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Sonochemical Functionalization of Boron Nitride Nanomaterials

Published online by Cambridge University Press:  27 December 2019

Haley B. Harrison  and
Jeffrey R. Alston Open the ORCID record for Jeffrey R. Alston [Opens in a new window]
Haley B. Harrison
Affiliation:
The University of North Carolina at Greensboro1, North Carolina Agricultural and Technical State University
Jeffrey R. Alston*
Affiliation:
The Joint School of Nanoscience and Nanoengineering Greensboro, North Carolina
*
*(Email: jralston1@ncat.edu)
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Abstract

Boron nitride nanotubes (BNNTs) and hexagonal boron nitride platelets (h-BNs) have received considerable attention for aerospace insulation applications due to their exceptional chemical and thermal stability. Presently, making BN nanomaterials compatible with polymer and composite matrices is challenging. Due to their inert and highly stable structure, h-BN and BNNTs are difficult to covalently functionalize. In this work, we present a novel sonochemical technique that enables covalent attachment of fluoroalkoxy substituents to the surface of BN nanomaterials in a controlled and metered process. Covalent functionalization is confirmed via colloidal stability analysis, FT-IR, and x-ray photoelectron spectroscopy (XPS).

Keywords

colloidx-ray photoelectron spectroscopy (XPS)surface chemistrynanoscalenanostructure
Type
Articles
Information
MRS Advances , Volume 5 , Issue 14-15: Soft Materials and Biomaterials , 2020 , pp. 709 - 716
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Copyright
Copyright © Materials Research Society 2019

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