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New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIII. Pansnerite, K3Na3Fe3+6(AsO4)8

Published online by Cambridge University Press:  30 July 2019

Igor V. Pekov ,
Natalia V. Zubkova ,
Natalia N. Koshlyakova ,
Atali A. Agakhanov ,
Dmitry I. Belakovskiy ,
Marina F. Vigasina ,
Vasiliy O. Yapaskurt ,
Sergey N. Britvin ,
Anna G. Turchkova  and
Evgeny G. Sidorov
...Show all authors
Igor V. Pekov*
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991Moscow, Russia
Natalia V. Zubkova
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991Moscow, Russia
Natalia N. Koshlyakova
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991Moscow, Russia
Atali A. Agakhanov
Affiliation:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Leninsky Prospekt 18-2, 119071Moscow, Russia
Dmitry I. Belakovskiy
Affiliation:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Leninsky Prospekt 18-2, 119071Moscow, Russia
Marina F. Vigasina
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991Moscow, Russia
Vasiliy O. Yapaskurt
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991Moscow, Russia
Sergey N. Britvin
Affiliation:
Dept. of Crystallography, St Petersburg State University, University Embankment 7/9, 199034St Petersburg, Russia
Anna G. Turchkova
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991Moscow, Russia
Evgeny G. Sidorov
Affiliation:
Institute of Volcanology and Seismology, Far Eastern Branch of Russian Academy of Sciences, Piip Boulevard 9, 683006Petropavlovsk-Kamchatsky, Russia
Dmitry Y. Pushcharovsky
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991Moscow, Russia
*
*Author for correspondence: Igor V. Pekov, Email: igorpekov@mail.ru
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Abstract

The new mineral pansnerite, ideally K3Na3Fe3+6(AsO4)8, was found in the Arsenatnaya fumarole at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. It is associated with aphthitalite, hematite, sanidine, badalovite, khrenovite, achyrophanite, arsenatrotitanite, ozerovaite, tilasite, calciojohillerite, johillerite, nickenichite, svabite, katiarsite, yurmarinite, anhydrite, rutile, cassiterite and pseudobrookite. Pansnerite forms tabular to lamellar (flattened on {010}), usually pseudo-hexagonal crystals up to 0.2 mm × 0.7 mm × 1 mm and crystal clusters up to 2 mm across. It is transparent to translucent, light green, pale greenish, yellowish–greenish or yellowish, with vitreous lustre. The mineral is brittle, with perfect {010} cleavage. The Mohs’ hardness is ca 3. Dcalc is 3.596 g cm–3. Pansnerite is optically biaxial (–), α = 1.702(4), β = 1.713(4), γ = 1.717(4), 2Vmeas = 45(10)° and 2Vcalc = 62°. Chemical composition (holotype, wt.%, electron microprobe data) is: Na2O 6.39, K2O 8.52, CaO 0.08, MgO 0.08, MnO 0.02, NiO 0.02, CuO 1.35, ZnO 0.34, Al2O3 7.35, Cr2O3 0.04, Fe2O3 16.72, SiO2 0.16, P2O5 0.22, V2O5 0.09, As2O5 57.76, SO3 0.04, total 99.20. The empirical formula based on 32 O apfu is K2.86Na3.26Ca0.02(Fe3+3.31Al2.28Cu0.27Zn0.07Mg0.03Cr0.01)Σ5.97(As7.95P0.05Si0.04V0.02S0.01)Σ8.06O32. Pansnerite is orthorhombic, Cmce, a = 10.7372(3), b = 20.8367(8), c = 6.47335(15) Å, V = 1448.27(7) Å3 and Z = 2. The strongest reflections of the X-ray powder diffraction pattern [d,Å(I)(hkl)] are: 10.49(100)(020), 5.380(88)(111), 4.793(65)(220), 3.105(46)(311, 002), 3.079(32)(112, 061), 2.932(35)(260), 2.783(65)(202) and 2.694(52)(400, 222). The crystal structure was solved from single-crystal X-ray diffraction data, R1 = 2.82%. The structure is based on heteropolyhedral layers formed by MO6 octahedra (M = Fe3+ and Al) sharing common vertices and connected by AsO4 tetrahedra. Na+ and K+ cations are located in the interlayer space. The mineral is named in honour of the German–Russian mineralogist and geographer Lavrentiy Ivanovich Pansner (1777–1851). Pansnerite forms a solid-solution series with the isotypic mineral ozerovaite, ideally KNa2Al3(AsO4)4.

Keywords

pansneritenew mineralpotassium sodium iron arsenateozerovaitecrystal structurefumarole sublimateTolbachik volcanoKamchatka
Type
Article
Information
Mineralogical Magazine , Volume 84 , Issue 1 , February 2020 , pp. 143 - 151
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019

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Footnotes

Associate Editor: Michael Rumsey

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