Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-23T07:42:03.660Z Has data issue: false hasContentIssue false
  • English
  • Français

An Investigation into Electric Field-Modulated Photoluminescence of Perovskite solar cells

Published online by Cambridge University Press:  10 August 2017

Zhihua Xu
Zhihua Xu*
Affiliation:
Department of Chemical Engineering, University of Minnesota Duluth, Duluth, MN 55812, U.S.A.
*
*(Email: xuz@d.umn.edu)
Get access

Abstract

Electric field-modulated photoluminescence (PL) of perovskite solar cells is investigated to gain deeper insight about the role of the mobile ions in organometal halide perovskites. The PL intensity of perovskite solar cells show significant dependence on the polarity of the external electric field and the voltage scanning direction. This phenomenon is discussed in the framework of an ion migration mechanism, which has been widely accounted for the current density-voltage (J-V) hysteresis in perovskite solar cells. The result suggests that the mobile ions not only change the internal electric field of perovskite solar cells, but also have an effect on the recombination of photogenerated charge carriers.

Keywords

photovoltaicphotoemissionthin film
Type
Articles
Information
MRS Advances , Volume 2 , Issue 53: Energy Storage and Conversion , 2017 , pp. 3099 - 3104
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Kojima, A., Teshima, K., Shirai, Y. and Miyasaka, T., Journal of the American Chemical Society 131 (17), 6050-+ (2009).CrossRefGoogle Scholar
Im, J. H., Lee, C. R., Lee, J. W., Park, S. W. and Park, N. G., Nanoscale 3 (10), 4088–4093 (2011).CrossRefGoogle Scholar
Lee, M. M., Teuscher, J., Miyasaka, T., Murakami, T. N. and Snaith, H. J., Science 338 (6107), 643-647 (2012).CrossRefGoogle Scholar
Liu, M. Z., Johnston, M. B. and Snaith, H. J., Nature 501 (7467), 395-+ (2013).Google Scholar
Burschka, J., Pellet, N., Moon, S. J., Humphry-Baker, R., Gao, P., Nazeeruddin, M. K. and Gratzel, M., Nature 499 (7458), 316-+ (2013).CrossRefGoogle Scholar
Snaith, H. J., Abate, A., Ball, J. M., Eperon, G. E., Leijtens, T., Noel, N. K., Stranks, S. D., Wang, J. T. W., Wojciechowski, K. and Zhang, W., Journal of Physical Chemistry Letters 5 (9), 1511–1515 (2014).CrossRefGoogle Scholar
Xiao, Z. G., Yuan, Y. B., Shao, Y. C., Wang, Q., Dong, Q. F., Bi, C., Sharma, P., Gruverman, A. and Huang, J. S., Nature Materials 14 (2), 193–198 (2015).CrossRefGoogle Scholar
Meloni, S., Moehl, T., Tress, W., Franckevicius, M., Saliba, M., Lee, Y. H., Gao, P., Nazeeruddin, M. K., Zakeeruddin, S. M., Rothlisberger, U. and Graetzel, M., Nature Communications 7, 9 (2016).CrossRefGoogle Scholar
Li, C., Tscheuschner, S., Paulus, F., Hopkinson, P. E., Kiessling, J., Kohler, A., Vaynzof, Y. and Huettner, S., Advanced Materials 28 (12), 2446–2454 (2016).CrossRefGoogle Scholar
Tress, W., Marinova, N., Moehl, T., Zakeeruddin, S. M., Nazeeruddin, M. K. and Gratzel, M., Energy & Environmental Science 8 (3), 995–1004 (2015).CrossRefGoogle Scholar
Wu, Y. L., Shen, H. P., Walter, D., Jacobs, D., Duong, T., Peng, J., Jiang, L. C., Cheng, Y. B. and Weber, K., Advanced Functional Materials 26 (37), 6807–6813 (2016).CrossRefGoogle Scholar
Dequilettes, D. W., Zhang, W., Burlakov, V. M., Graham, D. J., Leijtens, T., Osherov, A., Bulovic, V., Snaith, H. J., Ginger, D. S. and Stranks, S. D., Nature Communications 7, 9 (2016).CrossRefGoogle Scholar
Leijtens, T., Kandada, A. R. S., Eperon, G. E., Grancini, G., D’Innocenzo, V., Ball, J. M., Stranks, S. D., Snaith, H. J. and Petrozza, A., Journal of the American Chemical Society 137 (49), 15451–15459 (2015).CrossRefGoogle Scholar
Jacobs, D. L., Scarpulla, M. A., Wang, C., Bunes, B. R. and Zang, L., Journal of Physical Chemistry C 120 (15), 7893–7902 (2016).CrossRefGoogle Scholar
Deng, X. F., Wen, X. M., Lau, C. F. J., Young, T., Yun, J., Green, M. A., Huang, S. J. and Ho-Baillie, A. W. Y., Journal of Materials Chemistry C 4 (38), 9060–9068 (2016).CrossRefGoogle Scholar
Qiu, C. and Grey, J. K., Journal of Physical Chemistry Letters 6 (22), 4560–4565 (2015).CrossRefGoogle Scholar
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S. and Il Seol, S., Nature Materials 13 (9), 897–903 (2014).CrossRefGoogle Scholar
Beckers, I. E., Fiedeler, U., Siebentritt, S. and Lux-Steiner, M. C., Thin Solid Films 431, 205–209 (2003).CrossRefGoogle Scholar
Beckers, I. E., Fiedeler, U., Siebentritt, S. and Lux-Steiner, M. C., Journal of Physics and Chemistry of Solids 64 (9-10), 2031–2035 (2003).CrossRefGoogle Scholar