Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-23T01:33:32.599Z Has data issue: false hasContentIssue false
  • English
  • Français

Remediation of Wastewater from Chlorpyrifos Pesticide by Nano-Gold Photocatalyst

Published online by Cambridge University Press:  01 June 2020

Puja Goel  and
Manju Arora
Puja Goel*
Affiliation:
Physics Department, College of Basic Sciences and Humanities, G.B. Pant University of Agriculture and Technology, Pantnagar, India.
Manju Arora
Affiliation:
CSIR- National Physical Laboratory, Dr. K.S. Krishnan Marg, New Delhi, India.
*
Corresponding Author: Puja Goel, e-mail:pujagoel@gmail.com
Get access

Abstract

Successful disintegration of Chlorpyrifos pesticide by nearly monodisperse nano-gold photcatalyst (∼10 nm) for remediation of wastewater has been reported in current studies. Nano-Gold dispersion reaction with Chlorpyrifos solutions completes in 45 minutes at ambient temperature under the normal daylight and exhibit systematic variations in the solution color from wine red to pink to light sky blue and finally transforming into a transparent solution with fine precipitates. UV-Vis absorption studies correlates well with the systematic color changes as observed in the nano-gold treated Chlorpyrifos solutions with time. The characteristic localized surface plasmon resonance peak of nanogold dispersion observed at 529 nm red shifts to weak, medium and strong intensity peaks at ∼ 640 nm, 740 nm and 890 nm on increasing chlorpyrifos concentration owing to the aggregation of gold nanoparticles in small to bigger sized clusters. The fine turbidity in final transparent solution further confirms the aggregation of nanogold particles into stable bigger ensembles. IR transmission spectra of final transparent solutions showed disappearance of Chlorpyrifos νC-Cl and phosphorothioate functional group peaks indicating degradation of chlorpyrifos.

Type
Articles
Information
MRS Advances , Volume 5 , Issue 52-53: Nanoscale and Quantum Materials , 2020 , pp. 2661 - 2667
Check for updates
Copyright
Copyright © 2020 Materials Research Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Mostafalou, S. and Abdollahi, M., Toxicol. Appl. Pharmacol. 268, 157 (2013).CrossRefGoogle Scholar
Hodgson, E., “A Textbook of Modern Toxicology, 3rd ed. (John Wiley & Sons, Inc.: New Jersey, USA, 2004).CrossRefGoogle Scholar
United States Environmental Protection Agency (US EPA); Preliminary Cumulative Risk Assessment of the Organophosphorus Pesticides; US EPA: Washington, DC, USA, 2001Google Scholar
Garcia-Reyes, J. F., Gilbert-Lopez, B., Molina-Diaz, A., Fernandez-Alba, A.R., Anal. Chem. 80, 8966 (2008).CrossRefGoogle Scholar
Clausen, L., Fabricius, I., and Madsen, L., J. Environ. Qual, 30 (3), 846 (2001).Google Scholar
Mirkovic, M.M., Pasti, T.D.L., Dosenetal, A.M., RSC Advances, 6 (15), 12219 (2016).CrossRefGoogle Scholar
Ayranci, E. and Hoda, N., Chemosphere, 60 (11), 1600 (2005).CrossRefGoogle Scholar
Wang, P., Yin, Y., Guo, Y. and Wang, C., RSC Advances, 6 (13), 10615 (2016).Google Scholar
Lazarevic Pasti, T. D., Pasti, I. A., Jokic, B., Babic, B. M. and Vasic, V. M., RSC Advances, 6 (67), 62128 (2016).CrossRefGoogle Scholar
Maliyekkal, S. M., Sreeprasad, T. S., Krishnan, D. et al. , Small, 9 (2), 273 (2013).CrossRefGoogle Scholar
Bootharajuand, M.S. and Pradeep, T., Langmuir, 28 (5), 2671 (2012).Google Scholar
Simeonidis, K., Mourdikoudis, S., Kaprara, E., Mitrakas, M. and Polavarapu, L., Environmental Science: Water Research & Technology, 2(1), 43 (2016).Google Scholar
Nair, A.S. and Pradeep, T., J Nanosci. Nanotechno., 7(6), 1871 (2007).Google Scholar
Goel, P. and Arora, M., MRS Commun., 8(03), 1 (2018).CrossRefGoogle Scholar
Visser, Tom, Infrared Spectra of Pesticides, CRC Book, 1993, pp. 279.Google Scholar
Lin Vien, D., Colthup, N.B., Fateley, W.G. and Grassellie, J.G., “Infrared and Raman Characteristic Frequencies of Organic Molecules (Academic Press, London, 1991)”.Google Scholar
Devi, L. G., Murthy, B. N. and Kumar, S.G., J. Mol. Catal. A, 308, 174 (2009).CrossRefGoogle Scholar
Goel, P., Arora, M. and Biradar, A.M., RSC Adv., 5, 14974 (2015).Google Scholar
Mortland, M. M. and Raman, K. V. J., Agric. Food Chem., 15, 163 (1967).CrossRefGoogle Scholar