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Titanium in quartz as a record of ultrahigh-temperature metamorphism: the granulites of Karur, southern India

Published online by Cambridge University Press:  05 July 2018

K. Sato  and
M. Santosh
K. Sato*
Affiliation:
Research Center for the evolving Earth and Planets, also at Department of Earth andPlanetary Sciences, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama 2-12-1, Meguro-ku, Tokyo 152-8551, Japan
M. Santosh
Affiliation:
Department of Natural Environmental Science, Faculty of Science, Kochi University, Akebono-cho 2-5-1, Kochi 780-8520, Japan
*
*E-mail: ksato@geo.titech.ac.jp
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Abstract

The occurrence is reported of spectacular oriented needles of rutile within quartz veins and pods in granulite-facies rocks that have undergone partial melting under ultrahigh-temperature (UHT) conditions in the Karur region in southern India. Laser Raman spectroscopy and electron microprobe analysis confirm that (1) the mineral inclusions within quartz are pure rutiles, and (2) a secondcategory of quartz contains pure hematite inclusions. The rutile never coexists with the hematite inside the same quartz specimens. Fluidinclusions in the quartz are characterized as a CO2 + H2O mixture. Application of two geothermometric calibrations utilizing Ti in quartz yields minimum estimates of ~1190ºC, suggesting the formation of the rutile-quartz under UHT metamorphic condition. It is proposed that such Ti-rich quartz segregations couldbe another indicator for extreme crustal metamorphism at very high temperatures.

Keywords

rutile-quartzfluid inclusionshematiteLaser Raman spectroscopyultrahigh-temperature (UHT) metamorphismsouthern India.
Type
Research Article
Information
Mineralogical Magazine , Volume 71 , Issue 2 , April 2007 , pp. 143 - 154
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2007

