qin, L., Ye, X., Chen, X., Xie, A., Yan, Y., & Li, C. (2016a). A biomimetic Setaria viridisinspired imprinted nanoadsorbent: green synthesis and application to the highly selective and fast removal of sulfamethazine. RSC Advances, 6(12), 9619–9630. https://doi.org/10.1039/c5ra18715jCrossRefGoogle Scholar
Ma, W., Dai, J., Dai, X., Da, Z., & Yan, Y. (2016b). Preparation and characterization of chitosan/halloysite magnetic microspheres and their application for removal of tetracycline from an aqueous solution. Desalination and Water Treatment, 57(9), 4162–4173. https://doi.org/10.1080/19443994.2014.988653CrossRefGoogle Scholar
Maensiri, S., Masingboon, C., Boonchom, B., & Seraphin, S. (2007). A simple route to synthesize nickel ferrite (NiFe2O4) nanoparticles using egg white. Scripta Materialia, 56(9), 797–800.CrossRefGoogle Scholar
Majidi, S., Zeinali Sehrig, F., Farkhani, S. M., Soleymani Goloujeh, M., & Akbarzadeh, A. (2016). Current methods for synthesis of magnetic nanoparticles. Artificial Cells, Nanomedicine, and Biotechnology, 44(2), 722–734.CrossRefGoogle ScholarPubMed
Maleki, A., Hajizadeh, Z., & Firouzi-Haji, R. (2018). Ecofriendly functionalization of magnetic halloysite nanotube with SO3H for synthesis of dihydropyrimidinones. Microporous and Mesoporous Materials, 259, 46–53.CrossRefGoogle Scholar
Maleki, A., Hajizadeh, Z., & Salehi, P. (2019). Mesoporous halloysite nanotubes modified by CuFe2O4 spinel ferrite nanoparticles and study of its application as a novel and efficient heterogeneous catalyst in the synthesis of pyrazolopyridine derivatives. Scientific Reports, 9(1), 1–8.CrossRefGoogle ScholarPubMed
Mateo-Sagasta, J., Zadeh, S. M., Turral, H., & Burke, J. (2017). Water pollution from agriculture: a global review. Executive summary. Food and Agriculture Organization of the United Nations: https://www.fao.org/3/i7754e/i7754e.pdf.Google Scholar
Maziarz, P., & Matusik, J. (2017). Halloysite composites with Fe3O4 particles: The effect of impregnation on the removal of aqueous Cd (II) and Pb (II). Mineralogia, 48, 107–126.CrossRefGoogle Scholar
Maziarz, P., Matusik, J., Leiviskä, T., Strączek, T., Kapusta, C., Woch, W. M., Tokarz, W., & Gorniak, K. (2019). Toward highly effective and easily separable halloysite-containing adsorbents: The effect of iron oxide particles impregnation and new insight into As (V) removal mechanisms. Separation and Purification Technology, 210, 390–401.CrossRefGoogle Scholar
Mirbagheri, N. S., & Sabbaghi, S. (2018). A natural kaolin/γ-Fe2O3 composite as an efficient nano-adsorbent for removal of phenol from aqueous solutions. Microporous and Mesoporous Materials, 259, 134–141.CrossRefGoogle Scholar
Mu, B., Wang, W., Zhang, J., & Wang, A. (2014a). Superparamagnetic sandwich structured silver/halloysite nanotube/Fe3O4 nanocomposites for 4-nitrophenol reduction. RSC Advances, 4(74), 39439–39445.CrossRefGoogle Scholar
Mu, B., Zhang, W., & Wang, A. (2014b). Facile fabrication of superparamagnetic coaxial gold/halloysite nanotubes/Fe3O4 nanocomposites with excellent catalytic property for 4-nitrophenol reduction. Journal of Materials Science, 49(20), 7181–7191.CrossRefGoogle Scholar
Naumenko, E. A., Guryanov, I. D., Yendluri, R., Lvov, Y. M., & Fakhrullin, R. F. (2016). Clay nanotube-biopolymer composite scaffolds for tissue engineering. Nanoscale, 8(13), 7257–7271. https://doi.org/10.1039/c6nr00641hCrossRefGoogle ScholarPubMed
