Volume 41 - Issue 4 - August 1993
Research Article
Analyses of Palygorskites and Associated Clays from the Jbel Rhassoul (Morocco): Chemical Characteristics and Origin of Formation
- Azzedine Chahi, Joelle Duplay, Jacques Lucas
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- 28 February 2024, pp. 401-411
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The “Formation Rouge” from the Jbel Rhassoul in Morocco is composed of detrital sediments which have a lacustrine origin. The clays contained in the less than 2 µm fraction of the sediments are detrital phengites and illites, illite/smectites or smectites, and palygorskite. Due to the presence of well preserved long fibers, the palygorskite could not have been transported. They are authigenic and must have formed directly by precipitation from solutions rich in Mg and Al. The detrital illites are impoverished in K and tetrahedral Al. The illite/smectites or smectites, on the contrary, are K-rich but have a low tetrahedral charge. They are also richer in Mg and Fe and have a different crystal size, composition, and crystallinity from the illites. They most probably formed by crystallization, similar to the palygorskites, directly from the solution. The Al could have been provided by the detrital illite, which may have been unstable in an alkaline environment and released K and Al to the solutions.
Charge Heterogeneity and Nanostructure of 2:1 Layer Silicates by High-Resolution Transmission Electron Microscopy
- P. B. Malla, M. Robert, L. A. Douglas, D. Tessier, S. Komarneni
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- 28 February 2024, pp. 412-422
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Several soil and reference smectites and vermiculites and one reference illite were examined by high-resolution transmission electron microscopy (HRTEM) to decipher the nanostructure and layer charge heterogeneity in these minerals. HRTEM results were compared with those obtained from powder X-ray diffraction (XRD) analysis. Samples were either exchanged with Na+ ions followed by equilibration with a very dilute solution of NaCl in a pressure membrane apparatus at 316 hPa (pF = 2.5) to see the effect of hydration and applied pressure on layer organization, or exchanged with dodecylammonium ions to see the expansion behavior. Oriented samples were embedded in a low viscosity resin and cut approximately 500 Å thick perpendicular to d(001) using an ultramicrotome fitted with a diamond knife. In general, Na-saturated soil clays possessed crystallites that were thinner (c-direction) and shorter (ab-direction) as compared with reference clays. In all cases, samples treated with dodecylammonium chloride exhibited nanostructures that were more disintegrated as compared with Na-saturated samples. In a soil vermiculite, dodecylammonium ion exchange showed frayed edges indicating the initiation of mica transformation to vermiculite from edge toward core. In a reference vermiculite (Transvaal) treated with dodecylammonium ions, in addition to completely expanded crystallites, a regular interstratification between expanded vermiculite and mica (phlogopite) layers was clearly observed in some crystallites. Such nanostructural details were not detected by XRD. HRTEM of the Na-treated illite showed thick crystallites having 10 Å layer separations, whereas the dodecylammonium-exchanged illite showed three types of layers with different degrees of expansion indicating charge heterogeneity in illite: 1) unexpanded (10 Å, highest charge) crystallites; 2) expanded high-charge vermiculite-like (24 Å) crystallites; and 3) occasionally expanded high-charge vermiculite-like (24 Å) layers interspersed in the matrix of 10Å crystallites.
Synthesis and Paragenesis of Na-Beidellite as a Function of Temperature, Water Pressure, and Sodium Activity
- J. Theo Kloprogge, A. M. J. van der Eerden, J. Ben H. Jansen, John W. Geus, Roelof D. Schuiling
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- 28 February 2024, pp. 423-430
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In the chemical system Na2O-Al2O3-SiO2-H2O, the stability field of Na-beidellite is presented as a function of pressure, temperature, and Na- and Si-activity. Na0.7-beidellite was hydrothermally synthesized using a stoichiometric gel composition in the temperature range from 275° to 475°C and at pressures from 0.2 to 5 kbar. Below 275°C kaolinite was the only crystalline phase, and above about 500°C paragonite and quartz developed instead of beidellite. An optimum yield of 95% of the Na0.7- beidellite was obtained at 400°C and 1 kbar after 20 days. Gels with a Na-content equivalent to a layer charge lower than 0.3 per O20(OH)4 did not produce beidellite. They yielded kaolinite below 325°C and pyrophyllite above 325°C. With gels of a Na-content equivalent to a layer charge of 1.5, the Na-beidellite field shifted to a minimum between temperatures of 275° and 200°C. This procedure offers the potential to synthesize beidellite at low temperatures. Beidellite synthesized from Na1.0-gel approach a Na1.35 composition and those from Na1.5- and Na2.0-gels a Na1.8 composition.
