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Phase stability and consolidation of glassy/nanostructured Al85Ni9Nd4Co2 alloys

Published online by Cambridge University Press:  03 March 2011

L.C. Zhang ,
M. Calin ,
M. Branzei ,
L. Schultz  and
J. Eckert
L.C. Zhang*
Affiliation:
Fachgebiet Physikalische Metallkunde, Fachbereich 11-Material- und Geowissenschaften, Technische Universität Darmstadt, D-64287 Darmstadt, Germany; and Institut für Komplexe Materialien, IFW Dresden, D-01171 Dresden, Germany
M. Calin
Affiliation:
Fachgebiet Physikalische Metallkunde, Fachbereich 11-Material- und Geowissenschaften, Technische Universität Darmstadt, D-64287 Darmstadt, Germany; and Materials Science and Engineering Faculty, University “Politehnica” of Bucharest, R-060032 Bucharest, Romania
M. Branzei
Affiliation:
Materials Science and Engineering Faculty, University “Politehnica” of Bucharest, R-060032 Bucharest, Romania
L. Schultz
Affiliation:
Institut für Metallische Werkstoffe, IFW Dresden, D-01171 Dresden, Germany
J. Eckert
Affiliation:
Fachgebiet Physikalische Metallkunde, Fachbereich 11-Material- und Geowissenschaften, Technische Universität Darmstadt, D-64287 Darmstadt, Germany; and Institut für Komplexe Materialien, IFW Dresden, D-01171 Dresden, Germany
*
a) Address all correspondence to this author.e-mail address: lczhangimr@gmail.com and l.zhang@ifw-dresden.de
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Abstract

Al85Ni9Nd4Co2 metallic glass/nanostructured ribbons and powders were used as starting materials for producing bulk amorphous/nanostructured Al-based alloys. Glassy ribbons were obtained by melt spinning at wheel surface velocities ranging from 5 to 37 m/s. The amorphous ribbons exhibited a supercooled liquid region of ∼20 K, a reduced glass transition temperature of ∼0.47 and γ ∼ 0.328. Mechanical alloying of the elemental powder mixture did not lead to amorphization. However, amorphous powders obtained by milling the glassy ribbons for 9 h exhibited a thermal stability similar to the initial ribbons. Isothermal differential scanning calorimetry measurements were used to determine the consolidation parameters of the glassy powders. Consolidation at 513 K by uniaxial hot pressing and hot extrusion indicated that the former method leads to bulk glassy samples, whereas the latter one yields nanostructured α-Al/glassy matrix composites.