Nguyen, T. K. L., Cao, X. T., Park, C., & Lim, K. T. (2017). Preparation, characterization and application of magnetic halloysite nanotubes for dye removal. Molecular Crystals and Liquid Crystals, 644(1), 153–159.CrossRefGoogle Scholar
Nonkumwong, J., Ananta, S., & Srisombat, L. (2016). Effective removal of lead (II) from wastewater by amine-functionalized magnesium ferrite nanoparticles. RSC Advances, 6(53), 47382–47393.CrossRefGoogle Scholar
Pan, J., Yao, H., Xu, L., Ou, H., Huo, P., Li, X., & Yan, Y. (2011). Selective Recognition of 2,4,6-Trichlorophenol by Molecularly Imprinted Polymers Based on Magnetic Halloysite Nanotubes Composites. The Journal of Physical Chemistry C, 115(13), 5440–5449. https://doi.org/10.1021/jp111120xCrossRefGoogle Scholar
Pan, J., Hang, H., Dai, X., Dai, J., Huo, P., & Yan, Y. (2012a). Switched recognition and release ability of temperature responsive molecularly imprinted polymers based on magnetic halloysite nanotubes. Journal of Materials Chemistry, 22(33), 17167. https://doi.org/10.1039/c2jm32821fCrossRefGoogle Scholar
Pan, J., Wang, B., Dai, J., Dai, X., Hang, H., Ou, H., & Yan, Y. (2012b). Selective recognition of 2,4,5-trichlorophenol by temperature responsive and magnetic molecularly imprinted polymers based on halloysite nanotubes. Journal of Materials Chemistry, 22(8), 3360. https://doi.org/10.1039/c1jm14825gCrossRefGoogle Scholar
Pan, J., Zhu, W., Dai, X., Yan, X., Gan, M., Li, L., Hang, H., & Yan, Y. (2014). Magnetic molecularly imprinted microcapsules derived from Pickering emulsion polymerization and their novel adsorption characteristics for λ-cyhalothrin. RSC Advances, 4(9), 4435–4443.CrossRefGoogle Scholar
Pei, Y., Wang, J., Wu, K., Xuan, X., & Lu, X. (2009). Ionic liquid-based aqueous two-phase extraction of selected proteins. Separation and Purification Technology, 64(3), 288–295.CrossRefGoogle Scholar
Polat, G., & Açιkel, Y. S. (2019). Synthesis and Characterization of Magnetic Halloysite-Alginate Beads for the Removal of Lead (II) Ions from Aqueous Solutions. Journal of Polymers and the Environment, 27(9), 1971–1987.CrossRefGoogle Scholar
Rajabi, H. R., Roushani, M., & Shamsipur, M. (2013). Development of a highly selective voltammetric sensor for nanomolar detection of mercury ions using glassy carbon electrode modified with a novel ion imprinted polymeric nanobeads and multi-wall carbon nanotubes. Journal of Electroanalytical Chemistry, 693, 16–22.CrossRefGoogle Scholar
Riahi-Madvaar, R., Taher, M. A., & Fazelirad, H. (2017). Synthesis and characterization of magnetic halloysite-iron oxide nanocomposite and its application for naphthol green B removal. Applied Clay Science, 137, 101–106. https://doi.org/10.1016/j.clay.2016.12.019CrossRefGoogle Scholar
Rios, A., Zougagh, M., & Bouri, M. (2013). Magnetic (nano) materials as an useful tool for sample preparation in analytical methods. A Review. Analytical Methods, 5(18), 4558–4573.CrossRefGoogle Scholar
Rouhi, M., Babamoradi, M., Hajizadeh, Z., Maleki, A., & Maleki, S. T. (2020). Design and performance of polypyrrole/halloysite nanotubes/Fe3O4/Ag/Co nanocomposite for photocatalytic degradation of methylene blue under visible light irradiation. Optik, 212, 164721.CrossRefGoogle Scholar
