Hostname: page-component-77c89778f8-rkxrd Total loading time: 0 Render date: 2024-07-20T11:28:08.460Z Has data issue: false hasContentIssue false

The structure of aragonite

Published online by Cambridge University Press:  14 March 2018

Serge I. Tomkeieff*
Affiliation:
Geological Department, Armstrong College, Newcastle-upon-Tyne

Extract

We are unable to observe crystalline structure directly, and can only infer it by observation of the physical and chemical properties possessed by a crystal. It is quite reasonable to suppose that every vectorial property possessed by a crystal is dependent upon its leptonic structure. The X-ray method, which has produced such a revolutionary change in our Knowledge of crystal-structure, is not sufficient in some cases for the determination of leptonic structure. The X-ray spectral analysis gives only the spacings between the atomic planes of a crystal. The application of the method of intensities, which was so successful in the case of simple cubic crystals, may not be so in the case of crystals of a Inore complex chemical composition and of a lower symmetry. It is thus desirable to combine several methods and so approach the problem from different directions.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1925

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Page 408 note 1 The term ‘leptonic’ (λ∊πós, small, fine) was suggested by F. Rinne (Das feinbauliche Wesen der Materio nach dem Vorbildo der Kristalle. Berlin, 1922. Engl. transl, by W. S. Stiles, London, 1924). [Min. Abstr., vol. 2, p. 414.]

Page 409 note 1 Wherry, E. T., Amphisymmetric crystals. Amer. Journ. Sci., 1922, set. 5, vol. 4, p. 237 CrossRefGoogle Scholar. [Min. Abstr., vol. 2, p. 106.]

Page 409 note 2 J. Beckenkamp, F. Wallerant, C. Viola.

Page 410 note 1 Beckenkamp, J., Zeits. Kryst. Min., 1888, vol. 14, p. 376 Google Scholar; 1890, vol. 17, p. 321.

Page 410 note 2 Hankel, W. G., Über die thermoelektrischen Eigenschaften des Aragonites. Abhand. math.-physischen Cl. Sächs. Gesell. Wiss., 1874, vol. 10, pp. 348416 Google Scholar.

Page 411 note 1 Wallerant, F., Étude sur la forme primitive des corps cristallisés et sur la symétrie apparente. Bull. Soc. Franç. Min., 1901, vol. 24, p. 194 Google Scholar.

Page 411 note 2 Huggins, M. L., The crystal structures of aragonito (CaCO3) and related minerals. Physical Rey., 1922, vol. 19, p. 354. [Min. Abstr., vol. 21 p. 330Google Scholar].

Page 412 note 1 Bragg, W. L., The structure of aragonite. Proc. Roy. Soc. London, 1924, ser. A, vol. 105, p. 16.CrossRefGoogle Scholar [Min. Abstr, vol. 2, p. 195.]

Page 417 note 1 Linck, G., Über die Bildung der Carbonate des Calciums, Magnesiums und Eisens. C. Doelter's Handbuoh der Mineralehemie, 1911, vol. 1, p. 113 Google Scholar.

Page 417 note 2 H. Leitmeier. Ibid, 1912, vol. 1, pp. 350-1.

Page 420 note 1 Mallard, E., Traité de cristallographic, 1879, vol. 1, p. 806 Google Scholar (incorrectly numbered 305).

Page 422 note 1 Story-Maskelyne, N., The morphology of crystals, 1895, p. 99.Google Scholar

Page 431 note 1 Hilton, H., Mathematical crystallography, 1908, p. 46.Google Scholar

Page 432 note 1 Viola, C., Ueber den Aragonit von Sicilien und seine Structur. Zeits. Kryst. Min., 1897, vol. 28, p. 230 Google Scholar.

Page 432 note 2 Jaeger, F. M., Lectures on the principle of symmetry, 1917, p. 172 Google Scholar.

Page 432 note 3 E. Mallard, 1880. [F. M. Jaeger, loc. cit., p. 166.]

Page 432 note 4 W. H. and Bragg, W. L., X rays and crystal structure, 1921, p. 149 Google Scholar.

Page 433 note 1 Barlow, W., On homogeneous structures and the symmetrical partitioning of them, with application to crystals, Min. Mag., 1896, vol. 11, p. 119 CrossRefGoogle Scholar.

Page 433 note 2 Shearer, G., Molecular and crystal symmetry. Proc. Physical Soc. London, 1923, vol. 35, p. 86 Google Scholar.