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Ionic liquids-kaolinite nanostructured materials. Intercalation of pyrrolidinium salts

Published online by Cambridge University Press:  01 January 2024

Sadok Letaief  and
Christian Detellier
Sadok Letaief*
Affiliation:
Centre for Catalysis Research and Innovation, and Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada K1N 6N5
Christian Detellier
Affiliation:
Centre for Catalysis Research and Innovation, and Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada K1N 6N5
*
* E-mail address of corresponding author: lsado@science.uottawa.ca
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Abstract

Ionic liquids intercalated in kaolinite constitute a novel class of nanostructured material. Kaolinite-pyrrolidinium halide intercalates have been prepared successfully by reacting the pyrrolidinium salts with kaolinite which was preintercalated with dimethyl sulfoxide (DMSO) using the melt condition under N2. X-ray diffraction, 13C magic angle spinning nuclear magnetic resonance, differential thermal analysis (DTA)-thermal gravimetric analysis, and Fourier transform infrared spectroscopy confirm the displacement of DMSO during the intercalation process. Based on results from the various characterization techniques, a structural model is proposed in which one mole of the pyrrolidinium salt covers two or three structural units of kaolinite, depending on the structure and size of the salt. The thermal stability was improved remarkably after intercalation of the pyrrolidinium salts, compared to the pre-intercalate. The DTA-TGA data show that the largest number of organic units released and decomposed, occurs under N2 flow, at temperatures ranging from 260 to 340°C, depending on the nature of the intercalated organic salts.

Keywords

13C CP/MAS NMRFTIRIntercalationIonic LiquidsKaoliniteNanohybrid MaterialsNanostructured MaterialsPyrrolidinium29Si CP/MAS NMRTGAXRD
Type
Research Article
Information
Clays and Clay Minerals , Volume 56 , Issue 1 , February 2008 , pp. 82 - 89
Copyright
Copyright © 2008, The Clay Minerals Society

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