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Preparation of a high active photocatalyst, K2La2Ti3O10, by polymerized complex method and its photocatalytic activity of water splitting

Published online by Cambridge University Press:  31 January 2011

Shigeru Ikeda
Affiliation:
Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Michikazu Hara
Affiliation:
Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Junko N. Kondo
Affiliation:
Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Kazunari Domen
Affiliation:
Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Hiroyuki Takahashi
Affiliation:
Materials and Structure Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Toru Okub
Affiliation:
Materials and Structure Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Masato Kakihana
Affiliation:
Materials and Structure Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
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Abstract

A layered perovskite type oxide, K2La2Ti3O10, was prepared by a gel technique using the polymerized complex (PC) method. A single phase K2La2Ti3O10 was obtained by adding twice the potassium required for stoichiometry. The Ni–K2La2Ti3O10 catalyst prepared by the PC method exhibited a higher photocatalytic activity for decomposition of H2O into H2 and O2 than that prepared by a conventional solid state reaction.

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Articles
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1.Domen, K., Kudo, A., Shibata, M., Tanaka, A., Maruya, K., and Onishi, T., J. Chem. Soc. Chem. Commun., 1706 (1986).CrossRefGoogle Scholar
2.Domen, K., Kudo, A., and Onishi, T., J. Catal. 102, 92 (1986).CrossRefGoogle Scholar
3.Domen, K., Kudo, A., Shinozaki, A., Tanaka, A., Maruya, K., and Onishi, T., J. Chem. Soc. Chem. Commun., 356 (1986).CrossRefGoogle Scholar
4.Kudo, A., Tanaka, A., Domen, K., Maruya, K., Aika, K., and Onishi, T., J. Catal. 111, 67 (1988).CrossRefGoogle Scholar
5.Kudo, A., Sayama, K., Tanaka, A., Asakura, K., Domen, K., Maruya, K., and Onishi, T., J. Catal. 120, 337 (1989).CrossRefGoogle Scholar
6.Sayama, K., Tanaka, A., Domen, K., Maruya, K., and Onishi, T., Catal. Lett. 4, 217 (1990).CrossRefGoogle Scholar
7.Sayama, K., Tanaka, A., Domen, K., Maruya, K., and Onishi, T., J. Phys. Chem. 95, 1345 (1991).CrossRefGoogle Scholar
8.Domen, K., Yoshimura, J., Sekine, T., Tanaka, A., and Onishi, T., Catal. Lett. 4, 339 (1990).CrossRefGoogle Scholar
9.Yoshimura, J., Ebina, Y., Kondo, J., and Domen, K., J. Phys. Chem. 97, 1970 (1993).CrossRefGoogle Scholar
10.Sayama, K. and Arakawa, H., J. Photochem. Photobiol. A: Chem. 77, 243 (1994).CrossRefGoogle Scholar
11.Inoue, Y., Asai, Y., and Sato, K., J. Chem. Soc., Faraday Trans. 90, 797 (1994).CrossRefGoogle Scholar
12.Domen, K., Naito, S., Soma, M., Onishi, T., and Tamaru, K., J. Phys. Chem. 86, 3657 (1982).CrossRefGoogle Scholar
13.Sato, S. and White, J. M., Chem. Phys. Lett., 83 (1980).CrossRefGoogle Scholar
14.Ebina, Y., Tanaka, A., Kondo, J. N., and Domen, K., Chem. Mater. 8, 2534 (1996).CrossRefGoogle Scholar
15.Takata, T., Tanaka, A., Shinohara, K., Hara, M., Kondo, J. N., and Domen, K., Chem. Mater. 9, 1063 (1997).CrossRefGoogle Scholar
16.Ikeda, S., Tanaka, A., Hara, M., Kondo, J. N., Maruya, K., and Domen, K., Microporous. Mater. 9, 253 (1997).CrossRefGoogle Scholar
17.Pechini, M. P., U.S. Patent No. 3, July, 330,697 (1967).Google Scholar
18.Kakihana, M., J. Sol-Gel Sci. 5, 7 (1996).CrossRefGoogle Scholar
19.Gopalakrishan, J. and Bhat, V., Inorg. Chem. 26, 4299 (1987).CrossRefGoogle Scholar
20.Kondo, J. N., Tabata, S., and Domen, K., unpublished.Google Scholar