Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-24T16:40:07.323Z Has data issue: false hasContentIssue false
  • English
  • Français

Relation between cathodoluminescence and trace-element distribution of magmatic topaz from the Ary-Bulak massif, Russia

Published online by Cambridge University Press:  02 January 2018

Andrea Agangi ,
Arnold Gucsik ,
Hirotsugu Nishido ,
Kiyotaka Ninagawa  and
Vadim S. Kamenetsky
Andrea Agangi*
Affiliation:
Department of Geology, University of Johannesburg, Auckland Park 2006, South Africa Department of Applied Geology, Curtin University, Bentley, WA 6102, Australia
Arnold Gucsik
Affiliation:
Department of Geology, University of Johannesburg, Auckland Park 2006, South Africa
Hirotsugu Nishido
Affiliation:
Department of Applied Physics, Okayama University of Science, Okayama, Japan
Kiyotaka Ninagawa
Affiliation:
Research Institute for Natural Sciences, Okayama University of Science, Okayama, Japan
Vadim S. Kamenetsky
Affiliation:
School of Physical Sciences, University of Tasmania, Hobart, TAS 7001, Australia
*
E-mail: andrea.agangi@curtin.edu.au
Get access Rights & Permissions [Opens in a new window]

Abstract

In order to define the cathodoluminescence (CL) properties of magmatic topaz and its relation with trace-element composition, we studied topaz phenocrysts from the Ary-Bulak ongonite massif, Russia using a wide array of analytical techniques. Scanning electron microscopy CL panchromatic images reveal strong variations, which define micrometre-scale euhedral growth textures. Several truncations of these growth textures occur in single grains implying multiple growth and resorption events. The CL-spectra of both CLbright and -dark domains have a major peak in the near-ultraviolet centred at 393 nm. Cathodoluminescence images taken after several minutes of electron bombardment show decreasing emission intensity. Electron microprobe analyses indicate high F concentrations (average OH/(OH + F) = 0.04 calculated by difference, 100 wt.% – total from electron probe microanalyses), consistent with what has been found previously in topaz-bearing granites, and the OH stretching vibration (∼3653 cm–1) was detected in Raman spectra. Laser ablation inductively-coupled plasma mass spectrometry traverses performed across the CL textures detected trace elements at ppm to thousands of ppm levels, including: Fe, Mn, Li, Be, B, P, Nb, Ta, W, Ti, Ga, light rare-earth elements, Th and U. Lithium, W, Nb and Ta appear to be correlated with CL intensity, suggesting a role for some of these elements in the activation of CL in topaz. In contrast, no clear correlation was found between CL intensity and F contents, despite the fact that the replacement of OH for F is known to affect the cell parameters of topaz.

Keywords

topazfluorinelithiumongonitecathodoluminescenceRamanrare metals
Type
Research Article
Information
Mineralogical Magazine , Volume 80 , Issue 5 , August 2016 , pp. 881 - 899
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Agangi, A., McPhie, J. and Kamenetsky, V.S. (2011) Magma chamber dynamics in a silicic LIP revealed by quartz: The Mesoproterozoic Gawler Range Volcanics. Lithos, 126, 68–83.CrossRefGoogle Scholar
Agangi, A., Kamenetsky, V.S., Hofmann, A., Przybyłowicz, W. and Vladykin, N.V. (2014) Crystallisation of magmatic topaz and implications for Nb-Ta-W mineralisation in F-rich silicic melts - The Ary-Bulak ongonite massif. Lithos 202–203, 317–330.CrossRefGoogle Scholar
Akizuki, M., Hampar, M.S. and Zussman, J. (1979) An explanation of anomalous optical properties of topaz. Mineralogical Magazine, 43, 237—241.CrossRefGoogle Scholar
