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High-energy x-ray scattering studies of battery materials

Published online by Cambridge University Press:  08 June 2016

Matthew P.B. Glazer ,
John S. Okasinski ,
Jonathan D. Almer  and
Yang Ren
Matthew P.B. Glazer
Affiliation:
Materials Science and Engineering Department, Northwestern University, USA; mglazer@u.northwestern.edu
John S. Okasinski
Affiliation:
Advanced Photon Source, Argonne National Laboratory, USA; okasinski@aps.anl.gov
Jonathan D. Almer
Affiliation:
Advanced Photon Source, Argonne National Laboratory, USA; almer@aps.anl.gov
Yang Ren
Affiliation:
Advanced Photon Source, Argonne National Laboratory, USA; ren@aps.anl.gov
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Abstract

High-energy x-ray (HEX) scattering is a sensitive and powerful tool to nondestructively probe the atomic and mesoscale structures of battery materials under synthesis and operational conditions. The penetration power of HEXs enables the use of large, practical samples and realistic environments, allowing researchers to explore the inner workings of batteries in both laboratory and commercial formats. This article highlights the capability and versatility of HEX techniques, particularly from synchrotron sources, to elucidate materials synthesis processes and thermal instability mechanisms in situ, to understand (dis)charging mechanisms in operando under a variety of cycling conditions, and to spatially resolve electrode/electrolyte responses to highlight connections between inhomogeneity and performance. Such studies have increased our understanding of the fundamental mechanisms underlying battery performance. By deepening our understanding of the linkages between microstructure and overall performance, HEXs represent a powerful tool for validating existing batteries and shortening battery-development timelines.

Keywords

x-ray diffraction (XRD)energy storageLiintercalation
Type
Research Article
Information
MRS Bulletin , Volume 41 , Issue 6: Synchrotron Radiation Research in Materials Science , June 2016 , pp. 460 - 465
Copyright
Copyright © Materials Research Society 2016 

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