Sadjadi, S., Lazzara, G., Heravi, M. M., & Cavallaro, G. (2019). Pd supported on magnetic carbon coated halloysite as hydrogenation catalyst: Study of the contribution of carbon layer and magnetization to the catalytic activity. Applied Clay Science, 182, 105299.CrossRefGoogle Scholar
Selvaraj, M., Rajalakshmi, K., Ahn, D.-H., Yoon, S.-J., Nam, Y.-S., Lee, Y., Xu, Y., Song, J. W., & Lee, K. B. (2021). Tetraphenylethene-based fluorescent probe with aggregation-induced emission behavior for Hg2+ detection and its application. Analytica Chimica Acta, 1148, 238178.CrossRefGoogle ScholarPubMed
Shah, A., Nisar, A., Khan, K., Nisar, J., Niaz, A., Ashiq, M. N., & Akhter, M. S. (2019). Amino acid functionalized glassy carbon electrode for the simultaneous detection of thallium and mercuric ions. Electrochimica Acta, 321, 134658.CrossRefGoogle Scholar
Shen, X., Zhou, T., & Ye, L. (2012). Molecular imprinting of protein in Pickering emulsion. Chemical Communications, 48(66), 8198–8200.CrossRefGoogle ScholarPubMed
Shende, P., & Shah, P. (2021). Carbohydrate-based magnetic nanocomposites for effective cancer treatment. International Journal of Biological Macromolecules, 175, 281–293. https://doi.org/10.1016/j.ijbiomac.2021.02.044CrossRefGoogle ScholarPubMed
Shi, Z., Pang, W., Chen, M., Wu, Y., & Zhang, H. (2020). Polyaniline-Modified Magnetic Halloysite Nanotube-Based Magnetic Micro-Solid-Phase Extraction for the Analysis of Polycyclic Aromatic Hydrocarbons in Beer Samples by Gas Chromatography-Mass Spectrometry. Food Analytical Methods, 1–12.Google Scholar
Siddeeg, S. M., Tahoon, M. A., Alsaiari, N. S., Shabbir, M., & Rebah, F. B. (2021). Application of Functionalized Nanomaterials as Effective Adsorbents for the Removal of Heavy Metals from Wastewater: A Review. Current Analytical Chemistry, 17(1), 4–22.CrossRefGoogle Scholar
Sillu, D., & Agnihotri, S. (2019). Cellulase immobilization onto magnetic halloysite nanotubes: Enhanced enzyme activity and stability with high cellulose saccharification. ACS Sustainable Chemistry & Engineering, 8(2), 900–913.CrossRefGoogle Scholar
Sohrabi, M. R., Matbouie, Z., Asgharinezhad, A. A., & Dehghani, A. (2013). Solid phase extraction of Cd (II) and Pb (II) using a magnetic metal-organic framework, and their determination by FAAS. Microchimica Acta, 180(7–8), 589–597.CrossRefGoogle Scholar
Song, X., Wang, Y., Zhou, L., Luo, X., & Liu, J. (2021). Halloysite nanotubes stabilized polyurethane foam carbon coupled with iron oxide for high-efficient and fast treatment of arsenic (III/V) wastewater. Chemical Engineering Research and Design, 165, 298–307.CrossRefGoogle Scholar
Song, X., Zhou, L., Zhang, Y., Chen, P., & Yang, Z. (2019). A novel cactus-like Fe3O4/Halloysite nanocomposite for arsenite and arsenate removal from water. Journal of Cleaner Production, 224, 573–582.CrossRefGoogle Scholar
Sun, Y., Chen, J., Li, Y., Li, H., Zhu, X., Hu, Y., Huang, S., Li, J., & Zhong, S. (2016). Bio-inspired magnetic molecularly imprinted polymers based on Pickering emulsions for selective protein recognition. New Journal of Chemistry, 40(10), 8745–8752.CrossRefGoogle Scholar
Taghizadeh, M., Asgharinezhad, A. A., Samkhaniany, N., Tadjarodi, A., Abbaszadeh, A., & Pooladi, M. (2014). Solid phase extraction of heavy metal ions based on a novel functionalized magnetic multi-walled carbon nanotube composite with the aid of experimental design methodology. Microchimica Acta, 181(5–6), 597–605.CrossRefGoogle Scholar