Alberico, A., Ferrando, S., Ivaldi, G. and Ferraris, G. (2003) X-ray single-crystal structure refinement of an OH-rich topaz from Sulu UHP terrane (Eastern China) - Structural foundation of the correlation between cell parameters and fluorine content. European Journal of Mineralogy, 15, 875–881.CrossRefGoogle Scholar
Alonso, PI, Halliburton, L.E., Kohnke, E.E. and Bossoli, R.B. (1983) X-ray induced luminescence in crystalline SiO2. Journal Applied Physics, 54, 5369–5375.CrossRefGoogle Scholar
Antipin, V.S., Andreeva, I.A., Kovalenko, V.I. and Kuznetsov, V.A. (2009) Geochemical specifics of ongonites in the Ary-Bulak Massif, eastern Transbaikalia. Petrology, 17, 558–569.CrossRefGoogle Scholar
Badanina, E.V., Trumbull, R.B., Dulski, P., Wiedenbeck, M., Veksler, I.V. and Syritso, L.F. (2006) The behavior of rare-earth and lithophile traace elements in rare-metal granites: a study of fluorite, melt inclusions and host rocks from the Khangilay Complex, Transbaikalia, Russia.The Canadian Mineralogist, 44, 667–692.CrossRefGoogle Scholar
Barton, M.D. (1982) The thermodynamic properties of topaz solid solutions and some petrologic applications. American Mineralogist, 67, 956–974.Google Scholar
Bastos, Neto A.C., Ferron, J.T.M..M., Chauvet, A., Chemale Jr, F., de Lima, E.F., Barbanson, L. and Costa, C.F.M.. (2014) U-Pb dating of the Madeira Suite and structural control of the albite-enriched granite at Pitinga (Amazonia, Brazil): Evolution of the A-type magmatism and implications for the genesis of the Madeira Sn-Ta-Nb (REE, cryolite) world-class deposit. Precambrian Research, 243, 181—196.Google Scholar
Beny, J.M. and Piriou, B. (1987) Vibrational spectra of single-crystal topaz. Physics and Chemistry of Minerals, 15, 148–159.CrossRefGoogle Scholar
Bradley, D. and McCauley, A. (2013) A preliminary deposit model for lithium-cesium-tantalum (LCT) pegmatites. U.S. Geological Survey Open-File Report, 2013–1008. U.S. Geological Survey, Reston, Virginia, USA, 7pp.Google Scholar
Breiter, K.M. (2009) Evolution of rare-metal granitic magmas documented by quartz chemistry. European Journal of Mineralogy, 21, 335—346.CrossRefGoogle Scholar
Breiter, K.M., Gardenová, N., Vaculovič, T and Kanický, V (2013) Topaz as an important host for Ge in granites and greisens. Mineralogical Magazine, 77, 403–417.CrossRefGoogle Scholar
Burns, R.G. (1993). Mineralogical applications of crystal field theory. Cambridge topics in mineral physics and chemistry, 5. 2nd Edition. Cambridge University Press, Cambridge, UK.CrossRefGoogle Scholar
Burt, D.M., Sheridan, M.F., Bikun, J.V. and Christiansen, E.H. (1982) Topaz rhyolites; distribution, origin, and significance for exploration. Economic Geology, 77, 1818–1836.CrossRefGoogle Scholar
Charoy, B. and Noronha, F. (1996) Multistage growth of a rare-element, volatile-rich microgranite at argemela (Portugal). Journal of Petrology, 37, 73–94.CrossRefGoogle Scholar
Cohen, A.J. (1960) Substitutional and interstitial aluminum impurity in quartz, structure and color center interrelationships. Journal of Physics and Chemistry of Solids, 13, 321–325.CrossRefGoogle Scholar
Congdon, R.D. and Nash, W.P. (1988) High-fluorine rhyolite: An eruptive pegmatite magma at the Honeycomb Hills, Utah. Geology, 16, 1018–1021.2.3.CO;2>CrossRefGoogle Scholar
Correcher, V., Garcia-Guinea, J., Martin-Fernandez, C. and Can, N. (2011) Thermal effect on the cathodo-and thermoluminescence emission of natural topaz (Al2SiO4(F,OH)2). Spectroscopy Letters, 44, 486–89.CrossRefGoogle Scholar
