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Preparation of a polymer-intercalated layered manganese oxide nanocomposite through a delamination/reassembling process

Published online by Cambridge University Press:  01 July 2006

Zong-Huai Liu ,
Liping Kang ,
Zupei Yang ,
Zenglin Wang  and
Kenta Ooi
Zong-Huai Liu*
Affiliation:
Key Laboratory of Macromolecular Science of Shaanxi Province, Shaanxi Normal University,Xian 710062, People's Republic of China
Liping Kang
Affiliation:
Key Laboratory of Macromolecular Science of Shaanxi Province, Shaanxi Normal University,Xian 710062, People's Republic of China
Zupei Yang
Affiliation:
Key Laboratory of Macromolecular Science of Shaanxi Province, Shaanxi Normal University,Xian 710062, People's Republic of China
Zenglin Wang
Affiliation:
Key Laboratory of Macromolecular Science of Shaanxi Province, Shaanxi Normal University,Xian 710062, People's Republic of China
Kenta Ooi
Affiliation:
National Institute of Advanced Industrial Science and Technology, Takamatsu, Kagawa 761-0395, Japan
*
a) Address all correspondence to this author. e-mail: zhliu@snnu.edu.cn
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Abstract

Layered manganese oxide nanocomposite (PQN2MO) with Polyquaternium-2 (PQN2) incorporated between manganese oxide sheets was synthesized through a delamination/reassembling process. The synthesized material was characterized by powder x-ray diffraction (XRD), elemental analysis, thermal analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy observation. XRD analysis showed that the expansion of the interlayer depended on the amount of PQN2 intercalated; the largest expansion was 0.94 nm, corresponding to a layer of PQN2 chains existing in the interlayer at an angle of about 30°. Chemical analysis results indicated that the tetramethylammonium (TMA+) ions in the interlayer were partly replaced by PQN2 polycations by an ion exchange mechanism, resulting in a nanocomposite in which TMA+ ions and PQN2 polycations simultaneously existed in the interlayer. The intercalated PQN2 polycations were selectively extracted, and TMA+ ions were stable enough to remain in the interlayer against the acid treatment. PQN2MO nanocomposite was composed of platelike nanocomposite particles.