Tian, X., Wang, W., Tian, N., Zhou, C., Yang, C., & Komarneni, S. (2016). Cr(VI) reduction and immobilization by novel carbonaceous modified magnetic Fe3O4/halloysite nanohybrid. Journal of Hazardous Materials, 309, 151–156. https://doi.org/10.1016/j.jhazmat.2016.01.081CrossRefGoogle ScholarPubMed
Todorov, P. T., & Ilieva, E. N. (2006). Contamination with uranium from natural and antropological sources. Romanian Journal of Physics, 51(1/2), 27.Google Scholar
Tsoufis, T., Katsaros, F., Kooi, B., Bletsa, E., Papageorgiou, S., Deligiannakis, Y., & Panagiotopoulos, I. (2017). Halloysite nanotube-magnetic iron oxide nanoparticle hybrids for the rapid catalytic decomposition of pentachlorophenol. Chemical Engineering Journal, 313, 466–474.CrossRefGoogle Scholar
Türkeş, E., & Açιkel, Y. S. (2020). Synthesis and characterization of magnetic halloysite–chitosan nanocomposites: Use in the removal of methylene blue in wastewaters. International Journal of Environmental Science and Technology, 17(3), 1281–1294.CrossRefGoogle Scholar
Tušar, N., Kaucic, V., & Logar, N. (2013). Chapter 15 Functionalized Porous Silicates as Catalysts for Water and Air Purification. New and Future Developments in Catalysis; Suib, S. L., Ed.; Elsevier: Amsterdam, The Netherlands, 365–383.CrossRefGoogle Scholar
Vahidhabanu, S., Adeogun, A. I., & Babu, B. R. (2019). Biopolymer-grafted, magnetically tuned halloysite nanotubes as efficient and recyclable spongelike adsorbents for anionic azo dye removal. ACS Omega, 4(1), 2425–2436.CrossRefGoogle ScholarPubMed
Wan, X. Y., Zhan, Y. Q., Long, Z. H., Zeng, G. Y., & He, Y. (2017). Core@double-shell structured magnetic halloysite nanotube nano-hybrid as efficient recyclable adsorbent for methylene blue removal. Chemical Engineering Journal, 330, 491–504. https://doi.org/10.1016/j.cej.2017.07.178CrossRefGoogle Scholar
Wang, F., Ni, X., Zhang, J., Zhang, Q., Jia, H., He, H., & Dramou, P. (2022). Novel composite nanomaterials based on magnetic molecularly imprinted polymers for selective extraction and determination of rutin in fruit juice. Food Chemistry, 381, 132275.CrossRefGoogle ScholarPubMed
Wang, H., He, J., Song, L., Zhang, Y., Xu, M., Huang, Z., Jin, L., Ba, X., Li, Y., You, L., & Zhang, S. (2020a). Etching of Halloysite Nanotubes Hollow Imprinted Materials as Adsorbent for Extracting of Zearalenone from Grain Samples. Microchemical Journal, 104953.CrossRefGoogle Scholar
Wang, R., Wu, P., Cui, Y., Fizir, M., Shi, J., & He, H. (2020b). Selective recognition and enrichment of sterigmatocystin in wheat by thermo-responsive imprinted polymer based on magnetic halloysite nanotubes. Journal of Chromatography A, 460952.CrossRefGoogle Scholar
Wu, A., Zhao, X., Wang, J., Tang, Z., Zhao, T., Niu, L., Yu, W., Yang, C., Fang, M., Lv, H., & Liu, S. (2021). Application of solid-phase extraction based on magnetic nanoparticle adsorbents for the analysis of selected persistent organic pollutants in environmental water: a review of recent advances. Critical Reviews in Environmental Science and Technology, 51(1), 44–112.CrossRefGoogle Scholar
Xia, S., Song, Z., Jeyakumar, P., Shaheen, S. M., Rinklebe, J., Ok, Y. S., Bolan, N., & Wang, H. (2019). A critical review on bioremediation technologies for Cr (VI)-contaminated soils and wastewater. Critical Reviews in Environmental Science and Technology, 49(12), 1027–1078.CrossRefGoogle Scholar