da Silva, N.D., Guedes, K.J., Pinheiro, M.V.B.., Schweizer, S., Spaeth, J-M. and Krambrock, K. (2005) The O-(Al2) centre in topaz and its relation to the blue colour. Physica Status Solidi C, 2, 397–400.CrossRefGoogle Scholar
Downs, R.T. (2006). The RRUFF Project: an integrated study of the chemistry, crystallography, Raman and infrared spectroscopy of minerals. Pp. 03—13.in: Program and Abstracts of the, 19th General Meeting of the International Mineralogical Association, Kobe, Japan.Google Scholar
Farges, F., Linnen, R.L. and Brown, G.E. (2006) Redox and speciation of tin in hydrous silicate glasses: a comparison with Nb, Ta, Mo and W. The Canadian Mineralogist, 44, 795–810.CrossRefGoogle Scholar
Fukumi, K and Sakka, S. (1988) Coordination state of Nb + ions in silicate and gallate glasses as studied by Raman spectroscopy. Journal of Materials Science, 23, 2819–2823.CrossRefGoogle Scholar
Gabitov, R.I., Gaetani, G.A., Watson, E.B., Cohen, A.L. and Ehrlich, H.L. (2008) Experimental determination of growth rate effect on U6+ and Mg2+ partitioning between aragonite and fluid at elevated U6+ concentration. Geochimica et Cosmochimica Acta, 72, 4058–1068.CrossRefGoogle Scholar
Gaft, M., Reisfeld, R., Panczer, G., Blank, P. and Boulon, G. (1998) Laser-induced time-resolved luminescence of minerals. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 54, 2163–2175.CrossRefGoogle Scholar
Gaft, M., Reisfeld, R. and Panczer, G. (2005) Modern Luminescence Spectroscopy of Minerals and Materials. Springer-Verlag, Heidelberg, 356pp.Google Scholar
Gatta, G.D., Nestola, F., Bromiley, G.D. and Loose, A. (2006) New insight into crystal chemistry of topaz: A multi-methodological study. American Mineralogist, 91, 1839–1846.CrossRefGoogle Scholar
Götze, J. (2012) Application of cathodoluminescence microscopy and spectroscopy in geosciences. Microscopy and Microanalysis, 18, 1270–1284.CrossRefGoogle ScholarPubMed
Götze, J., Plötze, M. and Habermann, D. (2001) Origin, spectral characteristics and practical applications of the cathodoluminescence (CL) of quartz — a review. Mineralogy and Petrology, 71, 225—250Google Scholar
Götze, J., Plötze, M., Graupner, T., Hallbauer, D.K. and Bray, C.J. (2004) Trace element incorporation into quartz: A combined study by ICP-MS, electron spin resonance, cathodoluminescence, capillary ion analysis, and gas chromatography. Geochimica et Cosmochimica Acta, 68, 3741–3759.CrossRefGoogle Scholar
Griffith, W.P. (1969) Raman studies on rock-forming minerals. Part I. Orthosilicates and cyclosilicates. Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1372–1377.CrossRefGoogle Scholar
Gucsik, A. (2009) Cathodoluminescence and its Application in the Planetary Sciences. Springer-Verlag, Heidelberg, Germany, 160pp.CrossRefGoogle Scholar
Hayward, C.L. (1988) Cathodoluminescence of ore and gangue minerals and its application in the minerals industry. Pp. 269—325.in: Modern Approaches to Ore and Environmental Mineralogy (L.J. Cabri and D.J. Vaughan, editors). Mineralogical Association of Canada Short Course Series, 27. Mineralogical Association of Canada, Quebec, Canada.Google Scholar
Hervig, R.L., Kortemeier, W.T. andBurt, D.M. (1987) Ion-microprobe analyses of Li and B in topaz from different environments. American Mineralogist, 72, 392—396.Google Scholar
Kayama, M., Nakano, S. and Nishido, H. (2010) Characteristics of emission centers in alkali feldspar: A new approach by using cathodoluminescence spectral deconvolution. American Mineralogist, 95, 1783–1795.CrossRefGoogle Scholar
