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The corrosion and oxidation behavior of Zr-based metallic glasses

Published online by Cambridge University Press:  28 May 2014

Yonglong Hu ,
Wenhuan Cao  and
Chanhung Shek
Yonglong Hu*
Affiliation:
Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong, Hong Kong 999077, China
Wenhuan Cao
Affiliation:
Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong, Hong Kong 999077, China
Chanhung Shek
Affiliation:
Department of Physics and Materials Science, City University of Hong Kong, Kowloon Tong, Hong Kong 999077, China
*
a) Address all correspondence to this author. e-mail: yonglhu2-c@my.cityu.edu.hk
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Abstract

Zr-based bulk metallic glasses are promising engineering materials due to their good glass-forming abilities and unique combination of good strength (∼1.9 GPa) and medium stiffness. In this study, the corrosion behaviors of Zr–Co–Al–Ag BMGs, with silver content from 0 to 11 at.%, in NaCl and H2SO4 solutions were investigated. The corrosion resistance increased when the silver content increased. The oxidation behaviors of Zr–Co–Al–Ag BMGs were also studied. The oxidation kinetics of all the samples obeyed a two-stage parabolic rate law, which consisted of an initial transient oxidation followed by a steady-state oxidation stage. The addition of Ag was found to reduce the oxidation resistance of Zr–Co–Al–Ag BMGs. Some white nodules, possibly cobalt oxide, were observed when the Zr–Co–Al–Ag BMG with 8 at.% Ag was oxidized at high temperature.

Keywords

bulk metallic glassescorrosionoxidation
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 11 , 14 June 2014 , pp. 1248 - 1255
Copyright
Copyright © Materials Research Society 2014 

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