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Liquid–liquid extraction of oxide particles and application in supercapacitors

Published online by Cambridge University Press:  28 March 2017

Ri Chen ,
Mustafa S. Ata ,
Xinya Zhao ,
Ishwar Puri  and
Igor Zhitomirsky
Ri Chen
Affiliation:
Department of Mechanical Engineering, McMaster University, Hamilton, Ontario, Canada L8S 4L7; and Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario, Canada L8S 4L7
Mustafa S. Ata
Affiliation:
Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario, Canada L8S 4L7
Xinya Zhao
Affiliation:
Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario, Canada L8S 4L7
Ishwar Puri
Affiliation:
Department of Mechanical Engineering, McMaster University, Hamilton, Ontario, Canada L8S 4L7; and Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario, Canada L8S 4L7
Igor Zhitomirsky*
Affiliation:
Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario, Canada L8S 4L7
*
a)Address all correspondence to this author. e-mail: zhitom@mcmaster.ca
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Abstract

Many material manufacturing techniques require the use of nonaqueous colloidal suspensions, containing well dispersed oxide particles and various water insoluble functional components. We report an efficient method for the direct transfer of MnO2 and titania particles, synthesized in water, to an organic solvent through the interface of two immiscible liquids. Particle agglomeration during the drying stage was avoided, and stable suspensions of nonagglomerated particles in the organic phase were obtained. The benefits of this method were demonstrated by the fabrication of advanced composite MnO2-multiwalled carbon nanotube electrodes, containing a polymer binder, for electrochemical supercapacitors with high active mass loading and high active material to current collector mass ratio. The electrodes showed a capacitance of 5.13 F/cm2 and low impedance. High extraction efficiency from concentrated suspensions was achieved by the use of an advanced extractor, which allowed strong adsorption on the particles by the polydentate bonding. The extraction mechanism is discussed.

Keywords

adsorptioncolloidenergy storage
Type
Invited Articles
Information
Journal of Materials Research , Volume 32 , Issue 17: Focus Issue: Achieving Superior Ceramics and Coating Properties through Innovative Processing , 14 September 2017 , pp. 3242 - 3250
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Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Eugene Medvedovski