Kloprogge, J.T. and Frost, R.L. (2000) Raman micro-scopic study at 300 and 77 K of some pegmatite minerals from the Iveland—Evje area, Aust-Agder, Southern Norway. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 56, 501–513.CrossRefGoogle Scholar
Kostitsyn, Y.A., Kovalenko, V.I. and Yarmolyuk, W (1996) Rubidium-strontium isochron for the Arybulak ongonite stock, eastern Transbaikalia. Transactions (Doklady) of the Russian Academy of Sciences. Earth Science Sections, 345(8), 278–282.Google Scholar
Kovalenko, V.I. and Kovalenko, N.I. (1976) Ongonites (Topaz Bearing Quartz Keratophyre)-Subvolcanic Analogue of Rare Metal Li-F Granite. Nauka Press, Moscow.Google Scholar
Krambrock, K., Ribeiro, L.G.M.., Pinheiro, M.V.B.., Leal, A.S., de Menezes, C.B.M.Â., Spaeth, J.-M. (2007) Color centers in topaz: comparison between neutron and gamma irradiation. Physics and Chemistry of Minerals, 34, 437–444.CrossRefGoogle Scholar
London, D. and Kontak, D.J. (2012) Granitic pegmatites: scientific wonders and economic bonanzas. Elements, 8,257–261.CrossRefGoogle Scholar
MacRae, C.M. and Wilson, N.C. (2008) Luminescence database I — Minerals and materials. Microscopy and Microanalysis, 14, 184—204.CrossRefGoogle ScholarPubMed
Manning, D.A.C.. and Hill, P.I. (1990) The petrogenetic and metallogenic significance of topaz granite from the southwest England orefield. Pp. 246 in: Ore-bearing Granite Systems; Petrogenesis and Mineralizing Processes (H.J. Stein and J.L. Hannah, editors). Geological Society of America, Boulder, Colorado, USA.Google Scholar
Marfunin, A.S. (1979) Spectroscopy, Luminescence and Radiation Centers in Minerals. Springer, Berlin, Heidelberg, New York.CrossRefGoogle Scholar
Marshall, D.J. (1988) Cathodoluminescence of Geological Materials. Unwin Hyman, Boston, USA.Google Scholar
Müller, A., Seltmann, R. and Behr, H.J. (2000) Application of cathodoluminescence to magmatic quartz in a tin granite - case study from the Schellerhau Granite Complex, Eastern Erzgebirge, Germany. Mineralium Deposita, 35, 169—189.Google Scholar
Müller, A., Lennox, P. and Trzebski, R (2002) Cathodoluminescence and micro-structural evidence for crystallisation and deformation processes of granites in the Eastern Lachlan Fold Belt (SE Australia). Contributions to Mineralogy and Petrology, 143, 510–524.CrossRefGoogle Scholar
Northrup, P.A. and Reeder, R.J. (1994) Evidence for the importance of growth-surface structure to trace element incorporation in topaz. American Mineralogist, 79, 1167–1175.Google Scholar
Ottolini, L., Cámara, F. and Bigi, S. (2000) An investigation of matrix effects in the analysis of fluorine in humite-group minerals by EMPA, SIMS, and SREF. American Mineralogist, 85, 89–102.CrossRefGoogle Scholar
Pagel, M., Barbin, V., Blanc, P. and Ohnenstetter, D. (2000) Cathodoluminescence in Geosciences Springer-Verlag, Heidelberg.CrossRefGoogle Scholar
Payette, C. and Martin, R.F. (1990) Melt inclusions in the quartz phenocrysts of rhyolites from Topaz and Keg Mountains, Thomas Range, Utah. Geological Society of America Special Papers, 246, 89—102.Google Scholar
Peretyazhko, I.S. and Savina, E.A. (2010a) Fluid and magmatic processes in the formation of the Ary-Bulak ongonite massif (eastern Transbaikalia). Russian Geology and Geophysics, 51, 1110–1125.CrossRefGoogle Scholar
Peretyazhko, I.S. and Savina, E.A. (2010b) Sinks of liquid immiscibility in ongonitic magma: Evidence from the study of melt and fluid inclusions in rocks of the Ary-Bulak massif (Eastern Transbaikalia). Doklady Earth Sciences, 433, 1077–1082.CrossRefGoogle Scholar
