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Electron spectroscopy on the charge transfer complex [(7-amino-2,4 dimethyl-1,8 naphthyridine) (TCNQ)] (TCNQ = 7,7',8,8'-tetracyanoquinodimethane)

Published online by Cambridge University Press:  03 March 2011

A. Arena
Affiliation:
Istituto di Struttura della Materia, Università di Messina, Salita Sperone 31, 1-98166 Sant'Agata-Messina, Italy
S. Lo Schiavo
Affiliation:
Dipartimento di Chimica Inorganica, Analitica e Struttura Molecolare, Salita Sperone 31, 1-98166 Sant'Agata-Messina, Italy
A.M. Mezzasalma
Affiliation:
Istituto di Struttura della Materia, Università di Messina, Salita Sperone 31, 1-98166 Sant'Agata-Messina, Italy
S. Patané
Affiliation:
Istituto di Struttura della Materia, Università di Messina, Salita Sperone 31, 1-98166 Sant'Agata-Messina, Italy
P. Piraino
Affiliation:
Dipartimento di Chimica Inorganica, Analitica e Struttura Molecolare, Salita Sperone 31, 1-98166 Sant'Agata-Messina, Italy
G. Saitta
Affiliation:
Istituto di Struttura della Materia, Università di Messina, Salita Sperone 31, 1-98166 Sant'Agata-Messina, Italy
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Abstract

Reflection electron energy loss spectroscopy (REELS) and optical reflectivity measurements have been used to characterize in the valence energy region the dielectric behavior of 7-amino-2,4 dimethyl-1,8 naphthyridine and of the charge transfer complex formed by this compound and the 7,7',8,8'-tetracyanoquinodimethane (TCNQ). The effects of the charge transfer interaction on the core energy levels have been investigated by comparing the line shape of the carbon and nitrogen Is core photoelectron peaks of the electron-donor and electron-acceptor molecules and of the charge transfer complex formed by them.

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Articles
Copyright
Copyright © Materials Research Society 1994

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References

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