Xie, Y., Qian, D., Wu, D., & Ma, X. (2011). Magnetic halloysite nanotubes/iron oxide composites for the adsorption of dyes. Chemical Engineering Journal, 168(2), 959–963.CrossRefGoogle Scholar
Yamina, A. M., Fizir, M., Itatahine, A., He, H., & Dramou, P. (2018). Preparation of multifunctional PEG-graft-halloysite nanotubes for controlled drug release, tumor cell targeting, and bio-imaging. Colloids and Surfaces b: Biointerfaces, 170, 322–329.CrossRefGoogle ScholarPubMed
Yang, S., Zong, P., Hu, J., Sheng, G., Wang, Q., & Wang, X. (2013a). Fabrication of β-cyclodextrin conjugated magnetic HNT/iron oxide composite for high-efficient decontamination of U (VI). Chemical Engineering Journal, 214, 376–385.CrossRefGoogle Scholar
Yang, W., Jiao, F., Zhou, L., Chen, X., & Jiang, X. (2013b). Molecularly imprinted polymers coated on multi-walled carbon nanotubes through a simple indirect method for the determination of 2, 4-dichlorophenoxyacetic acid in environmental water. Applied Surface Science, 284, 692–699.CrossRefGoogle Scholar
Yendluri, R., Lvov, Y., de Villiers, M. M., Vinokurov, V., Naumenko, E., Tarasova, E., & Fakhrullin, R. (2017). Paclitaxel Encapsulated in Halloysite Clay Nanotubes for Intestinal and Intracellular Delivery. Journal of Pharmaceutical Science, 106(10), 3131–3139. https://doi.org/10.1016/j.xphs.2017.05.034CrossRefGoogle ScholarPubMed
Yu, L., Wang, H., Zhang, Y., Zhang, B., & Liu, J. (2016). Recent advances in halloysite nanotube derived composites for water treatment. Environmental Science-Nano, 3(1), 28–44. https://doi.org/10.1039/c5en00149hCrossRefGoogle Scholar
Yu, M., Wang, L., Hu, L., Li, Y., Luo, D., & Mei, S. (2019). Recent applications of magnetic composites as extraction adsorbents for determination of environmental pollutants. TrAC Trends in Analytical Chemistry, 119, 115611.CrossRefGoogle Scholar
Zain, M. E. (2011). Impact of mycotoxins on humans and animals. Journal of Saudi Chemical Society, 15(2), 129–144.CrossRefGoogle Scholar
Zango, Z. U., Sambudi, N. S., Jumbri, K., Ramli, A., Abu Bakar, N. H. H., Saad, B., Rozaini, M. N. H., Isiyaka, H. A., Osman, A. M., & Sulieman, A. (2020). An Overview and Evaluation of Highly Porous Adsorbent Materials for Polycyclic Aromatic Hydrocarbons and Phenols Removal from Wastewater. Water, 12(10), 2921.CrossRefGoogle Scholar
Zare Pirhaji, J., Moeinpour, F., Mirhoseini Dehabadi, A., & Yasini Ardakani, S. A. (2020a). Experimental study and modelling of effective parameters on removal of Cd (II) from water by halloysite/graphene quantum dots magnetic nanocomposite as an adsorbent using response surface methodology. Applied Organometallic Chemistry, 34(7), e5640.CrossRefGoogle Scholar
Zare Pirhaji, J., Moeinpour, F., Mirhoseini Dehabadi, A., & Yasini Ardakani, S. A. (2020b). Synthesis and characterization of halloysite/graphene quantum dots magnetic nanocomposite as a new adsorbent for Pb (II) removal from water. Journal of Molecular Liquids, 300, 112345.CrossRefGoogle Scholar
Zeng, X., Sun, Z., Wang, H., Wang, Q., & Yang, Y. (2016). Supramolecular gel composites reinforced by using halloysite nanotubes loading with in-situ formed Fe3O4 nanoparticles and used for dye adsorption. Composites Science and Technology, 122, 149–154.CrossRefGoogle Scholar
Zhang, A.-B., Liu, S.-T., Yan, K.-K., Ye, Y., & Chen, X.-G. (2014). Facile preparation of MnFe2O4/halloysite nanotubular encapsulates with enhanced magnetic and electromagnetic performances. RSC Advances, 4(26), 13565–13568.CrossRefGoogle Scholar
