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A novel Fe2O3 rhombohedra/graphene composite as a high stability electrode for lithium-ion batteries

Published online by Cambridge University Press:  02 March 2015

Yong Jiang ,
Xuetao Ling ,
Xinhui Cai ,
Zheng Jiao ,
Lingli Cheng ,
Lifeng Bian ,
Manhtai Nguyen ,
Yuliang Chu  and
Bing Zhao
Yong Jiang
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
Xuetao Ling
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
Xinhui Cai
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
Zheng Jiao
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
Lingli Cheng
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
Lifeng Bian
Affiliation:
Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu, China
Manhtai Nguyen
Affiliation:
Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu, China
Yuliang Chu
Affiliation:
Instrumental Analysis and Research Center, Shanghai University, Shanghai 200444, China
Bing Zhao*
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
*
a)Address all correspondence to this author. e-mail: bzhao@shu.edu.cn
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Abstract

We demonstrate in this paper the shape-controlled synthesis of α-Fe2O3 rhombohedra anchored graphene nanocomposites through a simple hydrothermal strategy by adopting inorganic species in the synthesis system. TEM investigations reveal that the rhombohedra with an average diameter of 80 nm is formed through oriented attachment of primary nanocrystals assisted by Ostwald ripening, and CH3COONa inorganic surfactant played an important role in control over the final morphology of the products. As high-performance anodes for lithium-ion batteries, the obtained Fe2O3 rhombohedra/graphene composite exhibits the first reversible capacity of 905.3 mAh g−1, and high capacity retention of 85.7% after 50 cycles. These values are much higher than those of bare Fe2O3 and Fe2O3 particle/graphene composites, indicating its excellent electrochemical stability. These results give us a guideline for the study of the morphology-dependent properties of functional oxide materials as well as further applications for magnetic materials, lithium-ion batteries, and gas sensors.

Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 6 , 28 March 2015 , pp. 761 - 769
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

