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Bolotinaite, ideally (Na7□)(Al6Si6O24)F⋅4H2O, a new sodalite-group mineral from the Eifel palaeovolcanic region, Germany

Published online by Cambridge University Press:  10 August 2022

Nikita V. Chukanov ,
Natalia V. Zubkova ,
Christof Schäfer ,
I.V. Pekov ,
Roman Yu. Shendrik ,
Marina F. Vigasina Open the ORCID record for Marina F. Vigasina [Opens in a new window] ,
Dmitry I. Belakovskiy ,
Sergey N. Britvin Open the ORCID record for Sergey N. Britvin [Opens in a new window] ,
Vasiliy O. Yapaskurt  and
Dmitry Yu. Pushcharovsky
Nikita V. Chukanov*
Affiliation:
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432 Russia Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Natalia V. Zubkova
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Christof Schäfer
Affiliation:
Gustav Stresemann-Strasse 34, 74257 Untereisesheim, Germany
I.V. Pekov
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Kosygina str. 19, 119991 Moscow, Russia
Roman Yu. Shendrik
Affiliation:
Vinogradov Institute of Geochemistry, Siberian Branch of Russian Academy of Sciences, 1a Favorskii St., Irkutsk, 664033, Russia
Marina F. Vigasina
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Dmitry I. Belakovskiy
Affiliation:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Leninsky Prospekt 18-2, 119071 Moscow, Russia
Sergey N. Britvin
Affiliation:
Department of Crystallography, St Petersburg State University, Universitetskaya Nab. 7/9, 199034 St Petersburg, Russia
Vasiliy O. Yapaskurt
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Dmitry Yu. Pushcharovsky
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
*
*Author for correspondence: Nikita V. Chukanov, Email: chukanov@icp.ac.ru
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Abstract

The new sodalite-group mineral bolotinaite, ideally (Na7□)(Al6Si6O24)F⋅4H2O, was discovered in a volcanic ejectum of trachitoid sanidinite collected from the In den Dellen (Zieglowski) pumice quarry, Laach Lake (Laacher See) palaeovolcano, Eifel region, Rhineland-Palatinate, Germany. The associated minerals are sanidine, nepheline, annite and zircon. Bolotinaite occurs as isolated interpenetration prismatic twins on (111) up to 1.3 mm long, complex twins, and rare non-twinned rhombic dodecahedra up to 0.2 mm across. The colour of bolotinaite is pale yellow to pinkish coloured, the streak is white and the lustre is vitreous. Weak orange–yellow fluorescence under longwave ultraviolet radiation (λ = 330 nm) is due to the presence of trace amounts of the S2•– radical anion. Bolotinaite is brittle, with a Mohs’ hardness of 5. No cleavage is observed. The fracture is uneven. D(meas) = 2.27(2) g⋅cm–3, D(calc) = 2.291 g⋅cm–3. Bolotinaite is optically isotropic, with n = 1.488(2) (λ = 589 nm). The chemical composition is (wt.%, electron microprobe, CO2 determined by quantitative IR spectroscopy analysis, H2O calculated from the empirical formula with four H2O molecules per formula unit): Na2O 18.30, K2O 3.87, CaO 0.57, Al2O3 28.85, SiO2 37.97, CO2 1.66, SO3 1.37, F 1.60, Cl 0.57, 2.22, H2O 7.21, –O≡(F,Cl) –0.80, total 101.17. The empirical formula is (Na5.92K0.82Ca0.10H0.08)(Si6.33Al5.67O24)(SO4)0.17F0.84Cl0.16(H2O)3.96(CO2)0.38. A high content of H2O and the presence of CO2 molecules and H+ cations as well as trace amounts of S2•– are confirmed by means of infrared and Raman spectroscopy. The crystal structure was determined using single-crystal X-ray diffraction data and refined to R = 0.0335. Bolotinaite is cubic, space group I$\bar{4}$3m, with a = 9.027(1) Å, V = 735.7(2) Å3 and Z = 1. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 6.36 (47) (110), 4.502 (10) (200), 3.679 (100) (211), 2.851 (28) (310), 2.603 (29) (222) and 2.126 (18) (330). The mineral is named in honour of the Russian crystallographer and crystal chemist Dr. Nadezhda Borisovna Bolotina (b. 1949).

Keywords

bolotinaitenew mineralsodalite groupcrystal structureIR spectroscopyRaman spectroscopyLaach Lake palaeovolcanoEifelGermany
Type
Article
Information
Mineralogical Magazine , Volume 86 , Issue 6 , December 2022 , pp. 920 - 928
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Juraj Majzlan

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