Hostname: page-component-78c5997874-lj6df Total loading time: 0 Render date: 2024-11-09T03:36:54.118Z Has data issue: false hasContentIssue false

The effect of cooling rate on immiscible silicate liquid microstructure: an example from the Palaeogene dykes of Northeast England

Published online by Cambridge University Press:  06 November 2019

Victoria C. Honour*
Affiliation:
Department of Earth Sciences, University of Cambridge, England, UK
Marian B. Holness
Affiliation:
Department of Earth Sciences, University of Cambridge, England, UK
Michael J. Stock
Affiliation:
Department of Earth Sciences, University of Cambridge, England, UK Department of Geology, Trinity College Dublin, Dublin, Ireland
*
*Author for correspondence: Victoria C. Honour, Email: vch28@cam.ac.uk

Abstract

The migration and accumulation of immiscible silicate liquids may play a significant role in the differentiation of crustal magma bodies and the formation of some economic mineral deposits. However, our understanding of the processes that control the segregation of these liquids is currently limited by the short timescales of petrological experiments. Detailed microstructural investigations of Palaeogene basaltic dykes from Northeast England, coupled with simple 1D thermal models, constrain the effects of cooling rate on the microstructure of unmixed immiscible silicate liquids under natural conditions. The size of unmixed Fe-rich droplets within a continuous silicic phase is related to the cooling rate by a power law, with droplet diameter increasing with decreasing cooling rate, accompanied by an increase in the number of droplets. Fe-rich droplet coarsening is a result of diffusion-controlled growth. The average apparent aspect ratio and grain size of matrix plagioclase crystals indicate that nucleation and growth of these grains probably occurred in a static (or only weakly convecting) fluid dynamical regime.