Zhang, H., Lai, H., Wu, X., Li, G., & Hu, Y. (2020). CoFe2O4@HNTs/AuNPs substrate for rapid magnetic solid-phase extraction and efficient SERS detection of complex samples all-in-one. Analytical Chemistry, 92(6), 4607–4613.CrossRefGoogle ScholarPubMed
Zhang, R., Zhu, X., Liu, Y., Cai, Y., Han, Q., Zhang, T., & Li, Y. (2019). The Application of Halloysite Nanotubes/Fe3O4 Composites Nanoparticles in Polyvinylidene Fluoride Membranes for Dye Solution Removal. Journal of Inorganic and Organometallic Polymers and Materials, 29(5), 1625–1636.CrossRefGoogle Scholar
Zhang, Y., Tang, A., Yang, H., & Ouyang, J. (2016). Applications and interfaces of halloysite nanocomposites. Applied Clay Science, 119, 8–17. https://doi.org/10.1016/j.clay.2015.06.034CrossRefGoogle Scholar
Zheng, P., Du, Y., & Ma, X. (2015). Selective fabrication of iron oxide particles in halloysite lumen. Materials Chemistry and Physics, 151, 14–17.CrossRefGoogle Scholar
Zhitkovich, A. (2011). Chromium in drinking water: Sources, metabolism, and cancer risks. Chemical Research in Toxicology, 24(10), 1617–1629.CrossRefGoogle ScholarPubMed
Zhong, S., Zhou, C., Zhang, X., Zhou, H., Li, H., Zhu, X., & Wang, Y. (2014). A novel molecularly imprinted material based on magnetic halloysite nanotubes for rapid enrichment of 2,4-dichlorophenoxyacetic acid in water. Journal of Hazardous Materials, 276, 58–65. https://doi.org/10.1016/j.jhazmat.2014.05.013CrossRefGoogle Scholar
Zhou, T., Jia, L., Luo, Y.-F., Xu, J., Chen, R.-H., Ge, Z.-J., Ma, T. L., Chen, H., & Zhu, T. F. (2016). Multifunctional nanocomposite based on halloysite nanotubes for efficient luminescent bioimaging and magnetic resonance imaging. International Journal of Nanomedicine, 11, 4765.CrossRefGoogle ScholarPubMed
Zhou, Y., Lu, J., Zhou, Y., & Liu, Y. (2019). Recent advances for dyes removal using novel adsorbents: A review. Environmental Pollution, 252, 352–365.CrossRefGoogle ScholarPubMed
Zhu, J., Wei, S., Chen, M., Gu, H., Rapole, S. B., Pallavkar, S., Ho, T. C., Hopper, J., & Guo, Z. (2013). Magnetic nanocomposites for environmental remediation. Advanced Powder Technology, 24(2), 459–467.CrossRefGoogle Scholar
Zhu, K., Duan, Y., Wang, F., Gao, P., Jia, H., Ma, C., & Wang, C. (2017). Silane-modified halloysite/Fe3O4 nanocomposites: Simultaneous removal of Cr (VI) and Sb (V) and positive effects of Cr (VI) on Sb (V) adsorption. Chemical Engineering Journal, 311, 236–246.CrossRefGoogle Scholar
Zhu, X., Li, H., Zhou, H., & Zhong, S. (2015). Fabrication and evaluation of protein imprinted polymer based on magnetic halloysite nanotubes. RSC Advances, 5(81), 66147–66154. https://doi.org/10.1039/c5ra09740aCrossRefGoogle Scholar
Zhu, X., Fan, X., Wang, Y., Zhai, Q., Hu, M., Li, S., & Jiang, Y. (2020). Amino modified magnetic halloysite nanotube supporting chloroperoxidase immobilization: enhanced stability, reusability, and efficient degradation of pesticide residue in wastewater. Bioprocess and Biosystems Engineering, 1–11.Google Scholar
Zhu, X., Fan, X., Wang, Y., Zhai, Q., Hu, M., Li, S., & Jiang, Y. (2021). Amino modified magnetic halloysite nanotube supporting chloroperoxidase immobilization: Enhanced stability, reusability, and efficient degradation of pesticide residue in wastewater. Bioprocess and Biosystems Engineering, 44(3), 483–493.CrossRefGoogle ScholarPubMed