Formation of Clay Minerals During Low Temperature Experimental Alteration of Obsidian
- Motoharu Kawano, Katsutoshi Tomita, Yoshitaka Kamino
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- 28 February 2024, pp. 431-441
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Experimental alteration of obsidian in distilled-deionized water at 150°, 175°, 200°, and 225°C was studied. The alteration products were examined by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy (TEM), and energy dispersive X-ray analysis (EDX) to evaluate the formation process of clay minerals. The surface composition of obsidian before and after alteration was examined by X-ray photoelectron spectroscopy (XPS), and concentrations of released elements in solution were measured to elucidate alteration and dissolution processes. TEM clearly showed that allophane appeared as the first reaction product in each experiment. With increasing reaction length, noncrystalline straight fibrous material was formed in the aggregates of allophane particles as a metastable transitional phase, and tended to form curled or wavy bundles of fibers with longer reaction. The non-crystalline fibers were transformed into highly curled smectite exhibiting small circular forms less than 1.0 µm in diameter as reaction progressed. EDX confirmed that the smectite consisted mainly of Si, Al, and small amounts of Ca, K, and Fe. XPS revealed the formation of a dealkalized leached layer on the surface of obsidian during the reaction. The concentration of released elements suggested that nonstoichiometric dissolution proceeded during the reaction.
Origin of the Mg-Smectite at the Cretaceous/Tertiary (K/T) Boundary at Stevns Klint, Denmark
- W. Crawford Elliott
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- 28 February 2024, pp. 442-452
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The clay mineralogy and major element geochemistry of four distinct layers within the Cretaceous/Tertiary (K/T) boundary marl (i.e., II, IIIa, IIIb, and IV) at Stevns Klint, Denmark, including “impact layer” (layer IIIa), were examined, and there was not a marked change in the clay mineralogy throughout this K/T boundary marl. A magnesium smectite (i.e., Mg-smectite) was the predominant clay mineral at the K/T boundary not only at Stevns Klint and at Nye Kløv; it was also found to be the predominant clay mineral in the K/T boundary at Karlstrup Quarry. In addition, Mg-smectite was found in a smectitic marl 32 meters below the K/T boundary at the Limhamn Quarry (near Malmö, Sweden), and it did not have anomalous concentrations of iridium or other siderophile trace elements. Given its occurrence in a Maastrichtian marl, it is therefore argued that the Mg-smectite is not derived from meteorite impact.
The rare earth element (REE) signatures of the Mg-smectites ranged from being comparable to the North American Shale Standard (NASC) to being one-half an order of magnitude depleted relative to NASC. One Mg-smectite collected from layer IIIb, immediately above the “impact/red layer,” was depleted in REE by one order of magnitude relative to NASC, and these levels of REE are comparable to those of smectite and illite/smectite (I/S) formed authigenically in bentonites and K-bentonites, respectively. Thus, the REE data suggest this Mg-smectite in all likelihood was formed authigenically from a glassy precursor. The presence of the low levels of REE of the Mg-smectite in the layer IIIb has no particular significance other than to suggest that this Mg-smectite separate was the least contaminated with illite or apatite having higher REE levels. With better separation, the other Mg-smectites would be expected to have comparably low levels of REE. Given the presence of the Mg-smectite throughout the K/T boundary and in Maastrichtian and Danian marls, the Mg-smectite is thought to be of volcanic origin. However, is not certain whether the Mg-smectite formed from volcanic glass deposited at the K/T boundary or whether it was formed from volcanic glass as young as late Cretaceous.
Some Colloidal Properties of Beidellite: Comparison with Low and High Charge Montmorillonites
- Frederic Hetzel, Harvey E. Doner
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- 28 February 2024, pp. 453-460
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Recent evidence of the occurrence of beidellite in many soils around the world necessitates a better understanding of the role of charge location on the colloidal behavior of this smectite as compared to the more frequently studied montmorillonites. Clay suspension stability and sorption of an organic polymer, two properties sensitive to surface charge characteristics, were selected to examine the differences in colloidal behaviors of these smectites. The Otay montmorillonite was shown to have a higher charge than either the beidellite or the SWy-1 montmorillonite. Even though structural formulae resulted in a higher permanent charge for the beidellite as compared to the SWy-1, effective charge of these two smectites is the same. The pH dependency of the critical coagulation concentration of the smectites could not be explained based only on edge charge considerations, and it is proposed that tetrahedral charge location enhances the pH effect on the CCC. Decreased poly(vinyl) alcohol sorption with either increasing surface charge or tetrahedral charge location was observed. Both parameters affect the ease of replacement of water molecules by PVA on the surface of smectites.