Type
Article
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Martin Lee

References

Ágústsdóttir, T., Woods, J., Greenfield, T., Green, R.G., White, R.S., Winder, T., Brandsdóttir, B., Steinthórsson, S. and Soosalu, H. (2016) Strike-slip faulting during the 2014 Bárðarbunga-Holuhraun dike intrusion, central Iceland. Geophysical Research Letters, 43, 14951503.CrossRefGoogle Scholar
Applegarth, L.J., Tuffen, H., James, M.R., Pinkerton, H. and Cashman, K.V. (2013) Direct observations of degassing-induced crystallization in basalts. Geology, 41, 243246.CrossRefGoogle Scholar
Ayele, A., Keir, D., Ebinger, C., Wright, T.J., Stuart, G.W., Buck, W.R., Jacques, E., Ogubazghi, G. and Sholan, J. (2009) September 2005 mega-dike emplacement in the Manda-Harraro nascent oceanic rift (Afar depression). Geophysical Research Letters, 36, L20306.CrossRefGoogle Scholar
Cashman, K.V. (1993) Relationship between plagioclase crystallization and cooling rate in basaltic melts. Contributions to Mineralogy and Petrology, 113, 126142.CrossRefGoogle Scholar
Cawthorn, R.G. and Walraven, F. (1998) Emplacement and Crystallization Time for the Bushveld Complex. Journal of Petrology, 39, 16691687.CrossRefGoogle Scholar
Chambers, L.M. and Pringle, M.S. (2001) Age and duration of activity at the Isle of Mull Tertiary igneous centre, Scotland, and confirmation of the existence of subchrons during Anomaly 26r. Earth and Planetary Science Letters, 193, 333345.CrossRefGoogle Scholar
Charlier, B. and Grove, T.L. (2012) Experiments on liquid immiscibility along tholeiitic liquid lines of descent. Contributions to Mineralogy and Petrology, 164, 2744.CrossRefGoogle Scholar
Farr, R.S., Honour, V.C. and Holness, M.B. (2017) Mean grain diameters from thin sections: matching the average to the problem. Mineralogical Magazine, 81, 515530.CrossRefGoogle Scholar
Fischer, L.A., Wang, M., Charlier, B., Namur, O., Roberts, R.J., Veksler, I.V., Cawthorn, R.G. and Holtz, F. (2016) Immiscible iron- and silica-rich liquids in the Upper Zone of the Bushveld Complex. Earth and Planetary Science Letters, 443, 108117.CrossRefGoogle Scholar
Frietsch, R. (1978) On the magmatic origin of iron ores of the Kiruna type. Economic Geology, 73, 478485.CrossRefGoogle Scholar
Giordano, D., Nichols, A.R. and Dingwell, D.B. (2005) Glass transition temperatures of natural hydrous melts: a relationship with shear viscosity and implications for the welding process. Journal of Volcanology and Geothermal Research, 142, 105118.CrossRefGoogle Scholar
Harker, A. and Clough, C.T. (1904) The Tertiary Igneous Rocks of Skye. J. Hedderwick & Sons, Glasgow.CrossRefGoogle Scholar
Hartlieb, P., Toifl, M., Kuchar, F., Meisels, R. and Antretter, T. (2016) Thermo-physical properties of selected hard rocks and their relation to microwave-assisted comminution. Minerals Engineering, 91, 3441.CrossRefGoogle Scholar
Helz, R.T., Clague, D.A., Sisson, T.W. and Thornber, C.R. (2014) Petrologic insights into basaltic volcanism at historically active Hawaiian volcanoes. Pp. 237292 in: Characteristics of Hawaiian Volcanoes (Poland, M.P., Takahashi, T.J. and Landowski, C.M., editors), USGS Professional Paper 1801.Google Scholar
Heslop, M. and Smythe, J. (1910) On the dyke at Crookdene (Northumberland) and its relations to the Collywell, Tynemouth, and Morpeth Dykes. Quarterly Journal of the Geological Society, 66, 118.CrossRefGoogle Scholar
Holmes, A. and Harwood, H. (1929) The tholeiite dikes of the north of England. Mineralogical Magazine, 22, 152.CrossRefGoogle Scholar
Holness, M.B. (2014) The effect of crystallization time on plagioclase grain shape in dolerites. Contributions to Mineralogy and Petrology, 168, 1076.CrossRefGoogle Scholar
Holness, M.B. and Sawyer, E.W. (2008) On the pseudomorphing of melt-filled pores during the crystallization of migmatites. Journal of Petrology, 49, 13431363.CrossRefGoogle Scholar
Holness, M.B., Stripp, G., Humphreys, M., Veksler, I.V., Nielsen, T.F. and Tegner, C. (2011) Silicate liquid immiscibility within the crystal mush: late-stage magmatic microstructures in the Skaergaard intrusion, East Greenland. Journal of Petrology, 52, 175222.CrossRefGoogle Scholar
Holness, M.B., Richardson, C. and Helz, R.T. (2012) Disequilibrium dihedral angles in dolerite sills: A new proxy for cooling rate. Geology, 40, 795798.CrossRefGoogle Scholar
