Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-22T23:59:40.670Z Has data issue: false hasContentIssue false
  • English
  • Français

An improved process for the graphene preparation via redox potential control

Published online by Cambridge University Press:  20 June 2019

Yue Zhang  and
Xuanjun Wang
Yue Zhang
Affiliation:
Section 207, Xi’an Research Institute of High-Tech, Xi’an, Shaanxi 710025, People’s Republic of China
Xuanjun Wang*
Affiliation:
Section 207, Xi’an Research Institute of High-Tech, Xi’an, Shaanxi 710025, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: wangxj503@sina.com
Get access

Abstract

The physicochemical properties and broad applications of graphene have been extensively studied, but its preparation method is still a bottleneck, and it cannot simultaneously meet the requirements of low process cost and high quality of products in the time being. In this article, the redox potential was employed to control the quality of graphene prepared from graphene oxide by chemical reduction. The effects of the initial redox potential on the productivity, microscopic morphology, and structural and intrinsic properties of graphene were investigated. Results showed that there was an optimum initial redox potential range between −1200 and −1180 mV. In such a range could the graphene with a high yield be obtained, and layers of graphene products could be stabilized at 1 or 2 layers. Therefore, the redox potential could be used as an effective parameter instead of trying to design orthogonal tests to determine the optimal conditions and control the synthesis of graphene.

Keywords

graphenepreparationredox potentialgraphene oxide
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 18 , 30 September 2019 , pp. 3212 - 3219
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Geim, A.K. and Novoselov, K.S.: The rise of graphene. Nat. Mater. 3, 6 (2012).Google Scholar
Xu, C., Xue, T., Guo, J., Qin, Q., Wu, S., and Song, H.: An experimental investigation on the mechanical properties of the interface between large-sized graphene and a flexible substrate. J. Appl. Phys. 16, 117 (2015).Google Scholar
Kumar, R., Singh, R.K., Dubey, P.K., and Kumar, P.: Pressure-dependent synthesis of high-quality few-layer graphene by plasma-enhanced arc discharge and their thermal stability. J. Nano Res. 9, 15 (2013).Google Scholar
Chen, Y., Li, S., Luo, R., Lv, X., and Wang, X.: Optimization of initial redox potential in the preparation of expandable graphite by chemical oxidation. N. Carbon Mater. 6, 28 (2013).Google Scholar
He, P., Tian, S., and Sun, J.: The invention relates to a method for preparing graphene. U.S. Patent No. CN103935999A, 2014.Google Scholar
Hu, G., Gao, H., and Liu, C.: A method for improving the yield of graphene prepared by supercritical fluid pretreatment with natural graphite. U.S. Patent No. CN104229787A, 2014.Google Scholar
Chen, P., Jin, X., and Liang, P.: A method for preparing graphene. U.S. Patent No. CN105366671A, 2016.Google Scholar
Sereshti, H., Khosraviani, M., Samadi, S., and Amini-Fazl, M.S.: Simultaneous determination of theophylline, theobromine and caffeine in different tea beverages by graphene-oxide based ultrasonic-assisted dispersive micro solid-phase extraction combined with HPLC-UV. RSC Adv. 4, 87 (2014).CrossRefGoogle Scholar
Gupta, A., Shaw, B.K., and Saha, S.K.: Bright green photoluminescence in aminoazobenzene-functionalized graphene oxide. J. Phys. Chem. 13, 118 (2014).Google Scholar
Andonovic, B., Temkov, M., and Ademi, A.: Laue functions model vs scherrer equation in determination of graphene layers number on the ground of XRD data. J. Chem. Technol. Metall. 6, 49 (2014).Google Scholar
Danilov, M.O., Slobodyanyuk, I.A., and Rusetskii, I.A.: Influence of the synthesis conditions of reduced graphene oxide on the electrochemical characteristics of the oxygen electrode. Minerva Nefrol. 1, 26 (2014).Google Scholar
Dervishi, E., Li, Z., Watanabe, F., Biswas, A., and Xu, Y.: Large-scale graphene production by RF-cCVD method. Chem. Commun. 27, 27 (2009).Google Scholar
Cançado, L.G., Mateus, G.D.S., Martins Ferreira, E.H., Ferdinand, H., Katerina, K., Kai, H., Alain, P., Carlos, A.A., Rodrigo, B.C., and Ado, J.: Disentangling contributions of point and line defects in the Raman spectra of graphene-related materials. 2D Mat. 2, 4 (2017).Google Scholar
Budde, H., Cocalópez, N., Xian, S., Richard, C., Antonio, L., Duhee, Y., Andrea, C.F., and Achim, H.: Raman radiation patterns of graphene. ACS Nano 2, 10 (2016).Google Scholar
Beams, R., Gustavo, C.L., and Novotny, L.: Raman characterization of defects and dopants in graphene. J. Phys.: Condens. Matter 8, 27 (2015).Google Scholar
Frolova, L.V., Magedov, I.V., Harper, A., Jha, S.K., Ovezmyradov, M., Chandler, G., Garacia, J., Donald, B., Shaner, E.A., Vasiliev, I., and Kalugin, N.G.: Tetracyanoethylene oxide-functionalized graphene and graphite characterized by Raman and Auger spectroscopy. Carbon 1, 81 (2015).Google Scholar
Ranjan, P., Tulika, S., Laha, R., and Balakrishnan, J.: Au concentration-dependent quenching of Raman 2D peak in graphene. J. Raman Spectrosc. 4, 48 (2017).Google Scholar
Cong, C. and Yu, T.: Evolution of Raman G, and G′, (2D) modes in folded graphene layers. Phys. Rev. B 23, 89 (2014).Google Scholar
Zhan, N., Olmedo, M., Wang, G., and Liu, J.: Layer-by-layer synthesis of large-area graphene films by thermal cracker enhanced gas source molecular beam epitaxy. Carbon 6, 49 (2011).Google Scholar
Gayathri, S., Jayabal, P., Kottaisamy, M., and Ramakrishnan, V.: Synthesis of few layer graphene by direct exfoliation of graphite and a Raman spectroscopic study. AIP Adv. 2, 4 (2014).Google Scholar