Chen, J., Xu, L., Li, W., and Guo, X.: α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications. Adv. Mater. 17, 582 (2005).Google Scholar
Zhang, W., Chen, J., Wang, X., and Qi, H.: Self-assembled three-dimensional flower-like α-Fe2O3 nanostructures and their application in catalysis. Appl. Organomet. Chem. 23, 200 (2009).Google Scholar
Song, H.J., Jia, X.H., Qi, H., Yang, X.F., Tang, H., and Min, C.Y.: Flexible morphology-controlled synthesis of monodisperse α-Fe2O3 hierarchical hollow microspheres and their gas-sensing properties. J. Mater. Chem. 22, 3508 (2012).Google Scholar
Zheng, Y., Cheng, Y., Wang, Y., Bao, F., Zhou, L., Wei, X., Zhang, Y., and Zheng, Q.: Quasicubic α-Fe2O3 nanoparticles with excellent catalytic performance. J. Phys. Chem. B 110, 3093 (2006).Google Scholar
Wu, C., Yin, P., Zhu, X., Ouyang, C., and Xie, Y.: Synthesis of hematite (α-Fe2O3) nanorods: Diameter-size and shape effects on their applications in magnetism, lithium ion battery, and gas sensors. J. Phys. Chem. B 110, 17806 (2006).Google Scholar
Wang, P., Ding, H., Bark, T., and Chen, C.: Nanosized α-Fe2O3 and Li–Fe composite oxide electrodes for lithium-ion batteries. Electrochim. Acta 52, 6650 (2007).Google Scholar
Wu, X., Guo, Y., Wan, L., and Hu, C.: α-Fe2O3 nanostructures: Inorganic salt-controlled synthesis and their electrochemical performance toward lithium storage. J. Phys. Chem. C 112, 16824 (2008).Google Scholar
An, Z., Zhang, J., Pan, S., and Yu, F.: Facile template-free synthesis and characterization of elliptic α-Fe2O3 superstructures. J. Phys. Chem. C 113, 8092 (2009).Google Scholar
Fan, J., Wang, T., Yu, C., Tu, B., Jiang, Z., and Zhao, D.: Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries. Adv. Mater. 16, 1432 (2004).Google Scholar
Prem, K.T., Ramesh, R., Lin, Y., and Fey, G.: Tin-filled carbon nanotubes as insertion anode materials for lithium-ion batteries. Electrochem. Commun. 6, 520 (2004).CrossRefGoogle Scholar
Piao, Y.Z., Kim, H.S., Sung, Y.E., and Hyeon, T.: Facile scalable synthesis of magnetite nanocrystals embedded in carbon matrix as superior anode materials for lithium-ion batteries. Chem. Commun. 46, 118 (2010).Google Scholar
Chen, D., Tang, L., and Li, J.: Graphene-based materials in electrochemistry. Chem. Soc. Rev. 39, 3157 (2010).Google Scholar
Zhao, B., Song, J., Liu, P., Xu, W., Fang, T., Jiao, Z., Zhang, H., and Jiang, Y.: Monolayer graphene/NiO nanosheets with two-dimension structure for supercapacitors. J. Mater. Chem. 21, 18792 (2011).Google Scholar
Mai, Y., Wang, X., Xiang, J., Qiao, Y., Zhang, D., Gu, C., and Tu, J.: CuO/graphene composite as anode materials for lithium-ion batteries. Electrochim. Acta 56, 2306 (2011).Google Scholar
Wang, H., Cui, L., Yang, Y., Casalongue, H., Robinson, J., Liang, Y., Cui, Y., and Dai, H.: Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries. J. Am. Chem. Soc. 132, 13978 (2010).CrossRefGoogle ScholarPubMed
He, F., Fan, J., Ma, D., Zhang, L., Leung, C., and Chan, H.: The attachment of Fe3O4 nanoparticles to graphene oxide by covalent bonding. Carbon 48, 3139 (2010).CrossRefGoogle Scholar
Zhou, G., Wang, D.W., Li, L., Li, N., Li, F., and Cheng, H.: Nanosize SnO2 confined in the porous shells of carbon cages for kinetically efficient and long-term lithium storage. Nanoscale 5, 1576 (2013).CrossRefGoogle ScholarPubMed
Lee, K., Deng, S., Fan, H., Mhaisalkar, S., Tan, H., Tok, E., Loh, K., Chin, W., and Sow, C.: α-Fe2O3 nanotubes reduced graphene oxide composites as synergistic electrochemical capacitor materials. Nanoscale 4, 2958 (2012).CrossRefGoogle ScholarPubMed
Zhu, J., Zhu, T., Zhou, X.Z., Zhang, Y.Y., Lou, X.W., Chen, X.D., Zhang, H., Hng, H.H., and Yan, Q.Y.: Facile synthesis of metal oxide/reduced graphene oxide hybrids with high lithium storage capacity and stable cyclability. Nanoscale 3, 1084 (2011).Google Scholar
Zhu, X., Zhu, Y., Murali, S., Stoller, M.D., and Ruoff, R.S.: Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano 5, 3333 (2011).Google Scholar
Xue, X.Y., Ma, C.H., Cui, C.X., and Xing, L.L.: High lithium storage performance of α-Fe2O3/graphene nanocomposites as lithium-ion battery anodes. Solid State Sci. 13, 1526 (2011).Google Scholar
Zhao, B., Liu, P., Jiang, Y., Pan, D., Tao, H., Song, J., Fang, T., and Xu, W.: Supercapacitor performances of thermally reduced graphene oxide. J. Power Sources 198, 423 (2012).CrossRefGoogle Scholar
Cong, H.P., He, J.J., Lu, Y., and Yu, S.: Water-soluble magnetic-functionalized reduced graphene oxide sheets: In situ synthesis and magnetic resonance imaging applications. Small 6, 169 (2010).CrossRefGoogle ScholarPubMed
Zhou, G., Wang, D.W., Li, F., Zhang, L., Li, N., Wu, Z., Wen, L., and Cheng, H.: Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries. Chem. Mater. 22, 5306 (2010).Google Scholar
Mensing, J., Kerdcharoen, T., Sriprachuabwong, C., Sriprachuabwong, C., Wisitsoraat, A., Phokharatkul, D., Lomas, T., and Tuantranont, A.: Facile preparation of graphene–metal phthalocyanine hybrid material by electrolytic exfoliation. J. Mater. Chem. 22, 17094 (2012).Google Scholar
Zhou, Y., Bao, Q.L., Tang, L., Zhong, Y.L., and Loh, K.P.: Hydrothermal dehydration for the “green” reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties. Chem. Mater. 21, 2950 (2009).Google Scholar
Zhang, M., Lei, D., Chen, Y.J., Yu, X.Z., and Wang, Y.G.: A green and fast strategy for the scalable synthesis of Fe2O3/graphene with significantly enhanced Li-ion storage properties. J. Mater. Chem. 22, 3868 (2012).Google Scholar
Pumera, M.: Graphene-based nanomaterials for energy storage. Energy Environ. Sci. 4, 668(2011).Google Scholar
Bourlinos, A.B., Gournis, D., Petridis, D., Szabo, T., Szeri, A., and Dekany, I.: Graphite oxide: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids. Langmuir 19, 6050 (2003).Google Scholar
Voorhees, P.W.: The theory of Ostwald ripening. J. Stat. Phys. 38, 231 (1985).CrossRefGoogle Scholar
Yang, H.G. and Zeng, H.C.: Preparation of hollow anatase TiO2 nanospheres via Ostwald ripening. J. Phys. Chem. B 108, 3492 (2004).CrossRefGoogle ScholarPubMed
Siegfried, M. and Choi, K.: Elucidating the effect of additives on the growth and stability of Cu2O surfaces via shape transformation of pre-grown crystals. J. Am. Chem. Soc. 128, 10356 (2006).Google Scholar
Filankembo, A. and Pileni, M.P.: Is the template of self-colloidal assemblies the only factor that controls nanocrystal shapes. J. Phys. Chem. B 104, 5865 (2000).Google Scholar
Tian, L., Zhuang, Q., Li, J., Wu, C., Shi, Y., and Sun, S.: The production of self-assembled Fe2O3–graphene hybrid materials by a hydrothermal process for improved Li-cycling. Electrochim. Acta 65, 153 (2012).Google Scholar
Liu, Z. and Tay, S.W.: Direct growth Fe2O3 nanorods on carbon fibers as anode materials for lithium ion batteries. Mater. Lett. 72, 74 (2012).Google Scholar
Wang, G., Liu, T., Luo, Y., Zhao, Y., Ren, Z., Bai, J., and Wang, H.: Preparation of Fe2O3/graphene composite and its electrochemical performance as an anode material for lithium ion batteries. J. Alloys Compd. 509, L216 (2011).Google Scholar
Wang, X., Tian, W., Liu, D., Zhi, C., Bando, Y., and Golberg, D.: Unusual formation of α-Fe2O3 hexagonal nanoplatelets in N-doped sandwiched graphene chamber for high-performance lithium-ions batteries. Nano Energy 2, 257 (2013).Google Scholar
Zou, Y., Kan, J., and Wang, Y.: Fe2O3-graphene rice-on-sheet nanocomposite for high and fast lithium ion storage. J. Phys. Chem. C 115, 20747 (2011).Google Scholar