Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-18T05:51:57.919Z Has data issue: false hasContentIssue false
  • English
  • Français

Modification of beads of chitosan and poly(vinyl alcohol) by means of glow discharge plasma for the adsorption of red 2 dye

Published online by Cambridge University Press:  08 February 2019

Antonio Alvarado-Bonifacio ,
Beatriz García-Gaitán Open the ORCID record for Beatriz García-Gaitán [Opens in a new window] ,
Celso Hernández-Tenorio ,
José Luis García-Rivas ,
Maricarmen Thalía Recillas-Mota ,
Rosa Elvira Zavala-Arce ,
María de la Luz Jiménez-Núñez  and
Teresa Soriano-Aguilar
Antonio Alvarado-Bonifacio
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, División de Estudios de Posgrado e Investigación, Av. Tecnológico s/n, Col. Agrícola Bellavista, C.P.52149, Metepec, Edo. de México, México.
Beatriz García-Gaitán*
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, División de Estudios de Posgrado e Investigación, Av. Tecnológico s/n, Col. Agrícola Bellavista, C.P.52149, Metepec, Edo. de México, México.
Celso Hernández-Tenorio
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, División de Estudios de Posgrado e Investigación, Av. Tecnológico s/n, Col. Agrícola Bellavista, C.P.52149, Metepec, Edo. de México, México.
José Luis García-Rivas
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, División de Estudios de Posgrado e Investigación, Av. Tecnológico s/n, Col. Agrícola Bellavista, C.P.52149, Metepec, Edo. de México, México.
Maricarmen Thalía Recillas-Mota
Affiliation:
Centro de Investigación en Alimentación y Desarrollo, Unidad Guaymas, Grupo de Investigación de Biopolímeros, Carretera al Varadero Nacional Km. 6.6, Col. Las Playitas, C.P.85480, Guaymas, Sonora, México.
Rosa Elvira Zavala-Arce
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, División de Estudios de Posgrado e Investigación, Av. Tecnológico s/n, Col. Agrícola Bellavista, C.P.52149, Metepec, Edo. de México, México.
María de la Luz Jiménez-Núñez
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, División de Estudios de Posgrado e Investigación, Av. Tecnológico s/n, Col. Agrícola Bellavista, C.P.52149, Metepec, Edo. de México, México.
Teresa Soriano-Aguilar
Affiliation:
Tecnológico Nacional de México/Instituto Tecnológico de Toluca, División de Estudios de Posgrado e Investigación, Av. Tecnológico s/n, Col. Agrícola Bellavista, C.P.52149, Metepec, Edo. de México, México.
*
*(Email: beatrizggmx@yahoo.com)
Get access

Abstract

Three sizes of beads 1, 2 and 3 mm of chitosan and poly (vinyl alcohol) were generated and crosslinked with ethylene glycol diglycidyl ether. The modification was carried out using a glass reactor, in which the beads were exposed to the glow discharge plasma (GDP). The adsorption experiments were carried out in triplicate at 30 °C, 200 rpm, 72 h at different pH values in the range between 2 and 7. The concentrations of the dye in the supernatants were determined by UV-vis spectrophotometry. The 1 mm beads with and without modification, as well as those adsorbed and without adsorbing were characterized by FTIR and SEM. A higher and constant adsorption capacity was observed using modified beads (814, 857 and 1509 mg/g for the 3, 2 and 1 mm beads, respectively). For unmodified beads the adsorption capacity decreased when the initial pH value was increased. This makes the beads modified by GDP a robust material with respect to pH variation and a good candidate to be used in the removal of synthetic dyes.

Keywords

absorptionbiomaterialpolymer
Type
Articles
Information
MRS Advances , Volume 3 , Issue 63: International Materials Research Congress XXVII , 2018 , pp. 3869 - 3874
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES:

Albadarin, A. B., Collins, M. N., Naushad, M., Shirazian, S., Walker, G. and Mangwandi, C., Chem. Eng. J. 307, 264 (2017).CrossRefGoogle Scholar
Jawad, A. H., Islam, M. A. and Hameed, B. H., Int. J. Biol. Macromol. 95, 743 (2017).CrossRefGoogle Scholar
Wen, Y., Shen, C., Ni, Y., Tong, S. and Yu, F., J. Hazard. Mater. 201–202, 162 (2012).CrossRefGoogle Scholar
Huang, R., Lui, Q., Huo, J. and Yang, B., Arab. J. Chem. 10, 24 (2017).CrossRefGoogle Scholar
Noroozi, B. and Sorial, G. A., J. Environ. Sci. 25 (3), 419 (2013).CrossRefGoogle Scholar
Marrakchi, F., Ahmed, M. J., Khanday, W. A., Asif, M. and Hameed, B. H., Int. J. Biol. Macromol. 98, 233 (2017).CrossRefGoogle Scholar
Kumari, H. J., Krishnamoorthy, P., Arumugam, T. K., Radhakrishnan, S. and Vasudevan, D., Int. J. Biol. Macromol. 96, 324 (2017).CrossRefGoogle Scholar
Oladipo, A. A., Gazi, M. and Yilmaz, E., Chem. Eng. Res. Des. 104, 264 (2015).CrossRefGoogle Scholar
Jin, L. and Bai, R., Langmuir 18, 9765 (2002).CrossRefGoogle Scholar
Coates, J., “Interpretation of infrared spectra, a practical approach”, Encyclopedia of Analytical Chemistry , ed. Meyers, R. A. (John Wiley & Sons Ltd, Chichester, 2000) pp. 10815-10837.Google Scholar
Zheng, L., Wang, C., Shu, Y., Yan, X. and Li, L., Colloids Surf. A Physicochem. Eng. Asp. 468, 129 (2014).CrossRefGoogle Scholar
Karkmaz, M., Puzenat, E., Guillard, C. and Herrmann, J. M., Appl. Catal., B 51, 183 (2004).CrossRefGoogle Scholar
Ahmed, F., Dewani, R., Pervez, M. K., Mahboob, S. J. and Soomro, S. A., Bulg. Chem. Commun. 48(1), 71 (2016).Google Scholar
Huo, Y., Wu, H., Wang, Z., Wang, F., Liu, Y., Feng, Y., Colloids Surf. A Physicochem. Eng. Asp. 549, 174 (2018).CrossRefGoogle Scholar
Abdellaoui, K., Pavlovic, I., Bouhent, M., Benhamou, A., Barriga, C., Appl. Clay. Sci. 143, 142 (2017).CrossRefGoogle Scholar
Ndifor-Angwafor, N. G., Tiotsop, I. H. K., Tchuifon, D. R. T., Sadeu, C. N., Bopda, A., Anagho, S. G., Kamdem, T. A.. J. Mater. Environ. Sci. 8(12), 4199 (2017).Google Scholar
Salem, A. N. M., Ahmed, M. A., El-Shahat, M. F.. J. Mol. Liq. 219, 780 (2016).CrossRefGoogle Scholar
Rêgo, T. V., Cadaval, T. R. S. Jr., Dotto, G. L., Pinto, L. A. A., J. Colloid Interface Sci. 411, 27 (2013).CrossRefGoogle Scholar
Ahmad, R., Kumar, R., Clean-Soil Air Water , 39(1),74 (2011).CrossRefGoogle Scholar
Nassar, N. N., Sep. Sci. Technol. 45(8), 1092 (2010).CrossRefGoogle Scholar