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References

Aranovich, L.Y. and Berman, R.G. (1996) Optimized standard state and solution properties of minerals II. Comparisons, predictions, and applications. Contributions to Mineralogy and Petrology, 126, 25–37.CrossRefGoogle Scholar
Bartlett, J.M., Dougherty-Page, J.S., Harris, N.B.W., Hawkesworth, C.J. and Santosh, M. (1998) The application of single zircon evaporation andmod el Ndages to the interpretation of polymetamorphic terrains: an example from the Proterozoic mobile belt of south India. Contributions to Mineralogy and Petrology, 131, 181–195.CrossRefGoogle Scholar
Cherniak, D.J., Watson, E.B. and Wark, D.A. (2007) Ti diffusion in quartz. Chemical Geology, 236, 65–74.CrossRefGoogle Scholar
Chetty, T.R.K. and Bhaskar Rao, Y.J. (2006) The Cauvery Shear Zone, Southern Granulite Terrain, India: A crustal-scale flower structure. Gondwana Research, 10, 77–85.Google Scholar
Collins, A.S. and Pisarevsky, S.A. (2005) Amalgamating eastern Gondwana: The evolution of the Circum- Indian Orogens. Earth-Science Reviews, 71, 229–270.CrossRefGoogle Scholar
Dallwitz, W.B. (1968) Co-existing sapphirine and quartz in granulite from Enderby Land, Antarctica. Nature, 219, 476–477.CrossRefGoogle Scholar
Das, K., Dasgupta, S. and Miura, H. (2003) An experimentally constrainedpetrogenetic gridin the silica-undersaturated portion of the system KFMASH at high temperatures andpr essures. Journal of Petrology, 44, 1055–1075.CrossRefGoogle Scholar
Drury, S.A., Harris, N.B.W., Holt, R.W., Reeves-Smith, G.J. and Wightman, R.T. (1984) Precambrian tectonics andcrustal evolution in south India. Journal of Geology, 92, 3–20.CrossRefGoogle Scholar
Elkins, L.T. and Grove, T.L. (1990) Ternary feldspar experiments and thermodynamic models. American Mineralogist, 75, 544–559.Google Scholar
Ellis, D.J., Sheraton, J.W., England, R.N. and Dallwitz, W.B. (1980) Osumilite-sapphirine-quartz granulites from Enderby Land Antarctica – Mineral assemblages andreactions. Contributions to Mineralogy and Petrology, 72, 123–143.CrossRefGoogle Scholar
Friedman, G.M. (1953) The spinel-silica reaction succession: a study of incompatible mineral phases. Journal of Geology, 62, 366–374.Google Scholar
Fuhrman, M.L. and Lind sley, D.H. (1988) Ternary feldspar modeling and thermometry. American Mineralogist, 73, 201–215.Google Scholar
Grew, E.S. (1980) Sapphirine quartz association from Archean rocks in Enderby Land, Antarctica. American Mineralogist, 65, 821–836.Google Scholar
Grew, E.S. (1982) Osumilite in the sapphirine–quartz terrane of Enderby Land, Antarctica: implications for osumilite petrogenesis in the granulite facies. American Mineralogist, 67, 762–787.Google Scholar
Grew, E.S. (1984) Note on sapphirine and sillimanite + orthopyroxene from Panrimalai, Madurai district, Tamil Nadu. Journal of Geological Society of India, 25, 116–119.Google Scholar
Harley, S.L. (1998) On the occurrence and characterization of ultrahigh-temperature crustal metamorphism. Pp. 81–107 in: What Drives Metamorphism and Metamorphic Reactions? (Treloar, P.J. and O’Brian, P.J., editors). Special Publication 138. Geological Society, London.Google Scholar
Harley, S.L. (2004) Extending our understand ing of ultrahigh temperature crustal metamorphism. Journal of Mineralogical and Petrological Sciences, 99, 140–158.CrossRefGoogle Scholar
Harley, S.L. and Motoyoshi, Y. (2000) Alumina-zoning in orthopyroxene in a sapphirine quartzite: evidence for >1120°C ultrahigh temperature metamorphism in the Napier Complex, Enderby Land, Antarctica. Contributions to Mineralogy and Petrology, 138, 293–307.CrossRefGoogle Scholar
Harris, N.B.W., Santosh, M. and Taylor, P.N. (1994) Crustal evolution in south India: constrains from Nd isotopes. Journal of Geology, 102, 139–150.CrossRefGoogle Scholar
Hensen, B.J. and Green, D.H. (1971) Experimental study of the stability of cordierite and garnet in pelitic compositions at high pressures andtemperatures. I: Compositions with excess alumino-silicate. Contributions to Mineralogy and Petrology, 33, 309–330.CrossRefGoogle Scholar
