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Magnetic Titanium-Pillared Clays (Ti-M-PILC): Magnetic Studies and Mössbauer Spectroscopy

Published online by Cambridge University Press:  01 January 2024

Cherifa Bachir ,
Yanhua Lan ,
Valeriu Mereacre ,
Annie K. Powell ,
Christian Bender Koch  and
Peter G. Weidler
Cherifa Bachir*
Affiliation:
Institute of Functional Interfaces, Forschungszentrum Karlsruhe, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany Department of Industrial Chemistry, Faculty of Sciences, B.P. 1505 EL-Mnaouer, University of Sciences and Technologies USTO ‘Mohamed Boudiaf’, Oran, Algeria
Yanhua Lan
Affiliation:
Institute for Inorganic Chemistry, University of Karlsruhe (TH), Engesserstr. 15 Geb. 30.45, D-76131 Karlsruhe, Germany
Valeriu Mereacre
Affiliation:
Institute for Inorganic Chemistry, University of Karlsruhe (TH), Engesserstr. 15 Geb. 30.45, D-76131 Karlsruhe, Germany
Annie K. Powell
Affiliation:
Institute for Inorganic Chemistry, University of Karlsruhe (TH), Engesserstr. 15 Geb. 30.45, D-76131 Karlsruhe, Germany
Christian Bender Koch
Affiliation:
Department of Basic Sciences and Environment, Faculty of Life Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg, Denmark
Peter G. Weidler
Affiliation:
Institute of Functional Interfaces, Forschungszentrum Karlsruhe, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany
*
* E-mail address of corresponding author: Cherifa.Bachir@ifg.fzk.de, bachir_c04@yahoo.fr, peter.weidler@ifg.fzk.de
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Abstract

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Pillared clays (PILCs) with magnetic properties are materials with potential for wide application in industry and the environment, but only a few studies of these types of materials have been carried out. The purpose of this study was to advance knowledge of the preparation and magnetic properties of pillared clays by examining in detail a series of magnetic Ti-pillared clays (Ti-M-PILCs). Samples were synthesized at ambient temperature by sodium borohydride reduction of ferrous ions added by ion-exchange to Ti-pillared montmorillonite (Ti-PILCs). The properties of the Ti-M-PILCs were investigated using a superconducting quantum interference device (SQUID) and Mössbauer spectroscopy. Hysteresis, zero-field-cooled (ZFC), and field-cooled (FC) regimes were measured on different precursor materials prepared by calcination of Ti-PILCs at temperatures between 200 and 600°C. Hysteresis loops, recorded between −7 and 7 T in the temperature range 200–300 K, were observed in most samples depending on the preparation of clays. The ZFC/FC measurements were made after heating from 2 to 300 Kunder an applied magnetic field of 39.8 kA m−1. The influence of the calcination temperature of the starting Ti-PILCs on the structural and magnetic properties of the Ti-M-PILCs was examined. The presence of two different Fe-alloy distributions was found; a dispersed one for the less-calcined Ti-PILCs and clusters for the more-calcined ones.

Keywords

Magnetic PropertiesMontmorilloniteMössbauer SpectroscopyTitanium Magnetic Pillared ClaysZFC/FC
Type
Research Article
Information
Clays and Clay Minerals , Volume 57 , Issue 4 , August 2009 , pp. 433 - 443
Copyright
Copyright © The Clay Minerals Society 2009

