Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-26T22:37:01.840Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of superconductors from soluble metal oxo alkoxide precursors

Published online by Cambridge University Press:  31 January 2011

M.W. Rupich ,
Y.P. Liu ,
J. Ibechem  and
J.P. Hachey
M.W. Rupich
Affiliation:
EIC Laboratories, Inc., Norwood, Massachusetts 02062
Y.P. Liu
Affiliation:
EIC Laboratories, Inc., Norwood, Massachusetts 02062
J. Ibechem
Affiliation:
EIC Laboratories, Inc., Norwood, Massachusetts 02062
J.P. Hachey
Affiliation:
EIC Laboratories, Inc., Norwood, Massachusetts 02062
Get access

Abstract

Soluble metal oxo alkoxide precursors are useful for the production of homogeneous, micron-sized YBa2Cu3O7−x powders and the fabrication of superconducting YBa2Cu3O7−x films on large area and nonplanar substrates. This paper describes the synthesis and chemistry of a series of soluble metal oxo alkoxide precursors for the YBa2Cu3O7−x superconducting material and the effect of the thermal processing conditions on the formation of the superconducting phase. We have found that the direct conversion of the metal oxo alkoxide precursors to an amorphous or crystalline YBa2Cu3O6.5 phase without the intermediate formation of the individual metal oxides or carbonates allows the formation of the superconducting phase at temperatures as low as 720 °C. The prevention of the intermediate formation of the metal oxide and carbonate phases is achieved by the controlled thermolysis of the metal oxo alkoxide precursors in an inert atmosphere. The precursors have potential use in the low-temperature deposition of films on large area or nonplanar surfaces and for the production of homogeneous powders.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 7 , July 1993 , pp. 1487 - 1496
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Macho, J.Schaeffer, R. W.Myer, G. H.Salomon, R. E. and Crow, J. E., J. Mater. Res. 7, 1046 (1992).CrossRefGoogle Scholar
2Mclntyre, P. C.Cima, M. J.Ng, M. F.Chiu, R. C. and Rhine, W. E.J. Mater. Res. 5, 2771 (1990).Google Scholar
3Rice, C. E.vandover, R. B., and Fisanick, G. J.Appl. Phys. Lett. 52, 1842 (1987).Google Scholar
4Hamdi, A. H.Mantese, J. V.Micheli, A. L.Laugal, R. C. O. and Dungan, D. F.Appl. Phys. Lett. 51, 2152 (1987).CrossRefGoogle Scholar
5Hussain, A. A. and Sayer, M.J. Supercond. 5, 11 (1992).CrossRefGoogle Scholar
6Ward, T. L.Kodas, T. T.Carim, A. H.Kroeger, D. M. and Hsu, H.J. Mater. Res. 7, 827 (1992).CrossRefGoogle Scholar
7Bowmer, T.N. and Shokoohi, F.K.J. Mater. Res. 6, 670 (1991).CrossRefGoogle Scholar
8Pak, S. S.Montgomery, F. C.Duggan, D. M.Chen, K. C. and Mazdiyasni, K. S.J. Am. Ceram. Soc. 75, 2268 (1992).CrossRefGoogle Scholar
9Mclntyre, P.C.Cima, M.J.Smith, J.A. and Hallock, R.B.J. Appl. Phys. 71, 1868 (1992).Google Scholar
10Rupich, M.W.Lagos, B. and Hachey, J.P.Appl. Phys. Lett. 55, 2447 (1989).CrossRefGoogle Scholar
11Rupich, M.W.Cogan, S.F.Lagos, B. and Hachey, J.P. in High-Temperature Superconductors: Fundamental Properties and Novel Materials Processing, edited by Christen, D.Narayan, J. and Schneemeyer, L. (Mater. Res. Soc. Symp. Proc. 169, Pittsburgh, PA, 1990), p. 1209.Google Scholar
12Rupich, M. W.Liu, Y. P. and Ibechem, J.Appl. Phys. Lett. 60, 1384 (1992).CrossRefGoogle Scholar
13Bodek, I. and Davies, G.Inorg. Chem. 17, 1814 (1978).CrossRefGoogle Scholar
14Davies, G. M. A. El-Sayed, Kozlowski, D. R.Kramer, C. E.Rupich, M. W., and Slaven, R.W.Adv. Chem. Series 173, 179 (1979).Google Scholar
15Horowitz, H.S.McLain, S.J.Sleight, A.W.Druliner, J.D.Gai, P.L., VanKavelaar, M. J.Wagner, J. L.Biggs, B. D. and Poon, S. J.Science 243, 66 (1989).Google Scholar
16Kumagai, T.Manabe, T.Kondo, W. and Mizuta, S.Jpn. J. Appl. Phys. 30, L28 (1991).Google Scholar
17Mclntyre, P. C.Cima, M. J. and Ng, M. F.J. Appl. Phys. Lett. 68, 4183 (1990).Google Scholar
18Manthiram, A. and Goodenough, J. B.Nature 329, 701 (1987).CrossRefGoogle Scholar
19Livage, J.Henry, M. and Sanchez, C.Prog. Solid State Chem. 18, 259 (1988).CrossRefGoogle Scholar