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The Effect of Silver Ion Occupancy on Hollandite Lattice Structure

Published online by Cambridge University Press:  26 February 2018

Alexander B. Brady ,
Jianping Huang ,
Jessica L. Durham ,
Paul F. Smith ,
Jianming Bai ,
Esther S. Takeuchi ,
Amy C. Marschilok  and
Kenneth J. Takeuchi
Alexander B. Brady
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794.
Jianping Huang
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
Jessica L. Durham
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
Paul F. Smith
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
Jianming Bai
Affiliation:
Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, N.Y., 11973.
Esther S. Takeuchi
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794. Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794. Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, N.Y., 11973.
Amy C. Marschilok*
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794. Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794. Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, N.Y., 11973.
Kenneth J. Takeuchi*
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794. Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
*
*corresponding authors: amy.marschilok@stonybrook.edu, kenneth.takeuchi.1@stonybrook.edu
*corresponding authors: amy.marschilok@stonybrook.edu, kenneth.takeuchi.1@stonybrook.edu
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Abstract

The effect of tunnel cations on tunnel size in α-MnO2 structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (KxMn8O16). This paper uses synthetic control of silver content in AgxMn8O16 to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.

Keywords

AgMnenergy storage
Type
Articles
Information
MRS Advances , Volume 3 , Issue 10: Theory, Characterization and Modeling , 2018 , pp. 547 - 552
Copyright
Copyright © Materials Research Society 2018 

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References

Byström, A. and Byström, A. M., Acta Crystallographica 3 (2), 146–154 (1950).Google Scholar
Ramsdell, L., Am. Mineral 27 (9), 610–613 (1942).Google Scholar
GnuNrn, J., Amer. Mineral 28 (1943).Google Scholar
Dharmarathna, S., King’ondu, C. K., Pedrick, W., Pahalagedara, L. and Suib, S. L., Chemistry of Materials 24 (4), 705–712 (2012).Google Scholar
Huang, H., Sithambaram, S., Chen, C.-H., King’ondu Kithongo, C., Xu, L., Iyer, A., Garces, H. F. and Suib, S. L., Chemistry of Materials 22 (12), 3664–3669 (2010).Google Scholar
Dyer, A., Pillinger, M., Newton, J., Harjula, R., Möller, T. and Amin, S., Chemistry of materials 12 (12), 3798–3804 (2000).Google Scholar
Li, L. and King, D. L., Chemistry of materials 17 (17), 4335–4343 (2005).Google Scholar
Nicolas-Tolentino, E., Tian, Z.-R., Zhou, H., Xia, G. and Suib, S. L., Chemistry of Materials 11 (7), 1733–1741 (1999).Google Scholar
Tsuji, M. and Komarneni, S., Journal of Materials Research 8 (3), 611–616 (1993).Google Scholar
Takeuchi, K. J., Yau, S. Z., Menard, M. C., Marschilok, A. C. and Takeuchi, E. S., ACS applied materials & interfaces 4 (10), 5547–5554 (2012).Google Scholar
Zhu, S., Marschilok, A. C., Lee, C.-Y., Takeuchi, E. S. and Takeuchi, K. J., Electrochemical and Solid-State Letters 13 (8), A98–A100 (2010).Google Scholar
Takeuchi, K. J., Yau, S. Z., Subramanian, A., Marschilok, A. C. and Takeuchi, E. S., Journal of The Electrochemical Society 160 (5), A3090–A3094 (2013).CrossRefGoogle Scholar
Zhang, J. and Burnham, C. W., American Mineralogist 79 (1-2), 168–174 (1994).Google Scholar
Poyraz, A. S., Huang, J., Pelliccione, C. J., Tong, X., Cheng, S., Wu, L., Zhu, Y., Marschilok, A. C., Takeuchi, K. J. and Takeuchi, E. S., Journal of Materials Chemistry A 5 (32), 16914–16928 (2017).Google Scholar
Wu, L., Xu, F., Zhu, Y., Brady, A. B., Huang, J., Durham, J. L., Dooryhee, E., Marschilok, A. C., Takeuchi, E. S. and Takeuchi, K. J., ACS nano 9 (8), 8430–8439 (2015).Google Scholar
Chang, F. M. and Jansen, M., Revue De Chimie Minerales 23, 48–54 (1986).Google Scholar
Chang, F. M. and Jansen, M., Angewandte Chemie International Edition 23 (11), 906–907 (1984).Google Scholar
Chen, J., Tang, X., Liu, J., Zhan, E., Li, J., Huang, X. and Shen, W., Chemistry of materials 19 (17), 4292–4299 (2007).Google Scholar
Takeuchi, K. J., Yau, S. Z., Menard, M. C., Marschilok, A. C. and Takeuchi, E. S., ACS Applied Materials & Interfaces 4 (10), 5547–5554 (2012).Google Scholar
Post, J. E., Von Dreele, R. B. and Buseck, P. R., Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry 38 (4), 1056–1065 (1982).Google Scholar
Hammersley, A. P., Svensson, S. O., Hanfland, M., Fitch, A. N. and Hausermann, D., High Pressure Research 14 (4-6), 235–248 (1996).Google Scholar
Toby, B. H. and Von Dreele, R. B., Journal of Applied Crystallography 46 (2), 544–549 (2013).Google Scholar
Djerdj, I., Arčon, D., Jagličić, Z. and Niederberger, M., The Journal of Physical Chemistry C 111 (9), 3614–3623 (2007).Google Scholar
Lee, E.-J., Chen, Z., Noh, H.-J., Nam, S. C., Kang, S., Kim, D. H., Amine, K. and Sun, Y.-K., Nano Letters 14 (8), 4873–4880 (2014).Google Scholar
Barudžija, T., Kusigerski, V., Cvjetićanin, N., Šorgić, S., Perović, M. and Mitrić, M., Journal of Alloys and Compounds 665, 261–270 (2016).Google Scholar
Kijima, N., Ikeda, T., Oikawa, K., Izumi, F. and Yoshimura, Y., Journal of Solid State Chemistry 177 (4), 1258–1267 (2004).Google Scholar
Vicat, J., Fanchon, E., Strobel, P. and Tran Qui, D., Acta Crystallographica Section B: Structural Science 42 (2), 162–167 (1986).Google Scholar
Kondrashev, Y. D. and Zaslavskii, A., Izvestiya Akademii Nauk SSSR, Seriya Fizicheskaya 15, 179–186 (1951).Google Scholar