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Development of sandwich-structured cobalt porphyrin/niobium molybdate nanosheets catalyst for oxygen reduction

Published online by Cambridge University Press:  15 November 2018

Mengjun Wang ,
Yan Liu ,
Xiaobo Zhang ,
Zichun Fan  and
Zhiwei Tong Open the ORCID record for Zhiwei Tong [Opens in a new window]
Mengjun Wang
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Yan Liu
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Xiaobo Zhang
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Zichun Fan
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
Zhiwei Tong*
Affiliation:
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China; and SORST, Japan Science and Technology Agency (JST), Kawaguchi-shi, Saitama 332-0012, Japan
*
a)Address all correspondence to this author. e-mail: zhiweitong575@hotmail.com
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Abstract

In this work, the negatively charged [NbMoO6]− nanosheets (NSs) were combined with positively charged [5,10,15,20-tetrakis (N-methylpyridinium-4-yl) porphyrinato cobalt] (CoTMPyP) to fabricate a sandwich-like CoTMPyP/[NbMoO6]− NSs intercalated material by a direct self-assembling process. The results confirmed that CoTMPyP cations formed an inclined monolayer between [NbMoO6]− NSs and the inclined angle was about 68°. The electrochemical properties of CoTMPyP/[NbMoO6]− NSs composite were also investigated by cyclic voltammetry and liner sweep voltammetry, which showed the enhanced electron transferred ability. The CoTMPyP/[NbMoO6]− NSs modified electrode displayed excellent electrocatalytic activity towards oxygen reduction with the reduction peak potential shifting from −0.681 to −0.235 V. And oxygen could be reduced to generate hydrogen peroxide with a two-electron process in neutral electrolytes. Moreover, the reduction peak current was linear relationship with the square root of scan rates, implying that the catalytic reaction depended on oxygen diffusion.

Keywords

cobalt porphyrinniobium molybdatehybrid materialoxygen reduction
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 24 , 28 December 2018 , pp. 4199 - 4206
Copyright
Copyright © Materials Research Society 2018 

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