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Properties of hydrogenated DLC films as prepared by a combined method of plasma source ion implantation and unbalanced magnetron sputtering

Published online by Cambridge University Press:  31 October 2011

Stefan Flege ,
Ruriko Hatada ,
Wolfgang Ensinger  and
Koumei Baba
Stefan Flege*
Affiliation:
Department of Materials Science, Technische Universität Darmstadt, 64287 Darmstadt, Germany
Ruriko Hatada
Affiliation:
Department of Materials Science, Technische Universität Darmstadt, 64287 Darmstadt, Germany
Wolfgang Ensinger
Affiliation:
Department of Materials Science, Technische Universität Darmstadt, 64287 Darmstadt, Germany
Koumei Baba
Affiliation:
Applied Technology Division, Industrial Technology Center of Nagasaki, Omura, Nagasaki 856-0026, Japan
*
a)Address all correspondence to this author. e-mail: flege@ca.tu-darmstadt.de
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Abstract

Unbalanced magnetron sputtering (UBMS) is suitable for the preparation of hard and hydrogen-free diamond-like carbon (DLC) films. Since those films generally suffer from internal stresses and bad adhesion, the addition of a methane source offers two advantages: (i) the control of the film properties by variation of the hydrogen content and (ii) a pretreatment of methane plasma source ion implantation (PSII), which results in a gradient carbon layer within the substrates, ensuring the adhesion of the subsequently deposited DLC films. PSII and UBMS were combined to prepare DLC films on stainless steel substrates and silicon wafers. Different amounts of methane were added to the working gas, argon, to investigate the effect of the hydrogen content on the film properties, i.e., hardness, adhesion, and friction coefficient. Composition and chemical structure of the films were investigated by depth profiling (secondary-ion mass spectrometry) and Raman spectroscopy. Smooth adhesive films could be obtained with the lowest friction coefficient for small additions of methane as a hydrogen source during the sputtering process.

Keywords

Ion implantationSputtering
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 5: Focus Issue: Plasma and Ion-Beam Assisted Materials Processing , 14 March 2012 , pp. 845 - 849
Copyright
Copyright © Materials Research Society 2011

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References

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