References

Booker, N.A. Keir, D. Priestley, A.J. Ritchie, C.B. Sudarmana, D.L. and Woods, M.A., 1991 Sewage clarification with magnetite particles Water Science and Technology 23 1703–1712 10.2166/wst.1991.0625.CrossRefGoogle Scholar
Brunauer, S. Emmett, P.H. and Teller, E., 1938 Adsorption of gases in multimolecular layers Journal of the American Chemical Society 60 309–319 10.1021/ja01269a023.CrossRefGoogle Scholar
Farmer, V.C., 1974 The Infrared Spectra of Minerals London Mineralogical Society 10.1180/mono-4.CrossRefGoogle Scholar
Kloprogge, J.T., 1998 Synthesis of smectites and porous pillared clays catalysts: a review Journal of Porous Materials 5 5–41 10.1023/A:1009625913781.CrossRefGoogle Scholar
Madejová, J. and Komadel, P., 2001 Baseline studies of the Clay Minerals Society source clays: Infrared methods Clays and Clay Minerals 49 410–432 10.1346/CCMN.2001.0490508.CrossRefGoogle Scholar
Mak, S.Y. and Chen, D.H., 2004 Fast adsorption of methylene blue on polyacrylic acid bound iron oxide magnetic nanoparticles Dyes Pigments 61 93–98 10.1016/j.dyepig.2003.10.008.CrossRefGoogle Scholar
Meier, L.P. and Kahr, G., 1999 Determination of the cation exchange capacity (CEC) of clay minerals using the complexes of copper (II) ion with triethylenetetraamine and tetraethylenepentamine Clays and Clay Minerals 47 386–388 10.1346/CCMN.1999.0470315.CrossRefGoogle Scholar
Morrish, A.H., 1965 The Physical Principles of Magnetism New York, London, Sydney John Wiley & Sons, Inc..Google Scholar
Moskowitz, B.M., 1991 Hitchhiker’s Guide to Magnetism USA The Environmental Magnetism Workshop, Institute for Rock Magnetism, University of Minnesota.Google Scholar
Naguib, N., Weidler, P.G., and Nüesch, R. (2003) Development of the application of magnetic micro-sorbents for the elimination of hazardous inorganic contaminants from natural waters. 10th Conference of the European Clay Groups Association, volume abstracts, p. 202.Google Scholar
Neimark, A.V. and Ravikovitch, P.I., 2001 Capillary condensation in MMS and pore structure characterization Microporous and Mesoporous Materials 44 697–707 10.1016/S1387-1811(01)00251-7.CrossRefGoogle Scholar
Oliveira, L.C.A. Rios, R.V.R.A. Fabris, J.D. Garg, V.K. Sapag, K. and Lago, R.M., 2002 Activated carbon/iron oxide magnetic composites for the adsorption of contaminants in water Carbon 40 2177–2183 10.1016/S0008-6223(02)00076-3.CrossRefGoogle Scholar
Oliveira, L.C.A. Rios, R.V.R.A. Fabris, J.D. Sapag, K. Garg, V.K. and Lago, R.M., 2003 Clay-iron oxide magnetic composites for the adsorption of contaminants in water Applied Clay Science 22 169–177 10.1016/S0169-1317(02)00156-4.CrossRefGoogle Scholar
Ravikovitch, P.I. and Neimark, A.V., 2001 Characterization of nanoporous materials from adsorption and desorption isotherms Colloids and Surfaces A: Physicochemical and Engineering Aspects 187 11–21 10.1016/S0927-7757(01)00614-8.CrossRefGoogle Scholar
Rozenson, I. and Heller-Kallai, L., 1976 Reduction and oxidation of Fe3+ in dioctahedral smectites — 1: Reduction with hydrazine and dithionate Clays and Clay Minerals 24 271–282 10.1346/CCMN.1976.0240601.CrossRefGoogle Scholar
Sterte, J., 1986 Synthesis and properties of titanium oxide cross-linked montmorillonite Clays and Clay Minerals 34 658–664 10.1346/CCMN.1986.0340606.CrossRefGoogle Scholar
Suzuki, M. Suzuki, I.S. and Walter, J., 2003 Quasi-two-dimensional magnetism in Ru and Rh metal layers sandwiched between grapheme sheets Physical Review B 67 094406 10.1103/PhysRevB.67.094406.CrossRefGoogle Scholar
Thommes, M. Smarsly, B. Groene, M. Ravikovitch, P.I. and Neimark, A.V., 2006 Adsorption hysteresis of nitrogen and argon in pore networks and characterization of novel micro-and mesoporous silicas Langmuir 22 756–764 10.1021/la051686h.CrossRefGoogle ScholarPubMed
Van Wonterghem, J. Morup, S. Koch, J.W. Charles, S.W. and Wells, S., 1986 Formation of ultra-fine amorphous alloy particles by reduction in aqueous solution Nature 322 622–623 10.1038/322622a0.CrossRefGoogle Scholar
Zhang, L. and Manthiram, A., 1996 Ambient temperature synthesis of fine metal particles in montmorillonite clay and their magnetic properties Nano Structured Materials 7 437–451 10.1016/0965-9773(96)00015-3.CrossRefGoogle Scholar
Zhang, Z.D. Yu, J.L. Zheng, J.G. Skorvanek, I. Kovac, J. Dong, X.L. Li, Z.J. Jin, S.R. Yang, H.C. Guo, Z.J. Liu, W. and Zhao, X.G., 2001 Structure and magnetic properties of boron-oxide-coated Fe(B) nanocapsules prepared by arc discharge in diborane Physical Review B 64 024404 10.1103/PhysRevB.64.024404.CrossRefGoogle Scholar