Hensen, B.J. and Green, D.H. (1972) Experimental study of the stability of cordierite and garnet in pelitic compositions at high pressures andtemperatures. II: Compositions without excess aluminosilicate. Contributions to Mineralogy and Petrology, 35, 331–354.CrossRefGoogle Scholar
Hensen, B.J. and Green, D.H. (1973) Experimental study of the stability of cordierite and garnet in pelitic compositions at high pressures andtemperatures. III: Synthesis of experimental data and geological applications. Contributions to Mineralogy and Petrology, 38, 151–166.CrossRefGoogle Scholar
Hensen, B.J. and Harley, S.L. (1990) Graphical analysis of P-T-X relations in granulite facies metapelites. Pp. 19–56 in: High-temperature Metamorphism and Crustal Anatexis (Ashworth, J.R. and Brown, M., editors). Unwin Hyman, London.Google Scholar
Hokada, T. (2001) Feldspar thermometry in ultrahightemperature metamorphic rocks: Evidence of crustal metamorphism attaining ∼1100°C in the Archean Napier Complex, East Antarctica. American Mineralogist, 86, 932–938.CrossRefGoogle Scholar
Hokada, T. and Suzuki, S. (2006) Feldspar in felsic orthogneiss as indicator for UHT crustal processes. Journal of Mineralogical and Petrological Sciences, 101, 260–264.CrossRefGoogle Scholar
Hollis, J.A. and Harley, S.L. (2003) Alumina solubility in orthopyroxene coexisting with sapphirine and quartz. Contributions to Mineralogy and Petrology, 144, 473–483.CrossRefGoogle Scholar
Jayananda, M., Moyen, J.-F., Martin, H., Peucat, J.-J., Auvray, B. and Mahabaleswar, B. (2000) Late Archaean (2550–2520 Ma) juvenile magmatism in the Eastern Dharwar craton, southern India: constraints from geochronology, Nd-Sr isotopes and whole rock geochemistry. Precambrian Research, 99, 225–254.CrossRefGoogle Scholar
Kelsey, D.E. (in press) On ultrahigh temperature crustal metamorphism. Gondwana Research.Google Scholar
Kelsey, D.E., White, R.W. and Powell, R. (2005) Calculatedphase equilibria in K2O-FeO-MgOAl2O3- SiO2-H2O for silica-undersaturated sapphirine- bearing mineral assemblages. Journal of Metamorphic Geology, 23, 217–239.CrossRefGoogle Scholar
Kawasaki, T. and Osanai, Y. (in press) Empirical thermometer of TiO2 in quartz for ultrahigh-temperature granulites of East Antarctica. in: Geodynamics evolution of East Antarctica: A key to the East-West Gondwana connection (Satish-Kumar, M., Motoyoshi, Y., Osanai, Y., Hiroi, Y. and Shiraishi, K., editors). Special Publication, Geological Society of London.Google Scholar
Kretz, R. (1983) Symbols for rock-forming minerals. American Mineralogist, 68, 277–279.Google Scholar
Kroll, H., Evangelakakis, C. and Voll, G. (1993) Twofeldspar geothermometry: a review and revision for slowly cooledrocks. Contributions to Mineralogy and Petrology, 114, 510–518.CrossRefGoogle Scholar
Lindsley, D.H. and Nekvasil, H. (1989) A Ternary Feldspar Model for all Reasons. EOS Transactions of the American Geophysical Union, 70, 506 pp.Google Scholar
Miyamoto, T., Yoshimura, Y., Sato, K., Motoyoshi, Y., Dunkley, D.J. and Carson, C.J. (2004) Occurrences of metamorphosedultramafic rock and associated rocks in HowardHills, Enderby Land, East Antarctica: Evidence of partial melting from geochemical andisotopic characteristics. Polar Geoscience, 17, 88–111.Google Scholar
Morimoto, T., Santosh, M., Tsunogae, T. and Yoshimura, Y. (2004) Spinel + quartz association from the Kerala khondalites, southern India: evidence for ultrahigh temperature metamorphism. Journal of Mineralogical and Petrological Sciences, 99, 257–278.CrossRefGoogle Scholar
Motoyoshi, Y. and Hensen, B.J. (2001) F-rich phlogopite stability in ultra-high-temperature metapelites from the Napier Complex, East Antarctica. American Mineralogist, 86, 1404–1413.CrossRefGoogle Scholar
Peucat, J.J., Mahabaleswar, B. and Jayananda, M. (1993) Age of younger tonalitic magmatism and granulitic metamorphism in the South India transition zone (Krishnagiri area); comparison with older Peninsular gneisses from the Gorur-Hassan area. Journal of Metamorphic Geology, 11, 879–888.CrossRefGoogle Scholar