Peretyazhko, I.S., Zagorsky, V.Y., Tsareva, E.A. and Sapozhnikov, A.N. (2007) Immiscibility of calcium fluoride and alumino silicate melts in ongonite from the Ary-Bulak intrusion, Eastern Transbaikal region. Doklady Earth Sciences, 413, 315–320.CrossRefGoogle Scholar
Peretyazhko, I.S., Savina, E.A., Dril', S.I. and Gerasimov, N.S. (2011) Rb-Sr isotope system and Rb-Sr partitioning in the rocks of the Ary-Bulak ongonite massif, formed with the participation of fluoride-silicate magmatic immiscibility. Russian Geology and Geophysics, 52, 1401–1411.CrossRefGoogle Scholar
Perny, B., Eberhardt, P., Ramseyer, K., Mullis, J. and Pankrath, R. (1992) Microdistribution of Al, Li, and Na in alpha-quartz - Possible causes and correlation with short-lived cathodoluminescence. American Mineralogist, 77, 534–544.Google Scholar
Priest, V., Cowan, D.L., Ros, F.K. and Reichl, D.G. (1987) Point defects in topaz crystals. Applied Physics Communications, 7, 86.Google Scholar
Raimbault, L., Cuney, M., Azencott, C., Duthou, J.-L. and Joron, J.L. (1995) Geochemical evidence for a multistage magmatic genesis of Ta-Sn-Li mineralization in the granite at Beauvoir, French Massif Central. Economic Geology, 90, 548–576.CrossRefGoogle Scholar
Raw Materials Supply Group (2014) Critical raw materials for the EU- Report of the Ad-hoc Working Group on defining critical raw materials. Raw Materials Supply Group, European Commission, Enterprise and Industry, 41 pp. [on line http://ec.europa.eu/enterprise/policies/ raw-materials/files/docs/crm-report-on-critical-raw-materials_en.pdf, accessed Dec 2014].Google Scholar
Remond, G., Cesbron, F., Chapoulie, R., Ohnenstetter, D., Rouques-Carmes, C. and Schvoerer, M. (1992) Cathodoluminescence applied to the microcharacteriza-tion of mineral materials: a present status in experimentation and interpretation. Scanning Microscopy, 6, 23—69.Google Scholar
Remond, G., Phillips, R.M. and Roques-Carmes, C. (2000) Importance of instrumental and experimental factors on the interpretation of cathodoluminescence data from wide band gap materials. Pp. 59–126.in: Cathodoluminescence in Geosciences. Springer-Verlag, Heidelberg, Germany.CrossRefGoogle Scholar
Schott, S., Rager, H., Schürmann, K. andTaran, M. (2003) Spectroscopic study of natural gem quality “Imperial” topazes from Ouro Preto, Brazil. European Journal of Mineralogy, 15, 701–706.CrossRefGoogle Scholar
Skvortsova, V., Mironova-Ulmane, N., Trinkler, L. and Chikvaidze, G. (2013) Optical properties of natural topaz. IOP Conference Series: Materials Science and Engineering, 49, 012051.CrossRefGoogle Scholar
Song, Y and Yuan, X. (2009) New method for identification of blue topaz - An application of cathodoluminescence (CL). Journal of Geography and Geology, 1, 13—19.CrossRefGoogle Scholar
Stevens-Kalceff, M.A. (2009) Cathodoluminescence microcharacterization of point defects in α-quartz. Mineralogical Magazine, 73, 585–605.CrossRefGoogle Scholar
Syritso, L.F., Badanina, E.V., Abushkevich, V.S., Volkova, E.V. and Shuklina, E.V. (2012) Volcanoplutonic association of felsic rocks in the rare-metal ore units of Transbaikalia: Geochemistry of rocks and melts, age, and P-T conditions of their crystallization. Petrology, 20, 567–592.CrossRefGoogle Scholar
Taylor, R.P. (1992) Petrological and geochemical characteristics of the Pleasant Ridge zinnwaldite-topaz granite, southern New Brunswick, and comparisons with other topaz-bearing felsic rocks. The Canadian Mineralogist, 30, 895–921.Google Scholar
Thomas, R. (1982) Ergebnisse der thermobarogeochem-ischen Untersuchungen an Flüssigkeitseinschlüssen in Mineralen der postmagmatischen Zinn—Wolfram-Mineralisation des Erzgebirges. Freiberg Forsch H C, 370, 1–85.Google Scholar