Keywords

IntercalationLayeredNanoscale
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 7 , July 2006 , pp. 1718 - 1725
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1.Choi, Y., Ham, H., Chung, I.: Effect of monomers on the basal spacing of sodium montmorillonite and the structures of polymer-clay nanocomposites. Chem. Mater. 16, 2522 (2004).CrossRefGoogle Scholar
2.Kerimo, J., Adams, D.M., Barbara, P.F., Kaschak, D.M., Mallouk, T.E.: NSOM investigations of the spectroscopy and morphology of self-assembled multilayered thin films. J. Phys. Chem. B 102, 9451 (1998).CrossRefGoogle Scholar
3.Zhu, H.Y., Lu, G.Q.: Engineering the structures of nanoporous clays with micelles of alkyl polyether surfactants. Langmuir 17, 588 (2001).CrossRefGoogle Scholar
4.Papp, S., Szél, J., Oszkó, A., Dékány, I.: Synthesis of polymer-stabilized nanosized rhodium particles in the interlayer space of layered silicates. Chem. Mater. 16, 1674 (2004).CrossRefGoogle Scholar
5.Kim, C., Kim, S-S., Guo, F., Hogan, T.P., Pinnavaia, T.J.: Polymer intercalation in mesostructured carbon. Adv. Mater. 16, 736 (2004).CrossRefGoogle Scholar
6.Yang, M., Koutsos, V., Zaiser, M.: Interactions between polymers and carbon nanotubes: A molecular dynamics study. J. Phys. Chem. B 109, 10009 (2005).CrossRefGoogle ScholarPubMed
7.Wang, J., Yang, J., Xie, J., Xu, N.: A novel conductive polymer-sulfur composite cathode material for rechargeable lithium batteries. Adv. Mater. 14, 963 (2002).3.0.CO;2-P>CrossRefGoogle Scholar
8.Lerner, M., Oriakhi, C. Polymers in ordered nanocomposites, in Handbook of Nanophase Materials edited by Goldstein, A.. (Marcel Dekker, New York, 1997), p. 199.Google Scholar
9.Gianellis, E.P.: Polymer layered silicate nanocomposites. Adv. Mater. 8, 29 (1996).CrossRefGoogle Scholar
10.Manias, E., Touny, A., Wu, L., Strawhecker, K., Lu, B., Chung, T.C.: Polypropylene/montmorillonite nanocomposites. Review of the synthetic routes and materials properties. Chem. Mater. 13, 3516 (2001).CrossRefGoogle Scholar
11.Tanaka, T., Ebina, Y., Takada, K., Kurashima, K., Sasaki, T.: Oversized titania nanosheet crystallites derived from flux-grown layered titanate single crystals. Chem. Mater. 15, 3564 (2003).CrossRefGoogle Scholar
12.Hibino, T.: Delamination of layered double hydroxides containing amino acids. Chem. Mater. 16, 5482 (2004).CrossRefGoogle Scholar
13.Peng, L., Yu, J., Li, J., Li, Y., Xu, R.: Lamellar mesostructured aluminophosphates: Intercalation of n-alkylamines into layered aluminophosphate by ultrasonic method. Chem. Mater. 17, 2101 (2005).CrossRefGoogle Scholar
14.Nakato, T., Miyamoto, N., Harada, A., Ushiki, H.: Sol-gel transition of niobium oxide nanosheet colloids: Hierarchical aspect of a novel macroscopic property appearing in colloidally dispersed states of layered niobate K4Nb6O17. Langmuir 19, 3157 (2003).CrossRefGoogle Scholar
15.Yang, X., Makita, Y., Liu, Z-H., Ooi, K.: Novel synthesis of layered graphite oxide-birnessite manganese oxide nanocomposite. Chem. Mater. 15, 1228 (2003).CrossRefGoogle Scholar
16.Wang, L., Ebina, Y., Takada, K., Sasaki, T.: Ultrathin films and hollow shells with pillared architectures fabricated via layer-by-layer self-assembly of titania nanosheets and aluminum keggin ions. J. Phys. Chem. B 108, 4283 (2004).CrossRefGoogle Scholar
17.Ma, J., Yu, Z., Zhang, Q., Xie, X., Mai, Y., Luck, I.: A novel method for preparation of disorderly exfoliated epoxy/clay nanocomposite. Chem. Mater. 16, 757 (2004).CrossRefGoogle Scholar
18.Feng, Q., Kanoh, H., Ooi, K.: Manganese oxide porous crystals. J. Mater. Chem. 9, 319 (1999).CrossRefGoogle Scholar
19.Liu, Z-H., Ooi, K., Kanoh, H., Tang, W., Tomida, T.: Swelling and delamination behaviors of birnessite-type manganese oxide by intercalation of tetraalkylammonium ions. Langmuir 16, 4154 (2000).CrossRefGoogle Scholar
20.Feng, Q., Sun, E-H., Yamagisawa, K., Yamasaki, N.: Synthesis of birnessite-type sodium manganese oxides by solution reaction and hydrothermal methods. J. Ceram. Soc. Jpn. 105, 564 (1997).CrossRefGoogle Scholar
21.Sasaki, T., Watanabe, M., Hashizume, H., Yamada, H., Nakazawa, H.: Macromolecule-like aspects for a colloidal suspension of an exfoliated titanate. Pairwise association of nanosheets and dynamic reassembling process initiated from it. J. Am. Chem. Soc. 118, 8329 (1996).CrossRefGoogle Scholar
22.Liu, Z-H., Wang, Z-M., Yang, X., Ooi, K.: Intercalation of organic ammonium ions into layered graphite oxide. Langmuir 18, 4926 (2002).CrossRefGoogle Scholar
23.Omomo, Y., Sasaki, T., Wang, L., Watanabe, M.: Redoxable nanosheet crystallites of MnO2 derived via delamination of a layered manganese oxide. J. Am. Chem. Soc. 125, 3568 (2003).CrossRefGoogle ScholarPubMed
24.Feng, Q., Kanoh, H., Miyai, Y., Ooi, K.: Metal ion extraction/insertion reactions with todorokite-type manganese oxide in the aqueous phase. Chem. Mater. 7, 1722 (1995).CrossRefGoogle Scholar
25.Liu, Z-H., Ooi, K., Kanoh, H., Tang, W., Yang, X., Tomida, T.: Synthesis of thermally stable silica-pillared layered manganese oxide by an intercalation/solvothermal reaction. Chem. Mater. 13, 473 (2001).CrossRefGoogle Scholar
26.Kooli, F.: Recrystallization of a new layered silicate from Na-kanemite–tetramethylammonium hydroxide–water–1,4-dioxane mixture. J. Mater. Chem. 12, 1374 (2002).CrossRefGoogle Scholar
27.Halaoui, L.I.: Layer-by-layer assembly of polyacrylate-capped CdS nanoparticles in poly(diallyldimethylammonium chloride) on solid surfaces. Langmuir 17, 7130 (2001).CrossRefGoogle Scholar
28.Yang, D.S., Wang, M.K.: Syntheses and characterization of well-crystallized birnessite. Chem. Mater. 13, 2589 (2001).CrossRefGoogle Scholar
29.Post, J.E., Veblen, D.R.: The tetravalent manganese oxides: Identification, hydration, and structural relationships by infrared spectroscopy. Am. Mineral. 75, 477 (1990).Google Scholar