The Electrophoretic Mobility of Imogolite and Allophane in the Presence of Inorganic Anions and Citrate
- Chunming Su, James B. Harsh
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- 28 February 2024, pp. 461-471
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The purpose of this study was to investigate bonding mechanisms of representative inorganic anions and citrate with imogolite and allophane using electrophoresis. The electrophoretic mobility (EM) of synthetic imogolite and allophanes with Al/Si molar ratios of 2.02, 1.64, and 1.26 was determined in 0.001 and 0.01 M sodium solutions. The highest point of zero mobility (PZM) values for imogolite and the highest point of zero charge (PZC) values for allophane occurred in the presence of ClO4, NO3, Br, I, and Cl. Below the PZM and PZC, Cl and I lowered the EM relative to the other anions but did not shift the PZM and PZC significantly. This indicates that Cl and I formed more outer-sphere complexes than the other ions. The EM of imogolite and allophane was negative at pH < 6 in 0.001 and 0.01 M NaF probably due to a phase change. We observed the formation of cryolite (Na3AlF6) with transmission electron microscopy (TEM) and X-ray diffraction (XRD) in the NaF systems at low pH. Conversely, phosphate at 0.001 and 0.01 M concentrations lowered both the PZM and the EM in imogolite and both the PZC and the EM in allophane compared with ClO4. Phosphate-treated allophane had the same PZC as a synthetic amorphous aluminum phosphate. The PZM values of imogolite and allophane with 2:1 Al/Si in 0.0001 M Na-citrate were 10.9 and 5.9, respectively. At pH 7.3, Na-citrate lowered allophane EM more than it lowered imogolite EM relative to ClO4.
The EM in NaClO4 and Na2SO4 was reversible by forward- and back-titration with NaOH and HClO4, indicated that ClO4 and SO4 were not specifically adsorbed. Chloride likely formed more outer-sphere complexes than ClO4. Imogolite EM and allophane EM in dilute NaF and NaH2PO4 solutions were not reversible, indicating either surface inner-sphere complexes or surface precipitates of aluminum fluoride and amorphous aluminum phosphate-like materials on these minerals. Sulfate gave a lower EM than the monovalent anions, implying a greater tendency to form outer-sphere complexes. Citrate appeared to form inner-sphere complexes on both imogolite and allophane, but formation was concentration-dependent. The tendency of anions to form surface complexes with imogolite and allophane is consistent with the tendency of anions to form soluble aluminum complexes.
Properties and Characterization of Al2O3 and SiO2-TiO2 Pillared Saponite
- P. B. Malla, S. Komarneni
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- 28 February 2024, pp. 472-483
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A saponite pillared with a single (Al2O3) or a mixed (SiO2-TiO2) oxide exhibited basal spacings of 16–19 and 30–40Å, respectively. The pillared structures were found to be stable up to 700°C. Water, nitrogen, and high resolution argon adsorption were used to study the effect of thermal treatments on surface chemistry, pore structure, and surface area of these pillared clays. The pillared saponites exhibited a hydrophobic behavior at temperatures > 500°C, whereas such behavior was observed at ≥300°C for montmorillonite. Most of the micropores in the Al2O3 pillared clays were < 10 Å, whereas the SiO2-TiO2 pillared clays showed a broad distribution of pores in both micropore and mesopore regions. The SiO2-TiO2 pillared samples possessed higher surface area compared with Al2O3 pillared clays. The percent decrease in surface area was smaller for pillared saponites compared with pillared montmorillonites when calcined from 300° to 700°C, indicating a higher thermal stability of the former. The pillared clays were also characterized by solid state 27Al and 29Si magic-angle spinning nuclear magnetic resonance (MAS/NMR) spectroscopy. There was no direct evidence of cross-linking (covalent bonding between the clay layer and pillar) in montmorillonite irrespective of the types of pillars. In saponite, however, a significant structural modification took place. 27Al spectra of Al2O3 pillared saponite heated at ≥300°C appear to indicate an increase in AlVI as a result, at least in part, of initiation of hydrolytic splitting of Si-O-Al bonds. The actual release of Al from the tetrahedral sheet probably occurred at a temperature > 500°C and completed around 700°C with the formation of Si-O-Si linkages. The decreased intensity of peak due to Si(1Al) in 29Si spectra of the sample heated at 700°C corroborates the 27Al MAS/NMR results. Additionally, the 29Si spectra indicated a cross-linking between SiO4 (clay sheet) with Al2O3 pillars, which could be achieved by inverting some silica tetrahedra into the interlayer. 27Al and 29Si spectra of SiO2TiO2 pillared saponite also showed the trend similar to that exhibited by Al2O3 pillared saponite, indicating that the crystal chemistry of the host may be more important than the nature of pillars in the structural modification and cross-linking behavior of thermally treated pillared clays.
