Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-23T03:00:57.177Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect of crystal orientation on microstructure and properties of bulk Fe2B intermetallic

Published online by Cambridge University Press:  28 January 2015

Shengqiang Ma ,
Zhifu Huang ,
Jiandong Xing ,
Guangzhu Liu ,
Yaling He ,
Hanguang Fu ,
Yong Wang ,
Yefei Li  and
Dawei Yi
Shengqiang Ma*
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Zhifu Huang
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Jiandong Xing
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Guangzhu Liu
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Yaling He
Affiliation:
MOE Key Laboratory of Thermo-Fluid Science and Engineering, School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Hanguang Fu
Affiliation:
Research Institute of Advanced Materials Processing Technology, School of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, People's Republic of China
Yong Wang
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Yefei Li
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Dawei Yi
Affiliation:
School of Materials Science and Engineering, Xi'an University of Science and Technology, Xi'an, Shaanxi Province 710054, People's Republic of China
*
a)Address all correspondence to this author. e-mail: sqma@mail.xjtu.edu.cn
Get access

Abstract

The effects of Fe2B-grain orientation on microstructure and properties of bulk Fe2B intermetallic fabricated by directional and ordinary solidification techniques have been investigated. The results show that unidirectional solidified Fe2B intermetallic possesses a strong (002) texture in the transverse direction owing to the opposite unidirectional heat-squeeze effect while random Fe2B grains can be produced under ordinary solidification conditions. The nonoriented Fe2B intermetallic has the highest linear expansion coefficient of 13.04 × 10−6 °C−1 while the microhardness and fracture toughness of transverse Fe2B intermetallic in the (002) plane are larger than those of Fe2B with other grain orientations and their values are ∼18.72 GPa and 6.42 MPa·m1/2, respectively. Liquid zinc corrosion results indicate that unidirectional Fe2B intermetallic with long axis perpendicular to the direction of liquid zinc corrosion displays the best corrosion resistance to liquid zinc owing to its beneficial barrier effect. The FeB transition phase can naturally form and grow parabolically during liquid zinc corrosion.

Keywords

borideorientationliquid zinccorrosionanisotropy
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 2 , 28 January 2015 , pp. 257 - 265
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: Jürgen Eckert