Raith, M., Karmakar, S. and Brown, M. (1997) Ultra high-temperature metamorphism andmult istage decompressional evolution of sapphirine granulites from the Palni hill ranges, southern India. Journal of Metamorphic Geology, 15, 379–399.CrossRefGoogle Scholar
Sajeev, K., Osanai, Y. and Santosh, M. (2004) Ultrahigh-temperature metamorphism followedby two-stage decompression of garnet-orthopyroxenesillimanite granulites from Ganguvarpatti, Madurai block, southern India. Contributions to Mineralogy and Petrology, 148, 29–46.CrossRefGoogle Scholar
Sandiford, M. and Powell, R. (1986) Pyroxene exsolution in granulites from Fyfe Hills, Enderby Land, Antarctica: evidence for 1000°C metamorphic temperatures in Archaean continental crust. American Mineralogist, 71, 946–954.Google Scholar
Santosh, M. and Collins, A.S. (2003) Gemstone mineralization in the Palghat–Cauvery Shear Zone Systems (Karur–Kangayam Belt), southern India. Gondwana Research, 6, 911–918.CrossRefGoogle Scholar
Santosh, M. and Sajeev, K. (2006) Anticlockwise evolution of ultrahigh-temperature granulites within continental collision zone in southern India. Lithos, 92, 447–464.CrossRefGoogle Scholar
Santosh, M., Tsunogae, T. and Koshimoto, S. (2004) First report of sapphirine-bearing rocks from the Palghat–Cauvery Shear Zone System, southern India. Gondwana Research, 7, 620–626.CrossRefGoogle Scholar
Santosh, M., Morimoto, T. and Tsutsumi, Y. (2006a) Geochronology of the khondalite belt of Trivandrum Block, southern India: electron probe ages and implications for Gondwana tectonics. Gondwana Research, 9, 261–278.CrossRefGoogle Scholar
Santosh, M., Collins, A.S., Tamashiro, I., Koshimoto, S., Tsutsumi, Y. and Yokoyama, K. (2006b) The timing of ultrahigh-temperature metamorphism in southern India: U–Th–Pb electron microprobe ages from zircon andmonazite in sapphirine-bearing granulites. Gondwana Research, 10, 128–155.CrossRefGoogle Scholar
Santosh, M., Tsunogae, T., Li, J.H. and Liu, S.J. (2007) Discovery of sapphirine-bearing Mg–Al granulites in the North China Craton: implications for Paleoproterozoic ultrahigh temperature metamorphism. Gondwana Research, 11, 263–285.CrossRefGoogle Scholar
Sato, K., Miyamoto, T. and Kawasaki, T. (2004) Experimental constraints of metamorphic pressure andtemperature, andphase relations of a phlogopitebearing orthopyroxene granulite from HowardHills, Napier Complex, East Antarctica. Journal of Mineralogical and Petrological Sciences, 99, 191–201.CrossRefGoogle Scholar
Shimpo, M., Tsunogae, T. and Santosh, M. (2006) First report of garnet–corundum rocks from southern India: implications for prograde high-pressure (eclogite-facies?) metamorphism. Earth and Planetary Science Letters, 242, 111–129.CrossRefGoogle Scholar
Tateishi, K., Tsunogae, T., Santosh, M. and Janardhan, A.S. (2004) First report of sapphirine + quartz assemblage from southern India: implications for ultrahigh-temperature metamorphism. Gondwana Research, 7, 899–912.CrossRefGoogle Scholar
Tsunogae, T. and Santosh, M. (2006) Spinel-sapphirinequartz bearing composite inclusion within garnet from an ultrahigh-temperature pelitic granulite: Implications for metamorphic history and P–T path. Lithos, 92, 524–536.CrossRefGoogle Scholar
Tsunogae, T., Santosh, M., Osanai, Y., Owada, M., Toyoshima, T. and Hokada, T. (2002) Very highdensity carbonic fluid inclusions in sapphirinebearing granulites from Tonagh Islandin the Archean Napier Complex, East Antarctica: implications for CO2 infiltration during ultrahigh-temperature (T>1100°C) metamorphism. Contributions to Mineralogy and Petrology, 143, 279–299.CrossRefGoogle Scholar
Tsunogae, T., Osanai, Y., Owada, M., Toyoshima, T., Hokada, T. and Crowe, W.A. (2003) High fluorine pargasites in ultrahigh temperature granulites from Tonagh Islandin the Archean Napier Complex, East Antarctica. Lithos, 70, 21–38.CrossRefGoogle Scholar
Wark, D.A. and Watson, E.B. (2006) TitaniQ: a titanium-in-quartz geothermometer. Contributions to Mineralogy and Petrology, 152, 743–754.CrossRefGoogle Scholar
Yoshimura, Y., Motoyoshi, Y., Grew, E.S., Miyamoto, T., Carson, C.J. and Dunkley, D.J. (2000) Ultrahightemperature metamorphic rocks from HowardHills in the Napier Complex, East Antarctica. Polar Geoscience, 13, 60–85.Google Scholar