Characterization of Hydroxy-Interlayered Vermiculite and Illite/Smectite Interstratified Minerals from the Weathering of Chlorite in a Cryorthod
- Dominique Righi, Sabine Petit, Alain Bouchet
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- 28 February 2024, pp. 484-495
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X-ray diffraction, FTIR, and chemical analyses were performed on clay fractions (1–2 µm, <0.1 µm), separated by means of size fractionations and high-gradient magnetic separation techniques, from a Cryorthod developed in a chlorite-mica schist saprolite. Weathering of large phyllosilicates pre-existing in the saprolite involves physical fragmentation and mineralogical transformations. Chloritic minerals in the coarse fractions were the most affected by physical breakdown, while micas were generally preserved. As a consequence, a concentration of mica layers occurred in the coarse clay fraction, while chloritic residues accumulated in the fine clays. These residues exhibited the typical XRD pattern of hydroxy-interlayered intergrade minerals, but the interlayered contaminants were found to be mainly hydroxy-Mg cations. Further mineralogical transformations of the intergrade minerals involved the progressive removal of the hydroxide interlayered sheet and dissolution of chloritic layers. Illite/smectite mixed-layers were formed in the surface horizon of the soil profile. These processes were associated with a strong decrease in Fe and Mg contents in the clay fractions.
Characterization of Tubular Chrysotile by Thermoporometry, Nitrogen Sorption, Drifts, and TEM
- Mark K. Titulaer, J. Cees van Miltenburg, J. Ben H. Jansen, John W. Geus
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- 28 February 2024, pp. 496-513
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The maximum crystal radius Rn of ice in hollow wet chrysotile tubes is established by thermoporometry to be between 2.8 and 3.2 nm, and the internal pore volume Vn of the tubes to be between 0.008 and 0.02 ml/g. The hollow tubes of chrysotile and, for comparative reasons, small plates of talc, are hydrothermally synthesized at temperatures between 563 and 600 K and at pressures between 75 and 120 hPa. Size and shape of the pores can be varied by changing the Mg/Si molar ratios in steps of 3/1.5 and 3/2 for chrysotile and 3/3.6 and 3/4 for talc. The tubular morphology of the aggregates dried at 393 K is investigated by 1) transmission electron microscopy (TEM), 2) nitrogen adsorption and desorption at 77 K, and 3) diffuse reflectance infrared fourier transformed spectroscopy (DRIFTS). The radius within the hollow tubes, Ri, is between 2.5 and 4.0 nm as measured by TEM, and between 2.8 and 3.2 nm as determined by nitrogen adsorption and desorption. The measured radii agree well with the value calculated from crystallographic data, which is smaller than 5.3 nm. Within the dried aggregates the tubes are clustered in regular patterns, in which each tube is surrounded by six other tubes. The external radius, Ro, between the clustered tubes is from 1.6 to 2.9 nm as observed by TEM, and from 1.8 to 2.3 nm by N2 adsorption and desorption. The external radius is not measured by thermoporometry. Where thermoporometry only measures the average pore size and pore volume within the tubes, TEM and N2 adsorption and desorption additionally provide the corresponding values between the tubes. A third pore radius, 5 to 20 nm between the clusters of chrysotile tubes, is established with N2 adsorption and desorption.
Sampling and Analysis of KGa-1B Well-Crystallized Kaolin Source Clay
- Robert J. Pruett, Harold L. Webb
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- 28 February 2024, pp. 514-519
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Additional well-crystallized kaolin from Washington County, Georgia, has been supplied to the Clay Minerals Society Source Clay Repository to replace the exhausted supply of KGa-1. This kaolin is called KGa-1B and is from a geographic location and stratigraphic position close to where KGa-1 was collected. Slight mineralogical and chemical differences are observed between KGa-1 and KGa-1B. KGa-1B crude appears slightly better crystalline than KGa-1, and it has a slightly higher titania content than KGa-1. The Al2O3, SiO2, Fe2O3, alkali, and alkaline earth contents appear similar for both samples. KGa-1 has a slightly coarser particle size than KGa-1B crude. More intensive post-depositional alteration may have cleansed and crystallized the KGa-1B material to a slightly greater degree than the KGa-1 material.