References

REFERENCES

Dybkov, V.I., Lengauer, W., and Barmak, K.: Formation of boride layers at the Fe-10%Cr alloy-boron interface. J. Alloys Compd. 398, 113 (2005).CrossRefGoogle Scholar
Hu, Z., Fan, Y., Wu, Y., Yan, Q., and Chen, Y.: Crystallization and structure of high boron content iron-boron ultrafine amorphous alloy particles. J. Mater. Sci. 31, 611 (1996).CrossRefGoogle Scholar
Ozdemir, O., Usta, M., Bindal, C., and Ucisik, A.: Hard iron boride (Fe2B) on 99.97wt% pure iron. Vacuum 80, 1391 (2006).CrossRefGoogle Scholar
Sen, U., Sen, S., Koksal, S., and Yilmaz, F.: Fracture toughness of borides formed on boronized ductile iron. Mater. Des. 26, 175 (2005).CrossRefGoogle Scholar
Taktak, S.: Some mechanical properties of borided AISI H13 and 304 steels. Mater. Des. 28, 1836 (2007).CrossRefGoogle Scholar
Kayali, Y., Taktak, S., Ulu, S., and Yalcin, Y.: Investigation of mechanical properties of boro-tempered ductile iron. Mater. Des. 31, 1799 (2010).CrossRefGoogle Scholar
Tsipas, D.N., Triantafyllidis, G.K., Kiplagat, K.J., and Psillaki, P.: Degradation behaviour of boronized carbon and high alloy steels in molten aluminium and zinc. Mater. Lett. 37, 128 (1998).CrossRefGoogle Scholar
Ma, S.Q., Xing, J.D., Fu, H.G., Yi, D.W., Zhi, X.H., and Li, Y.F.: Effects of boron concentration on the corrosion resistance of Fe-B alloys immersed in 460 °C molten zinc bath. Surf. Coat. Technol. 204, 2208 (2010).CrossRefGoogle Scholar
Ma, S.Q., Xing, J.D., Yi, D.W., Fu, H.G., Zhang, J.J., Li, Y.F., Zhang, Z.Y., Liu, G.F., and Zhu, B.J.: Interfacial morphology and corrosion resistance of Fe-B cast steel containing chromium and nickel in liquid zinc. Corros. Sci. 53, 2826 (2011).CrossRefGoogle Scholar
Ma, S.Q., Xing, J.D., Yi, D.W., Fu, H.G., Zhang, J.J., Li, Y.F., Zhang, Z.Y., Liu, G.F., and Zhu, B.J.: Microstructure and corrosion behavior of cast Fe-B alloys dipped into liquid zinc bath. Mater. Charact. 61, 866 (2010).CrossRefGoogle Scholar
Tsipas, D.N. and Rus, J.: Boronizing of alloy steels. J. Mater. Sci. Lett. 6, 118 (1987).CrossRefGoogle Scholar
Yi, D.W., Xing, J.D., Ma, S.Q., Fu, H.G., Li, Y.F., Chen, W., Yan, J.B., Zhang, J.J., and Zhang, R.R.: Investigations on microstructures and two-body abrasive wear behavior of Fe-B cast alloy. Tribol. Lett. 45, 427 (2012).CrossRefGoogle Scholar
Huang, Z.F., Xing, J.D., and Guo, C.: Improving fracture toughness and hardness of Fe2B in high boron white cast iron by chromium addition. Mater. Des. 31, 3084 (2010).CrossRefGoogle Scholar
Coronado, J.J.: Effect of (Fe,Cr)7C3 carbide orientation on abrasion wear resistance and fracture toughness. Wear 270, 287 (2011).CrossRefGoogle Scholar
Doğan, Ö.N. and Hawk, J.A.: Effect of carbide orientation on abrasion of high Cr white cast iron. Wear 189, 136 (1995).CrossRefGoogle Scholar
Wang, S.R., Song, L.H., Qiao, Y., and Wang, M.: Effect of carbide orientation on impact-abrasive wear resistance of high-Cr iron used in shot blast machine. Tribol. Lett. 50, 439 (2013).CrossRefGoogle Scholar
Sun, L., Gao, Y.M., Xiao, B., Li, Y.F., and Wang, G.L.: Anisotropic elastic and thermal properties of titanium borides by first-principles calculations. J. Alloys Compd. 579, 457 (2013).CrossRefGoogle Scholar
Yin, F.C., Ruan, X.L., Zhao, M.X., Liu, Y.X., and Li, Z.: The 600 °C and 450 °C isothermal sections of the Zn-Fe-B system. J. Alloys Compd. 565, 79 (2013).CrossRefGoogle Scholar
Huang, Z.F., Ma, S.Q., Xing, J.D., and Wang, B.Y.: Bulk Fe2B crystal fabricated by mechanical ball milling and plasma activated sintering. J. Alloys Compd. 582, 196 (2014).CrossRefGoogle Scholar
Liu, W.C., Jiang, L.K., Cao, L., Mei, J., Wu, G.H., Zhang, S., Xiao, L., Wang, S.H., and Ding, W.J.: Fatigue behavior and plane-strain fracture toughness of sand-cast Mg-10Gd-3Y-0.5Zr magnesium alloy. Mater. Des. 59, 466 (2014).CrossRefGoogle Scholar
Wang, W.J., Lin, J.P., Wang, Y.L., and Chen, G.L.: The corrosion of Fe3Al alloy in liquid zinc. Corros. Sci. 1340 (2007).CrossRefGoogle Scholar
Ma, S.Q., Xing, J.D., Fu, H.G., He, Y.L., Bai, Y., Li, Y.F., and Bai, Y.P.: Interface characteristics and corrosion behaviour of oriented bulk Fe2B alloy in liquid zinc. Corros. Sci. 78, 71 (2014).CrossRefGoogle Scholar
Raghavan, V.: B-Fe-Si (boron-iron-silicon). J. Phase Equilib. Diffus. 28, 380 (2007).CrossRefGoogle Scholar
Aronsson, B. and Engström, I.: X-ray investigations on Me-Si-B systems (Me=Mn, Fe, Co). II. Some features of the Fe-Si-B and Mn-Si-B systems. Acta Chem. Scand. 14, 1403 (1960).CrossRefGoogle Scholar
Li, Y. and Chang, R.P.H.: Synthesis and characterization of iron silicon boron (Fe5Si2B) and iron boride (Fe3B) nanowires. J. Am. Chem. Soc. 128, 12778 (2006).CrossRefGoogle ScholarPubMed
Li, M.S., Fu, S.L., Xu, W.D., Zhang, R.L., and Yu, R.H.: Valence electron structure of Fe2B phase and its eigen-brittleness. Acta Metall. Sin. 31, 201 (1995).Google Scholar
Xiao, B., Xing, J.D., Ding, S.F., and Su, W.: Stability, electronic and mechanical properties of Fe2B. Phys. B 403, 1723 (2008).CrossRefGoogle Scholar
Van de Walle, A. and Ceder, G.: The effect of lattice vibrations on substitutional alloy thermodynamics. Rev. Mod. Phys. 74, 11 (2002).CrossRefGoogle Scholar
Quong, A.A. and Liu, A.Y.: First-principles calculations of the thermal expansion of metals. Phys. Rev. B 56, 7767 (1997).CrossRefGoogle Scholar
Hernández-Sanchez, E., Rodriguez, G., Meneses-Amador, A., Bravo-Bárcenas, D., Arzate-Vazquez, I., Martínez-Gutiérrez, H., Romero-Romo, M., and Campos-Silva, I.: Effect of the anisotropic growth on the fracture toughness measurements obtained in the Fe2B layer. Surf. Coat. Technol. 237, 292 (2013).CrossRefGoogle Scholar
Guo, C.Q.: Modeling of spatial distribution of the eutectic M2B borides in Fe-Cr-B cast irons. J. Mater. Sci. 39, 1109 (2004).CrossRefGoogle Scholar
Ma, S.Q., Xing, J.D., Liu, G.F., Yi, D.W., Fu, H.G., Zhang, J.J., and Li, Y.F.: Effect of chromium concentration on microstructure and properties of Fe-3.5B alloy. Mater. Sci. Eng., A 527, 6800 (2010).CrossRefGoogle Scholar
Wang, W.J., Lin, J.P., Wang, Y.L., and Chen, G.L.: The corrosion of intermetallic alloys in liquid zinc. J. Alloys Compd. 428, 237 (2007).CrossRefGoogle Scholar
Marder, A.R.: The metallurgy of zinc-coated steel. Prog. Mater. Sci. 45, 191 (2000).CrossRefGoogle Scholar
Dybkov, V.I. and Duchenko, O.V.: Growth kinetics of compound layers at the nickel-bismuth interface. J. Alloys Compd. 234, 295 (1996).CrossRefGoogle Scholar