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The Chemistry of ethylenediamine Tetra-Acetic acid in sea water

Published online by Cambridge University Press:  11 May 2009

C. P. Spencer
C. P. Spencer
Affiliation:
Marine Biology Station, University College of North Wales
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Extract

A general formula has been derived for the quantitative treatment of systems involving a number of interdependent equilibria. The formula has been applied specifically to the equilibria set up between metallic cations and their chelates when EDTA is added to sea water. This system involves competition for the fully dissociated quadrivalent anion of EDTA (the principal ion of EDTA which forms complexes) by the metallic cations and by the hydrogenions present. The equilibrium concentration of a metallic cation in any particular case will depend upon the equilibrium concentration of the quadrivalent anion of EDTA, in the sense that the higher the concentration of this ion the lower will be the concentration of the metallic cation. The general formula allows the calculation of the equilibrium concentration of the quadrivalent EDTA anion, and from this the concentrations at equilibrium of each metallic cation can be readily found.

Type
Research Article
Information
Journal of the Marine Biological Association of the United Kingdom , Volume 37 , Issue 1 , February 1958 , pp. 127 - 144
Copyright
Copyright © Marine Biological Association of the United Kingdom 1958

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References

Calvin, M. & Martell, A. E., 1953.Chemistry of Metal Chelate Compounds. New York: Prentice-Hall, Inc.Google Scholar
Carini, F. F. & Marteix, A. E., 1952. The effect of potassium chloride on the equilibrium between ethylene diamine tetra-acetate and calcium ions. J. Atner. chem. Soc, Vol. 74, pp. 5745–8.CrossRefGoogle Scholar
Chaberek, S.Bersworth, F. C. & Martell, A. E., 1955. Chelating agents as metal buffers in biological systems. I. Principles and use of ethylene diamine tetraacetic acid. Arch. Biochem. Biophys., Vol. 55, pp. 321–37.CrossRefGoogle Scholar
Mitchell, P. H. & Rakestraw, N. W., 1933. The buffer capacity of sea water. Biol. Bull, Woods Hole, Vol. 65, pp. 437–51.CrossRefGoogle Scholar
Raaflaub, J., 1956. Application of metal buffers and metal indicators in biochemistry. Methods of Biochemical Analysis, Vol. 3, pp. 301–25. New York: Interscience Publishers, Inc.CrossRefGoogle Scholar
Sverdrup, H. U.Johnson, M. W. & Fleming, R. H., 1942.The Oceans, their Physics, Chemistry and General Biology. New York: Prentice-Hall, Inc.Google Scholar