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Study of the temperature effect on the morphology and structure of ZnS nanoparticles synthesized by hydrothermal method

Published online by Cambridge University Press:  16 November 2020

Claudia J. Bahena-Martínez ,
Nayely Torres-Gómez  and
Alfredo R. Vilchis-Néstor Open the ORCID record for Alfredo R. Vilchis-Néstor [Opens in a new window]
Claudia J. Bahena-Martínez
Affiliation:
Master in Materials Science from the Facultad de Química, Universidad Autónoma del Estado de México, Av. Paseo Colón-Av. Paseo Tollocan, 50000, Toluca, México State, México Centro Conjunto de Investigación en Química Sustentable, CCIQS UAEM-UNAM, Highway Km. 14.5, San Cayetano, Toluca - Atlacomulco, 50200, Toluca de Lerdo, México.
Nayely Torres-Gómez
Affiliation:
Tecnológico Nacional de México – Campus Toluca. Av. Tecnológico, Bellavista Metepec, 52149, México, México.
Alfredo R. Vilchis-Néstor
Affiliation:
Centro Conjunto de Investigación en Química Sustentable, CCIQS UAEM-UNAM, Highway Km. 14.5, San Cayetano, Toluca - Atlacomulco, 50200, Toluca de Lerdo, México.
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Abstract

The control over the materials structure is crucial for the modulation of its properties, in order to achieve this control is important to know the formation mechanism of the material as function of parameters used. For this purpose, the effect of temperature (120, 140, 160 and 180 °C) on the hydrothermal synthesis of zinc sulphide is evaluated and a proposal of the sequence of reactions formation of zinc sulphur is presented. ZnS nanostructures with blend-phase were obtained, the temperature increment induces the growth of the nanostructure ranged between .62 and 12.72 nm, furthermore, increase the crystallinity of the ZnS nanostructures. The proposed reactions suggest the formation of a complex of thioacetamide with the Zn+2 and its subsequent decomposition into ZnS.

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Articles
Information
MRS Advances , Volume 5 , Issue 63: International Materials Research Congress XXIX , 2020 , pp. 3379 - 3388
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Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

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