References

REFERENCES

Otsuki, A., Dodbiba, G., Shibayama, A., Sadaki, J., Mei, G., and Fujita, T.: Separation of rare earth fluorescent powders by two-liquid flotation using organic solvents. Jpn. J. Appl. Phys. 47, 5093 (2008).Google Scholar
Wang, L.P., Kanemitsu, Y., Dodbiba, G., Fujita, T., Oya, Y., and Yokoyama, H.: Separation of ultrafine particles of alumina and zircon by liquid–liquid extraction using kerosene as the organic phase and sodium dodecylsulfate (SDS) as the surfactant collector for abrasive manufacturing waste recycling. Sep. Purif. Technol. 108, 133 (2013).CrossRefGoogle Scholar
Cheng, W. and Wang, E.: Size-dependent phase transfer of gold nanoparticles from water into toluene by tetraoctylammonium cations: A wholly electrostatic interaction. J. Phys. Chem. B 108, 24 (2004).Google Scholar
Zambrana, G., Medina, R., Gutierrez, G., and Vargas, R.: Recovery of minus ten micron cassiterite by liquid–liquid extraction. Int. J. Miner. Process. 1, 335 (1974).Google Scholar
Hu, B., Nakahiro, Y., and Wakamatsu, T.: The effect of organic solvents on the recovery of fine mineral particles by liquid–liquid extraction. Miner. Eng. 6, 731 (1993).CrossRefGoogle Scholar
Gaponik, N., Talapin, D.V., Rogach, A.L., Eychmuller, A., and Weller, H.: Efficient phase transfer of luminescent thiol-capped nanocrystals: From water to nonpolar organic solvents. Nano Lett. 2, 803 (2002).CrossRefGoogle Scholar
Yao, H., Momozawa, O., Hamatani, T., and Kimura, K.: Phase transfer of gold nanoparticles across a water/oil interface by Stoichiometric ion-pair formation on particle surfaces. Bull. Chem. Soc. Jpn. 73, 2675 (2000).Google Scholar
Erler, J., Machunsky, S., Grimm, P., Schmid, H-J., and Peuker, U.A.: Liquid–liquid phase transfer of magnetite nanoparticles-evaluation of surfactants. Powder Technol. 247, 265 (2013).Google Scholar
Karg, M., Schelero, N., Oppel, C., Gradzielski, M., Hellweg, T., and von Klitzing, R.: Versatile phase transfer of gold nanoparticles from aqueous media to different organic media. Chem.–Eur. J. 17, 4648 (2011).Google Scholar
Kumar, A., Mukherjee, P., Guha, A., Adyantaya, S., Mandale, A., Kumar, R., and Sastry, M.: Amphoterization of colloidal gold particles by capping with valine molecules and their phase transfer from water to toluene by electrostatic coordination with fatty amine molecules. Langmuir 16, 9775 (2000).CrossRefGoogle Scholar
Mayya, K.S. and Caruso, F.: Phase transfer of surface-modified gold nanoparticles by hydrophobization with alkylamines. Langmuir 19, 6987 (2003).CrossRefGoogle Scholar
Kumar, A., Joshi, H., Pasricha, R., Mandale, A., and Sastry, M.: Phase transfer of silver nanoparticles from aqueous to organic solutions using fatty amine molecules. J. Colloid Interface Sci. 264, 396 (2003).CrossRefGoogle ScholarPubMed
Underwood, S. and Mulvaney, P.: Effect of the solution refractive index on the color of gold colloids. Langmuir 10, 3427 (1994).Google Scholar
Feng, X., Ma, H., Huang, S., Pan, W., Zhang, X., Tian, F., Gao, C., Cheng, Y., and Luo, J.: Aqueous-organic phase-transfer of highly stable gold, silver, and platinum nanoparticles and new route for fabrication of gold nanofilms at the oil/water interface and on solid supports. J. Phys. Chem. B 110, 12311 (2006).Google Scholar
Casagrande, T., Lawson, G., Li, H., Wei, J., Adronov, A., and Zhitomirsky, I.: Electrodeposition of composite materials containing functionalized carbon nanotubes. Mater. Chem. Phys. 111, 42 (2008).Google Scholar
Su, Y. and Zhitomirsky, I.: Hybrid MnO2/carbon nanotube-VN/carbon nanotube supercapacitors. J. Power Sources 267, 235 (2014).Google Scholar
Pujari, S.P., Scheres, L., Marcelis, A., and Zuilhof, H.: Covalent surface modification of oxide surfaces. Angew. Chem., Int. Ed. 53, 6322 (2014).CrossRefGoogle ScholarPubMed
Boissezon, R., Muller, J., Beaugeard, V., Monge, S., and Robin, J-J.: Organophosphonates as anchoring agents onto metal oxide-based materials: Synthesis and applications. RSC Adv. 4, 35690 (2014).Google Scholar
Kalska-Szostko, B., Rogowska, M., and Satula, D.: Organophosphorous functionalization of magnetite nanoparticles. Colloids Surf., B 111, 656 (2013).Google Scholar
Li, F., Zhong, H., Zhao, G., Wang, S., and Liu, G.: Adsorption of α-hydroxyoctyl phosphonic acid to ilmenite/water interface and its application in flotation. Colloids Surf., A 490, 67 (2016).Google Scholar
Pauly, C.l.S., Genix, A-C., Alauzun, J.G., Sztucki, M., Oberdisse, J., and Mutin, P.H.: Surface modification of alumina-coated silica nanoparticles in aqueous sols with phosphonic acids and impact on nanoparticle interactions. Phys. Chem. Chem. Phys. 17, 19173 (2015).Google Scholar
Thomas, G., Demoisson, F., Boudon, J., and Millot, N.: Efficient functionalization of magnetite nanoparticles with phosphonate using a one-step continuous hydrothermal process. Dalton Trans. 45, 10821 (2016).CrossRefGoogle ScholarPubMed
Kar, P., Pandey, A., Greer, J.J., and Shankar, K.: Ultrahigh sensitivity assays for human cardiac troponin I using TiO2 nanotube arrays. Lab Chip 12, 821 (2012).CrossRefGoogle ScholarPubMed