Keywords

AlAmorphousRapid solidification
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 5 , May 2007 , pp. 1145 - 1155
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Vasudevan, A.K. and Roherty, R.D.: Aluminium Alloys Contemporary Research and Application (Academic Press, San Diego, CA, 1989).Google Scholar
2Donachie, M.J. Jr.: Titanium and Titanium Alloys (American Society for Metals, Metals Park, OH, 1982).Google Scholar
3Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999).CrossRefGoogle Scholar
4Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloy. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
5He, Y., Poon, S.J., and Shiflet, G.J.: Synthesis and properties of metallic glasses that contain aluminum. Science 241, 1640 (1988).CrossRefGoogle ScholarPubMed
6Inoue, A., Ohtera, K., Tsai, A.P., and Masumoto, T.: New amorphous alloys with good ductility in Al–Y–M and Al–La–M (M = Fe, Co, Ni or Cu) systems. Jpn. J. Appl. Phys. 27, L280 (1988).CrossRefGoogle Scholar
7Inoue, A.: Amorphous, nanoquasicrystalline and nanocrystalline alloys in Al-based systems. Prog. Mater. Sci. 43, 365 (1998).CrossRefGoogle Scholar
8Perepezko, J.H., Hebert, R.J., and Tong, W.J.: Amorphization and nanostructure synthesis in Al alloys. Intermetallics 10, 1079 (2002).CrossRefGoogle Scholar
9He, Y., Dougherty, G., Shiflet, G.J., and Poon, S.J.: Unique metallic glass formability and ultra-high tensile strength in A1–Ni–Fe–Gd alloys. Acta Metall. Mater. 41, 337 (1993).CrossRefGoogle Scholar
10Egami, T. and Waseda, Y.: Atomic size effect on the formability of metallic glasses. J. Non-Cryst. Solids 64, 113 (1984).CrossRefGoogle Scholar
11Poon, S.J., He, Y., Shiflet, G.J., and Dougherty, G.: Science and Technology of Rapid Solidification and Processing (Kluwer Academic Publishers, New York, Boston, Dordrecht, London, Moscow, 1995), p. 43.CrossRefGoogle Scholar
12Hackenberg, R.E., Gao, M.C., Kaufman, L., and Shiflet, G.J.: Thermodynamics and phase equilibria of the Al–Fe–Gd metallic glass-forming system. Acta Mater. 50, 2245 (2002).CrossRefGoogle Scholar
13Guo, F.Q., Enouf, S.J., Poon, S.J., and Shiflet, G.J.: Formation of ductile Al-based metallic glasses without rare-earth elements. Philos. Mag. Lett. 81, 203 (2001).CrossRefGoogle Scholar
14Kim, Y.H., Choi, G.S., Kim, I.G., and Inoue, A.: High-temperature mechanical properties and structural changes in amorphous Al–Ni–Fe–Nd alloys. Mater. Trans., JIM 37, 1471 (1996).CrossRefGoogle Scholar
15Börner, I. and Eckert, J.: Phase formation and properties of mechanically alloyed amorphous Al85Y8Ni5Co2. Scripta Mater. 45, 237 (2001).CrossRefGoogle Scholar
16Chattopadhyay, P.P., Gannabattula, R.N.R., Pabi, S.K., and Manna, I.: Development of amorphous Al65Cu35−xTix alloys by mechanical alloying. Scripta Mater. 45, 1191 (2001).CrossRefGoogle Scholar
17Dougherty, G.M., Shiflet, G.J., and Poon, S.J.: Synthesis and microstructural evolution of A1–Ni–Fe–Gd metallic glass by mechanical alloying. Acta Metall. Mater. 42, 2275 (1994).CrossRefGoogle Scholar
18Benameur, T. and Inoue, A.: Amorphization of aluminum base multicomponent systems by ball milling. Mater. Trans., JIM 36, 240 (1995).CrossRefGoogle Scholar
19Eckert, J., Schultz, L., and Urban, K.: Formation of quasicrystalline and amorphous phase in mechanically alloyed Al-based and Ti–Ni-based alloys. Acta Metall. Mater. 39, 1497 (1991).CrossRefGoogle Scholar
20Schurack, F., Eckert, J., and Schultz, L.: Synthesis and properties of mechanically alloyed and ball milled high strength amorphous or quasicrystalline Al-alloys. J. Metast. Nanocryst. Mater. 2, 49 (1999).Google Scholar
21Tsai, A.P., Aoki, K., Inoue, A., and Masumoto, T.: Synthesis of stable quasicrystalline particle-dispersed Al base composite alloys. J. Mater. Res. 8, 5 (1993).CrossRefGoogle Scholar
22Zhang, L.C., Xu, J., and Ma, E.: Mechanically alloyed amorphous Ti50(Cu0.45Ni0.55)44−xAlxSi4B2 alloys with supercooled liquid region. J. Mater. Res. 17, 1743 (2002).CrossRefGoogle Scholar
23Zhang, L.C., Shen, Z.Q., and Xu, J.: Mechanically milling-induced amorphization in Sn-containing Ti-based multicomponent alloy systems. Mater. Sci. Eng., A 394, 204 (2005).CrossRefGoogle Scholar
24Zhang, L.C., Shen, Z.Q., and Xu, J.: Thermal stability of mechanically alloyed boride/ Ti50Cu18Ni22Al4Sn6 glassy alloy composites. J. Non-Cryst. Solids 351, 2277 (2005).CrossRefGoogle Scholar
25Kawamura, Y., Kato, H., Inoue, A., and Masumoto, T.: Fabrication of bulk amorphous alloys by powder consolidation. Int. J. Powder Metall. 33, 50 (1997).Google Scholar
26Inoue, A., Masumoto, N., and Masumoto, T.: Al–Ni–Y–Co amorphous alloys with high mechanical strengths, wide supercooled liquid region and large glass-forming capacity. Mater. Trans., JIM 31, 493 (1990).CrossRefGoogle Scholar