Holness, M.B., Neufeld, J.A., Gilbert, A.J. and Macdonald, R. (2017) Orientation of tabular mafic intrusions controls convective vigour and crystallization style. Journal of Petrology, 58, 20352053.CrossRefGoogle Scholar
Honour, V.C., Holness, M.B.Charlier, B., Piazolo, S.C., Namur, O., Prosa, T.J., Martin, I., Helz, R.T., Maclennan, J. and Jean, M.M. (2019 a). Compositional boundary layers trigger liquid unmixing in a basaltic crystal mush. Nature Communications, 10, 4821.CrossRefGoogle Scholar
Honour, V.C., Holness, M.B., Partridge, J.L. and Charlier, B. (2019 b) Microstructural evolution of silicate immiscible liquids in ferrobasalts. Contributions to Mineralogy and Petrology, 174, 77.CrossRefGoogle Scholar
Hort, M. (1998) Abrupt change in magma liquidus temperature because of volatile loss or magma mixing: effects on nucleation, crystal growth and thermal history of the magma. Journal of Petrology, 39, 10631076.CrossRefGoogle Scholar
Humphreys, M.C. (2011) Silicate liquid immiscibility within the crystal mush: evidence from Ti in plagioclase from the Skaergaard intrusion. Journal of Petrology, 52, 147174.CrossRefGoogle Scholar
Jakobsen, J.K., Veksler, I.V., Tegner, C. and Brooks, C.K. (2011) Crystallization of the Skaergaard intrusion from an emulsion of immiscible iron-and silica-rich liquids: evidence from melt inclusions in plagioclase. Journal of Petrology, 52, 345373.CrossRefGoogle Scholar
James, G., Witten, D., Hastie, T. and Tibshirani, R. (2013) An Introduction to Statistical Learning. Springer, New York.CrossRefGoogle Scholar
Jolly, R.J.H. and Sanderson, D.J. (1995) Variation in the form and distribution of dykes in the Mull swarm, Scotland. Journal of Structural Geology, 17, 15431557.CrossRefGoogle Scholar
Jones, J.M. (1967) The Geology of the coast section from Tynemouth to Seaton Sluice. Transactions of the Natural History Society of Northumbria, 16, 153192.Google Scholar
Kerr, A.C., Kent, R.W., Thomson, B.A., Seedhouse, J.K. and Donaldson, C.H. (1999) Geochemical evolution of the Tertiary Mull volcano, Western Scotland. Journal of Petrology, 40, 873908.CrossRefGoogle Scholar
Kirkpatrick, R.J. (1977) Nucleation and growth of plagioclase, Makaopuhi and Alae lava lakes, Kilauea Volcano, Hawaii. Geological Society of America Bulletin, 88, 7884.2.0.CO;2>CrossRefGoogle Scholar
Kohn, S. (2000) The dissolution mechanisms of water in silicate melts; a synthesis of recent data. Mineralogical Magazine, 64, 389408.CrossRefGoogle Scholar
Land, D.H. (1974) Geology of the Tynemouth District. HM Stationery Office, London.Google Scholar
Lester, G., Clark, A., Kyser, T. and Naslund, H. (2013) Experiments on liquid immiscibility in silicate melts with H2O, P, S, F and Cl: implications for natural magmas. Contributions to Mineralogy and Petrology, 166, 329349.CrossRefGoogle Scholar
Levich, V.G. (1962) Motion and diffusion in thin liquid films. Pp. 689700 in: Physicochemical Hydrodynamics (Amundson, N.R., editors). Prentice-Hall, Englewood Cliffs.Google Scholar
Macdonald, R., Baginski, B., Upton, B., Pinkerton, H., MacInnes, D. and MacGillivray, J. (2010) The Mull Palaeogene dyke swarm: Insights into the evolution of the Mull igneous centre and dyke-emplacement mechanisms. Mineralogical Magazine, 74, 601622.CrossRefGoogle Scholar
Martin, B. and Kushiro, I. (1991) Immiscibility synthesis as an indication of cooling rates of basalts. Journal of Volcanology and Geothermal Research, 45, 289310.CrossRefGoogle Scholar
Martin, D., Griffiths, R.W. and Campbell, I.H. (1987) Compositional and thermal convection in magma chambers. Contributions to Mineralogy and Petrology, 96, 465475.CrossRefGoogle Scholar
McNaught, A.D. (1997) Compendium of Chemical Terminology. Blackwell Science, Oxford.Google Scholar
Mitchell, J.G., Rands, P.N. and Ineson, P.R. (1989) Perturbation of the K-Ar age system in the Cleveland dyke, UK: evidence of an Early Eocene age for barite mineralisation in the Magnesian Limestone of County Durham. Chemical Geology, 79, 4964.Google Scholar
Ostwald, W. (1897) Studien über die Bildung und Umwandlung fester Körper. Zeitschrift für Physikalische Chemie, 22, 289330.Google Scholar
Peltier, A., Ferrazzini, V., Staudacher, T. and Bachèlery, P. (2005) Imaging the dynamics of dyke propagation prior to the 2000–2003 flank eruptions at Piton de La Fournaise, Reunion Island. Geophysical Research Letters, 32, L22302.CrossRefGoogle Scholar