Thomas, R. and Davidson, P. (2013) The missing link between granites and granitic pegmatites. Journal of Geosciences, 58, 183–200 CrossRefGoogle Scholar
Thomas, R., Webster, J.D. and Heinrich, W (2000) Melt inclusions in pegmatite quartz: complete miscibility between silicate melts and hydrous fluids at low pressure. Contributions to Mineralogy and Petrology, 139,394–401.CrossRefGoogle Scholar
Thomas, S.-M., Thomas, R., Davidson, P., Reichart, P., Koch-Müller, M. and Dollinger, G. (2008) Application of Raman spectroscopy to quantify trace water concentrations in glasses and garnets. American Mineralogist,93, 1550–1557.CrossRefGoogle Scholar
Thomas, R., Davidson, P., Rhede, D. and Leh, M. (2009) The miarolitic pegmatites from the Konigshain: a contribution to understanding the genesis of pegmatites. Contributions to Mineralogy and Petrology, 157, 505–523.CrossRefGoogle Scholar
U.S. Geological Survey (2011) Mineral Commodity Summaries 2011. U.S. Geological Survey, Reston, Virginia, USA. 198 pp. [on line http://minerals.usgs. gov/minerals/pubs/mcs/201 1/mcs201 1.pdf, accessed Dec 2014].Google Scholar
Vasyukova, O.V., Goemann, K., Kamenetsky, V.S., MacRae, C.M. and Wilson, N.C. (2013) Cathodoluminescence properties of quartz eyes from porphyry-type deposits: Implications for the origin of quartz. American Mineralogist, 98, 98–109.CrossRefGoogle Scholar
Wasim, M., Zafar, W., Tufail, M., Arif, M., Daud, M. and Ahmad, A. (2011) Elemental analysis of topaz from northern areas of Pakistan and assessment of induced radioactivity level after neutron irradiation for color induction. Journal of Radioanalytical & Nuclear Chemistry, 287, 821–826.CrossRefGoogle Scholar
Watt, G.R., Wright, P., Galloway, S. and McLean, C. (1997) Cathodoluminescence and trace element zoning in quartz phenocrysts and xenocrysts. Geochimica et Cosmochimica Acta, 61, 4337—4348.CrossRefGoogle Scholar
Waychunas, G.A. (2014) Luminescence spectroscopy. Pp. 175–217.in: Spectroscopic Methods in Mineralogy and Material Sciences (G.S. Henderson, D.R. Neuville and R.T Downs, editors). Reviews in Mineralogy & Geochemistry, 78. Geological Society of America and the Geochemical Society, Chantilly, Virginia, USA.Google Scholar
Williams, P.M. and Yoffe, A.D. (1969) Monochromatic cathodoluminescence image in the scanning electron microscope. Nature, 221, 952—953.CrossRefGoogle Scholar
Williams-Jones, A.E., Samson, I.M. and Olivo, G.R. (2000) The genesis of hydrothermal fluorite-REE deposits in the Gallinas Mountains, New Mexico. Economic Geology, 95, 327–341.CrossRefGoogle Scholar
Wunder, B. and Marler, B. (1997) Ge-analogues of aluminum silicates; high-pressure synthesis and properties of orthorhombic Al2GeO4(OH)2. European Journal of Mineralogy, 9, 1147–1158.CrossRefGoogle Scholar
Wunder, B., Rubie, D.C., Ross, C.R., Medenbach, O., Seifert, F. and Schreyer, W (1993) Synthesis, stability, and properties of Al2SiO4(OH)2; a fully dehydrated analogue of topaz. American Mineralogist, 78, 285–297.Google Scholar
Yacobi, B.G. and Holt, D.B. (1990) Cathodoluminescence Microscopy of Inorganic Solids. Plenum Press, New York, 292pp.CrossRefGoogle Scholar
Zhang, R.Y., Liou, J.G. and Shu, J.F. (2002) Hydroxyl-rich topaz in high-pressure and ultrahigh-pressure kyanite quartzites, with retrograde woodhouseite, from the Sulu terrane, eastern China. American Mineralogist, 87, 445–453.CrossRefGoogle Scholar
Zhang, J., Lu, T., Wang, M. and Chen, H. (2011) The radioactive decay pattern of blue topaz treated by neutron irradiation. Gems and Gemology, 47, 302–307.CrossRefGoogle Scholar