27Inoue, A., Ochiai, T., Horio, Y., and Masumoto, T.: Formation and mechanical properties of amorphous A1–Ni–Nd alloys. Mater. Sci. Eng., A 179–180, 649 (1994).CrossRefGoogle Scholar
28Schurack, F., Eckert, J., and Schultz, L.: Al–Mn–Ce quasicrystalline composites: Phase formation and mechanical properties. Philos. Mag. 83, 807 (2003).CrossRefGoogle Scholar
29Zhang, L.C., Xu, J., and Ma, E.: Consolidation and properties of ball-milled Ti50Cu18Ni22Al4Sn6 glassy alloy by equal channel angular extrusion. Mater. Sci. Eng., A 434, 280 (2006).CrossRefGoogle Scholar
30Hong, S.J., Warren, P.J., and Chun, B.S.: Nanocrystallization behaviour of Al–Y–Ni with Cu additions. Mater. Sci. Eng., A 304–306, 362 (2001).CrossRefGoogle Scholar
31Tsai, A.P., Kamiyama, T., Kawamura, Y., Inoue, A., and Masumoto, T.: Formation and precipitation mechanism of nanoscale Al particles in Al-Ni base amorphous alloys. Acta Mater. 45, 1477 (1997).CrossRefGoogle Scholar
32Perepezko, J.H., Hebert, R.J., Wu, R.I., and Wilde, G.: Atomistic simulations of the phase stability and elastic properties of nickel– zirconium alloys. J. Non-Cryst. Solids 317, 52 (2003).CrossRefGoogle Scholar
33Turnbull, D. and Cohen, M.H.: Under what conditions can a glass be formed. Contemp. Phys. 5, 473 (1969).CrossRefGoogle Scholar
34Lu, Z.P. and Liu, C.T.: A new glass-forming ability criterion for bulk metallic glasses. Acta Mater. 50, 3501 (2002).CrossRefGoogle Scholar
35Chen, L.C. and Spaepen, F.: Analysis of calorimetric measurements of grain growth. J. Appl. Phys. 69, 679 (1991).CrossRefGoogle Scholar
36Vasiliev, A.L., Aindow, M., Blackburn, M.J., and Watson, T.J.: Phase formation during the devitrification of Al-rich melt-spun Al–8.5Ni–5.0Y–3.0(Co,Fe) alloys. Scripta Mater. 52, 699 (2005).CrossRefGoogle Scholar
37Schumacher, P. and Greer, A.L.: Heterogeneously nucleated α-A1 in amorphous aluminium alloys. Mater. Sci. Eng., A 178, 309 (1994).CrossRefGoogle Scholar
38Allen, D.R., Foley, J.C., and Perepezko, J.H.: Nanocrystal development during primary crystallization of amorphous alloys. Acta Mater. 46, 431 (1998).CrossRefGoogle Scholar
39Calin, M. and Köster, U.: Nanocrystallization of Al–Ni–Y and Al–Ni–Nd Metallic Glasses. Mater. Sci. Forum 269–272, 749 (1998).CrossRefGoogle Scholar
40Eckert, J., Schultz, L., Hellstern, E., and Urban, K.: Glass-forming range in mechanically alloyed Ni–Zr and the influence of the milling intensity. J. Appl. Phys. 64, 3224 (1988).CrossRefGoogle Scholar
41Eckert, J., Schultz, L., and Urban, K.: Amorphization reaction during mechanical alloying: Influence of the milling conditions. J. Mater. Sci. 26, 441 (1991).CrossRefGoogle Scholar
42Eckert, J., Schultz, L., and Urban, K.: Formation of quasicrystal by mechanical alloying. Appl. Phys. Lett. 55, 117 (1989).CrossRefGoogle Scholar
43Eckert, J., Schultz, L., and Urban, K.: Progress of quasicrystal formation during mechanical alloying in Al-Cu-Mn and the influence of the milling intensity. Z. Metallkd. 81, 862 (1990).Google Scholar
44Azaroff, L. and Buerger, M.J.: The Powder Method in X-Ray Crystallography (McGraw-Hill, New York, 1958), p. 238.Google Scholar
45He, Y., Shiflet, G.J., and Poon, S.J.: Ball milling-induced nanocrystal formation in aluminum-base metallic glasses. Acta Mater. 43, 83 (1995).CrossRefGoogle Scholar
46Jiang, W.H. and Atzmon, M.: The effect of compression and tension on shear-band structure and nanocrystallization in amorphous Al90Fe5Gd5: A high-resolution transmission-electron-microscopy study. Acta Mater. 51, 4095 (2003).CrossRefGoogle Scholar
47Chen, H., He, Y., Shiflet, G.J., and Poon, S.J.: Deformation-induced nanocrystal formation in shear bands of amorphous alloys. Nature 367, 541 (1994).CrossRefGoogle Scholar
48Zhang, L.C., Shen, Z.Q., and Xu, J.: Glass formation in a (Ti,Zr, Hf)–(Cu,Ni,Ag)–Al high-order alloy system by mechanical alloying. J. Mater. Res. 18, 2141 (2003).CrossRefGoogle Scholar
49Gloriant, T., Gich, M., Suriñach, S., Baró, M.D., and Greer, A.L.: Evaluation of the volume fraction crystallised during devitrification of Al-based amorphous alloys. Mater. Sci. Forum 343–346, 365 (2000).CrossRefGoogle Scholar
50Ma, E., Thompson, C.V., and Clevenger, L.A.: Nucleation and growth during reaction in multiplayer Al/Ni films: The early stage of Al3Ni formation. J. Appl. Phys. 69, 2211 (1988).CrossRefGoogle Scholar
51Greer, A.L.: Metallic glasses. Science 267, 1947 (1995).CrossRefGoogle ScholarPubMed
52Kim, J.J., Choi, Y., Suresh, S., and Argon, A.S.: Nanocrystallization during nanoindentation of a bulk amorphous metal alloy at room temperature. Science 295, 654 (2002).CrossRefGoogle ScholarPubMed
53Kawamura, Y., Inoue, A., Sasamori, K., and Masumoto, T.: Consolidation mechanism of aluminum-based amorphous alloy powders during warm extrusion. Mater. Sci. Eng., A 181–182, 1174 (1994).CrossRefGoogle Scholar
54Hill, R.: The Mathematical Theory of Plasticity (Oxford University Press, London, UK, 1967).Google Scholar