Philpotts, A.R. (1978) Textural evidence for liquid immiscibility in tholeiites. Mineral Magazine, 42, 417425.CrossRefGoogle Scholar
Philpotts, A.R. (1979) Silicate liquid immiscibility in tholeiitic basalts. Journal of Petrology, 20, 99118.CrossRefGoogle Scholar
Philpotts, A.R. (1981) A model for the generation of massif-type anorthosites. The Canadian Mineralogist, 19, 233253.Google Scholar
Philpotts, A.R. (1982) Compositions of immiscible liquids in volcanic rocks. Contributions to Mineralogy and Petrology, 80, 201218.CrossRefGoogle Scholar
Pupier, E., Duchene, S. and Toplis, M.J. (2008) Experimental quantification of plagioclase crystal size distribution during cooling of a basaltic liquid. Contributions to Mineralogy and Petrology, 155, 555570.CrossRefGoogle Scholar
Putnis, A. and Mauthe, G. (2001) The effect of pore size on cementation in porous rocks. Geofluids, 1, 3741.CrossRefGoogle Scholar
Roedder, E. (1951) Low Temperature liquid immiscibility in the system K2O-FeO-Al2O3-SiO2. American Mineralogist, 36, 282286.Google Scholar
Ryan, M.P. and Sammis, C.G. (1981) The glass transition in basalt. Journal of Geophysical Research: Solid Earth, 86, 95199535.CrossRefGoogle Scholar
Saunders, A., Fitton, J., Kerr, A., Norry, M. and Kent, R. (1997) The north Atlantic igneous province. Large igneous provinces: Continental, oceanic, and planetary flood volcanism, 100, 4593.Google Scholar
Schiavi, F., Walte, N. and Keppler, H. (2009) First in situ observation of crystallization processes in a basaltic-andesitic melt with the moissanite cell. Geology, 37, 963966.CrossRefGoogle Scholar
Schneider, C.A., Rasband, W.S. and Eliceiri, K.W. (2012) NIH Image to ImageJ: 25 years of image analysis. Nature methods, 9, 671675.CrossRefGoogle ScholarPubMed
Sloan, T. (1971) The Structure of the Mull Tertiary Dyke Swarm. PhD thesis, University of London.Google Scholar
Teall, J.J.H. (1884) Petrological notes on some North-of-England dykes. Quarterly Journal of the Geological Society, 40, 209247.CrossRefGoogle Scholar
Teall, J.J.H. (1889) On the amygdaloids of the tynemouth dyke. Geological Magazine, 6, 481483.CrossRefGoogle Scholar
Underhill, J.R. (2009) Role of intrusion-induced salt mobility in controlling the formation of the enigmatic ‘Silverpit Crater’, UK Southern North Sea. Petroleum Geoscience, 15, 197216.CrossRefGoogle Scholar
Veksler, I.V., Dorfman, A.M., Danyushevsky, L.V., Jakobsen, J.K. and Dingwell, D.B. (2006) Immiscible silicate liquid partition coefficients: implications for crystal-melt element partitioning and basalt petrogenesis. Contributions to Mineralogy and Petrology, 152, 685702.CrossRefGoogle Scholar
Veksler, I.V., Dorfman, A.M., Borisov, A.A., Wirth, R. and Dingwell, D.B. (2007) Liquid immiscibility and the evolution of basaltic magma. Journal of Petrology, 48, 21872210.CrossRefGoogle Scholar
Veksler, I.V., Dorfman, A.M., Rhede, D., Wirth, R., Borisov, A.A. and Dingwell, D.B. (2008) Liquid unmixing kinetics and the extent of immiscibility in the system K2O–CaO–FeO–Al2O3–SiO2. Chemical Geology, 256, 119130.CrossRefGoogle Scholar
Wall, M., Cartwright, J., Davies, R. and McGrandle, A. (2010) 3D seismic imaging of a Tertiary Dyke Swarm in the Southern North Sea, UK. Basin Research, 22, 181194.CrossRefGoogle Scholar
Wright, T.J., Ebinger, C., Biggs, J., Ayele, A., Yirgu, G., Keir, D. and Stork, A. (2006) Magma-maintained rift segmentation at continental rupture in the 2005 Afar dyking episode. Nature, 442, 291.CrossRefGoogle ScholarPubMed
Yao, W., Maris, H., Pennington, P. and Seidel, G. (2005) Coalescence of viscous liquid drops. Physical Review E, 71, 016309.CrossRefGoogle ScholarPubMed
Yoder, H., Stewart, D. and Smith, J. (1957) Feldspars. Carnegie Institution Washington Yearbook, 56, 206214.Google Scholar
Zellmer, G.F., Sakamoto, N., Hwang, S.-L., Matsuda, N., Iizuka, Y., Moebis, A. and Yurimoto, H. (2016) Inferring the effects of compositional boundary layers on crystal nucleation, growth textures, and mineral chemistry in natural volcanic tephras through submicron-resolution imaging. Frontiers in Earth Science, 4, 88.CrossRefGoogle Scholar
Supplementary material: File

Honour et al. supplementary material

Honour et al. supplementary material 1

Download Honour et al. supplementary material(File)
File 19.4 KB
Supplementary material: Image

Honour et al. supplementary material

Honour et al. supplementary material 2

Download Honour et al. supplementary material(Image)
Image 225.6 KB