Ata, M., Liu, Y., and Zhitomirsky, I.: A review of new methods of surface chemical modification, dispersion and electrophoretic deposition of metal oxide particles. RSC Adv. 4, 22716 (2014).Google Scholar
Subramanian, V., Zhu, H., and Wei, B.: Alcohol-assisted room temperature synthesis of different nanostructured manganese oxides and their pseudocapacitance properties in neutral electrolyte. Chem. Phys. Lett. 453, 242 (2008).Google Scholar
Cheong, M. and Zhitomirsky, I.: Electrophoretic deposition of manganese oxide films. Surf. Eng. 25, 346 (2009).Google Scholar
Li, J. and Zhitomirsky, I.: Electrophoretic deposition of manganese oxide nanofibers. Mater. Chem. Phys. 112, 525 (2008).Google Scholar
Taberna, P., Simon, P., and Fauvarque, J.F.: Electrochemical characteristics and impedance spectroscopy studies of carbon-carbon supercapacitors. J. Electrochem. Soc. 150, A292 (2003).Google Scholar
Machunsky, S. and Peuker, U.A.: Liquid–liquid interfacial transport of nanoparticles. Phys. Separ. Sci. Eng. 2007, 34832 (2007).Google Scholar
Giza, M., Thissen, P., and Grundmeier, G.: Adsorption kinetics of organophosphonic acids on plasma-modified oxide-covered aluminum surfaces. Langmuir 24, 8688 (2008).Google Scholar
Dzunuzovic, E.S., Dzunuzovic, J.V., Marinkovic, A.D., Marinovic-Cincovic, M.T., Jeremic, K.B., and Nedeljkovic, J.M.: Influence of surface modified TiO2 nanoparticles by gallates on the properties of PMMA/TiO2 nanocomposites. Eur. Polym. J. 48, 1385 (2012).Google Scholar
Zhitomirsky, I. and Petric, A.: Electrophoretic deposition of ceramic materials for fuel cell applications. J. Eur. Ceram. Soc. 20, 2055 (2000).Google Scholar
Zhitomirsky, I. and Petric, A.: Electrophoretic deposition of electrolyte materials for solid oxide fuel cells. J. Mater. Sci. 39, 825 (2004).Google Scholar
Toor, A., Feng, T., and Russell, T.P.: Self-assembly of nanomaterials at fluid interfaces. Eur. Phys. J. E 39, 1 (2016).Google Scholar
Andala, D.M., Shin, S.H.R., Lee, H-Y., and Bishop, K.J.: Templated synthesis of amphiphilic nanoparticles at the liquid–liquid interface. ACS Nano 6, 1044 (2012).Google Scholar
Lee, W.P., Chen, H., Dryfe, R., and Ding, Y.: Kinetics of nanoparticle synthesis by liquid–liquid interfacial reaction. Colloids Surfaces A. 343, 3 (2009).CrossRefGoogle Scholar
Liang, X., Xing, L., Xiang, J., Zhang, F., Jiao, J., Cui, L., Song, B., Chen, S., Zhao, C., and Sai, H.: The role of the liquid–liquid interface in the synthesis of nonequilibrium crystalline Wurtzite ZnS at room temperature. Cryst. Growth Des. 12, 1173 (2012).Google Scholar
Li, Y., Wu, K., and Zhitomirsky, I.: Electrodeposition of composite zinc oxide-chitosan films. Colloids Surf., A 356, 63 (2010).Google Scholar
Li, J. and Zhitomirsky, I.: Cathodic electrophoretic deposition of manganese dioxide films. Colloids Surf., A 348, 248 (2009).Google Scholar
Jacob, G.M., Yang, Q.M., and Zhitomirsky, I.: Electrodes for electrochemical supercapacitors. Mater. Manuf. Process. 24, 1359 (2009).Google Scholar
Devaraj, S. and Munichandraiah, N.: High capacitance of electrodeposited MnO2 by the effect of a surface-active agent. Electrochem. Solid-State Lett. 8, A373 (2005).CrossRefGoogle Scholar
Athouel, L., Moser, F., Dugas, R., Crosnier, O., Bélanger, D., and Brousse, T.: Variation of the MnO2 birnessite structure upon charge/discharge in an electrochemical supercapacitor electrode in aqueous Na2SO4 electrolyte. J. Phys. Chem. C 112, 7270 (2008).Google Scholar
Bélanger, D., Brousse, T., and Long, J.W.: Manganese oxides: Battery materials make the leap to electrochemical capacitors. Electrochem. Soc. Interf. 17, 49 (2008).Google Scholar
Jiang, R., Huang, T., Tang, Y., Liu, J., Xue, L., Zhuang, J., and Yu, A.: Factors influencing MnO2/multi-walled carbon nanotubes composite’s electrochemical performance as supercapacitor electrode. Electrochim. Acta 54, 7173 (2009).Google Scholar
Toupin, M., Brousse, T., and Belanger, D.: Charge storage mechanism of MnO2 electrode used in aqueous electrochemical capacitor. Chem. Mater. 16, 3184 (2004).Google Scholar
Nam, K-W. and Kim, K-B.: Manganese oxide film electrodes prepared by electrostatic spray deposition for electrochemical capacitors. J. Electrochem. Soc. 153, A81 (2006).Google Scholar
Xia, H. and Huo, C.: Electrochemical properties of MnO2/CNT nanocomposite in neutral aqueous electrolyte as cathode material for asymmetric supercapacitors. Int. J. Smart Nano Mater. 2, 283 (2011).Google Scholar
Jacob, G.M. and Zhitomirsky, I.: Microstructure and properties of manganese dioxide films prepared by electrodeposition. Appl. Surf. Sci. 254, 6671 (2008).Google Scholar
Li, J. and Zhitomirsky, I.: Electrophoretic deposition of manganese dioxide-carbon nanotube composites. J. Mater. Process. Technol. 209, 3452 (2009).Google Scholar
Wang, Y., Liu, Y., and Zhitomirsky, I.: Surface modification of MnO2 and carbon nanotubes using organic dyes for nanotechnology of electrochemical supercapacitors. J. Mater. Chem. A 1, 12519 (2013).Google Scholar
Zhu, Y., Shi, K., and Zhitomirsky, I.: Anionic dopant-dispersants for synthesis of polypyrrole coated carbon nanotubes and fabrication of supercapacitor electrodes with high active mass loading. J. Mater. Chem. A 2, 14666 (2014).Google Scholar